(a) Interpretation: The molarity of 1.25 L of solution containing 0.455 mol of solute is to be calculated. Concept introduction: A solution is prepared by mixing proper amount of solute and solvent. The concentration of solution when measured on the basis of solution volume, is expressed in terms of percent weight by volume ( % w / v ) , percent volume by volume ( % v / v ) and molarity ( M ) . When concentration is measured on the basis of mass of solvent, it is expressed in terms of percent weight by weight ( % w / w ) .

Question

For questions 1-4, consider the following complexes: [Co(CN)6]+, [CoCl4]², [Cr(H2O)6]²+ 2. Draw the corresponding d-orbital splitting for each of the complexes; predict the spin- state (low-spin/high spin) for each of the complexes (if applicable); explain your arguments. Calculate the crystal field stabilization energy for each complex (in Ao or At). (6 points)

Answer 1

Question

100%

Chapter 7, Problem 7.20E

Interpretation Introduction

(a)

Interpretation:

The molarity of 1.25 L of solution containing 0.455 mol of solute is to be calculated.

Concept introduction:

A solution is prepared by mixing proper amount of solute and solvent. The concentration of solution when measured on the basis of solution volume, is expressed in terms of percent weight by volume (% w/v), percent volume by volume (% v/v) and molarity (M). When concentration is measured on the basis of mass of solvent, it is expressed in terms of percent weight by weight (% w/w).

Interpretation Introduction

(b)

Interpretation:

The molarity of 250 mL of solution containing 0.215 mol of solute is to be calculated.

Concept introduction:

A solution is prepared by mixing proper amount of solute and solvent. The concentration of solution when measured on the basis of solution volume, is expressed in terms of percent weight by volume (% w/v), percent volume by volume (% v/v) and molarity (M). When concentration is measured on the basis of mass of solvent, it is expressed in terms of percent weight by weight (% w/w).

Interpretation Introduction

(c)

Interpretation:

The molarity of 0.175 mol of solute present in 100 mL of solution is to be calculated.

Concept introduction:

A solution is prepared by mixing proper amount of solute and solvent. The concentration of solution when measured on the basis of solution volume, is expressed in terms of percent weight by volume (% w/v), percent volume by volume (% v/v) and molarity (M). When concentration is measured on the basis of mass of solvent, it is expressed in terms of percent weight by weight (% w/w).

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For questions 1-4, consider the following complexes: [Co(CN)6]+, [CoCl4]², [Cr(H2O)6]²+ 2. Draw the corresponding d-orbital splitting for each of the complexes; predict the spin- state (low-spin/high spin) for each of the complexes (if applicable); explain your arguments. Calculate the crystal field stabilization energy for each complex (in Ao or At). (6 points)

For questions 1-4, consider the following complexes: [Co(CN)6]4, [COC14]², [Cr(H2O)6]²+ 1. Assign oxidation number to the metal, then indicate d-electron count. (3 points)

Using iodometry I want to titrate a sodium thiosulfate solution and I use 15 mL. If I have 50 mL of a 0.90 M copper solution and KI, what will be the molarity of sodium thiosulfate?

Answer 2

Question

100%

Chapter 7, Problem 7.20E

Interpretation Introduction

(a)

Interpretation:

The molarity of 1.25 L of solution containing 0.455 mol of solute is to be calculated.

Concept introduction:

A solution is prepared by mixing proper amount of solute and solvent. The concentration of solution when measured on the basis of solution volume, is expressed in terms of percent weight by volume (% w/v), percent volume by volume (% v/v) and molarity (M). When concentration is measured on the basis of mass of solvent, it is expressed in terms of percent weight by weight (% w/w).

Interpretation Introduction

(b)

Interpretation:

The molarity of 250 mL of solution containing 0.215 mol of solute is to be calculated.

Concept introduction:

A solution is prepared by mixing proper amount of solute and solvent. The concentration of solution when measured on the basis of solution volume, is expressed in terms of percent weight by volume (% w/v), percent volume by volume (% v/v) and molarity (M). When concentration is measured on the basis of mass of solvent, it is expressed in terms of percent weight by weight (% w/w).

Interpretation Introduction

(c)

Interpretation:

The molarity of 0.175 mol of solute present in 100 mL of solution is to be calculated.

Concept introduction:

A solution is prepared by mixing proper amount of solute and solvent. The concentration of solution when measured on the basis of solution volume, is expressed in terms of percent weight by volume (% w/v), percent volume by volume (% v/v) and molarity (M). When concentration is measured on the basis of mass of solvent, it is expressed in terms of percent weight by weight (% w/w).

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Answer 3

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Chapter 7, Problem 7.20E

Interpretation Introduction

(a)

Interpretation:

The molarity of 1.25 L of solution containing 0.455 mol of solute is to be calculated.

Concept introduction:

A solution is prepared by mixing proper amount of solute and solvent. The concentration of solution when measured on the basis of solution volume, is expressed in terms of percent weight by volume (% w/v), percent volume by volume (% v/v) and molarity (M). When concentration is measured on the basis of mass of solvent, it is expressed in terms of percent weight by weight (% w/w).

Interpretation Introduction

(b)

Interpretation:

The molarity of 250 mL of solution containing 0.215 mol of solute is to be calculated.

Concept introduction:

A solution is prepared by mixing proper amount of solute and solvent. The concentration of solution when measured on the basis of solution volume, is expressed in terms of percent weight by volume (% w/v), percent volume by volume (% v/v) and molarity (M). When concentration is measured on the basis of mass of solvent, it is expressed in terms of percent weight by weight (% w/w).

Interpretation Introduction

(c)

Interpretation:

The molarity of 0.175 mol of solute present in 100 mL of solution is to be calculated.

Concept introduction:

A solution is prepared by mixing proper amount of solute and solvent. The concentration of solution when measured on the basis of solution volume, is expressed in terms of percent weight by volume (% w/v), percent volume by volume (% v/v) and molarity (M). When concentration is measured on the basis of mass of solvent, it is expressed in terms of percent weight by weight (% w/w).

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Answer 4

Question

100%

Chapter 7, Problem 7.20E

Interpretation Introduction

(a)

Interpretation:

The molarity of 1.25 L of solution containing 0.455 mol of solute is to be calculated.

Concept introduction:

A solution is prepared by mixing proper amount of solute and solvent. The concentration of solution when measured on the basis of solution volume, is expressed in terms of percent weight by volume (% w/v), percent volume by volume (% v/v) and molarity (M). When concentration is measured on the basis of mass of solvent, it is expressed in terms of percent weight by weight (% w/w).

Interpretation Introduction

(b)

Interpretation:

The molarity of 250 mL of solution containing 0.215 mol of solute is to be calculated.

Concept introduction:

A solution is prepared by mixing proper amount of solute and solvent. The concentration of solution when measured on the basis of solution volume, is expressed in terms of percent weight by volume (% w/v), percent volume by volume (% v/v) and molarity (M). When concentration is measured on the basis of mass of solvent, it is expressed in terms of percent weight by weight (% w/w).

Interpretation Introduction

(c)

Interpretation:

The molarity of 0.175 mol of solute present in 100 mL of solution is to be calculated.

Concept introduction:

A solution is prepared by mixing proper amount of solute and solvent. The concentration of solution when measured on the basis of solution volume, is expressed in terms of percent weight by volume (% w/v), percent volume by volume (% v/v) and molarity (M). When concentration is measured on the basis of mass of solvent, it is expressed in terms of percent weight by weight (% w/w).

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Answer 5

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Answer 6

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100%

Answer 7

Chapter 7, Problem 7.20E

Interpretation Introduction

(a)

Interpretation:

The molarity of 1.25 L of solution containing 0.455 mol of solute is to be calculated.

Concept introduction:

A solution is prepared by mixing proper amount of solute and solvent. The concentration of solution when measured on the basis of solution volume, is expressed in terms of percent weight by volume (% w/v), percent volume by volume (% v/v) and molarity (M). When concentration is measured on the basis of mass of solvent, it is expressed in terms of percent weight by weight (% w/w).

Interpretation Introduction

(b)

Interpretation:

The molarity of 250 mL of solution containing 0.215 mol of solute is to be calculated.

Concept introduction:

A solution is prepared by mixing proper amount of solute and solvent. The concentration of solution when measured on the basis of solution volume, is expressed in terms of percent weight by volume (% w/v), percent volume by volume (% v/v) and molarity (M). When concentration is measured on the basis of mass of solvent, it is expressed in terms of percent weight by weight (% w/w).

Interpretation Introduction

(c)

Interpretation:

The molarity of 0.175 mol of solute present in 100 mL of solution is to be calculated.

Concept introduction:

A solution is prepared by mixing proper amount of solute and solvent. The concentration of solution when measured on the basis of solution volume, is expressed in terms of percent weight by volume (% w/v), percent volume by volume (% v/v) and molarity (M). When concentration is measured on the basis of mass of solvent, it is expressed in terms of percent weight by weight (% w/w).

Answer 8

Chapter 7, Problem 7.20E

Interpretation Introduction

(a)

Interpretation:

The molarity of 1.25 L of solution containing 0.455 mol of solute is to be calculated.

Concept introduction:

A solution is prepared by mixing proper amount of solute and solvent. The concentration of solution when measured on the basis of solution volume, is expressed in terms of percent weight by volume (% w/v), percent volume by volume (% v/v) and molarity (M). When concentration is measured on the basis of mass of solvent, it is expressed in terms of percent weight by weight (% w/w).

Answer 9

Chapter 7, Problem 7.20E

Interpretation Introduction

(a)

Interpretation:

The molarity of 1.25 L of solution containing 0.455 mol of solute is to be calculated.

Concept introduction:

A solution is prepared by mixing proper amount of solute and solvent. The concentration of solution when measured on the basis of solution volume, is expressed in terms of percent weight by volume (% w/v), percent volume by volume (% v/v) and molarity (M). When concentration is measured on the basis of mass of solvent, it is expressed in terms of percent weight by weight (% w/w).

Answer 10

Interpretation Introduction

(b)

Interpretation:

The molarity of 250 mL of solution containing 0.215 mol of solute is to be calculated.

Concept introduction:

A solution is prepared by mixing proper amount of solute and solvent. The concentration of solution when measured on the basis of solution volume, is expressed in terms of percent weight by volume (% w/v), percent volume by volume (% v/v) and molarity (M). When concentration is measured on the basis of mass of solvent, it is expressed in terms of percent weight by weight (% w/w).

Answer 11

Interpretation Introduction

(b)

Interpretation:

The molarity of 250 mL of solution containing 0.215 mol of solute is to be calculated.

Concept introduction:

A solution is prepared by mixing proper amount of solute and solvent. The concentration of solution when measured on the basis of solution volume, is expressed in terms of percent weight by volume (% w/v), percent volume by volume (% v/v) and molarity (M). When concentration is measured on the basis of mass of solvent, it is expressed in terms of percent weight by weight (% w/w).

Answer 12

Interpretation Introduction

(c)

Interpretation:

The molarity of 0.175 mol of solute present in 100 mL of solution is to be calculated.

Concept introduction:

A solution is prepared by mixing proper amount of solute and solvent. The concentration of solution when measured on the basis of solution volume, is expressed in terms of percent weight by volume (% w/v), percent volume by volume (% v/v) and molarity (M). When concentration is measured on the basis of mass of solvent, it is expressed in terms of percent weight by weight (% w/w).

Answer 13

Interpretation Introduction

(c)

Interpretation:

The molarity of 0.175 mol of solute present in 100 mL of solution is to be calculated.

Concept introduction:

A solution is prepared by mixing proper amount of solute and solvent. The concentration of solution when measured on the basis of solution volume, is expressed in terms of percent weight by volume (% w/v), percent volume by volume (% v/v) and molarity (M). When concentration is measured on the basis of mass of solvent, it is expressed in terms of percent weight by weight (% w/w).

Answer 14

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Ch. 7 - Many solutions are found in the home. Some are...Ch. 7 - Prob. 7.2E Ch. 7 - Classify the following as being a solution or not...Ch. 7 - Classify the following as being a solution or not...Ch. 7 - Use the term soluble, insoluble, or immiscible to...Ch. 7 - Use the term soluble, insoluble, or immiscible to...Ch. 7 - Define the term miscible. It is not defined in the...Ch. 7 - Classify the following solutions as unsaturated,...Ch. 7 - Prob. 7.9E Ch. 7 - Prob. 7.10E

Chapter 7 Solutions