The reagent must be provided to achieve the given transformation. Concept Introduction : The OTs group is a good leaving group which can be displaced by simple nucleophilic substitution.

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Answer 1

Question

Chapter 7, Problem 71PP

(a)

Interpretation Introduction

Interpretation:

The reagent must be provided to achieve the given transformation.

Concept Introduction :

The OTs group is a good leaving group which can be displaced by simple nucleophilic substitution.

(b)

Interpretation Introduction

Interpretation:

The reagent must be provided to achieve the given transformation of alcohol to cyano compound.

Concept Introduction :

The OH group is a bad leaving group which can be displaced by cyanide after converting the OH to a good leaving group.

(c)

Interpretation Introduction

Interpretation:

The reagents must be provided for the conversion of tertiary alcohol to tertiary bromide.

Concept Introduction :

The tertiary alcohols can undergo acid catalyzed S_N1 substitution.

(d)

Interpretation Introduction

Interpretation:

A suitable reagent must be provided for the conversion of chloro to thiol with inversion of configuration.

Concept Introduction :

The less hindered haloalkanes undergo nucleophilic substitution reaction with inversion of configuration. This is the S_N2 pathway.

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Answer 2

Question

Chapter 7, Problem 71PP

(a)

Interpretation Introduction

Interpretation:

The reagent must be provided to achieve the given transformation.

Concept Introduction :

The OTs group is a good leaving group which can be displaced by simple nucleophilic substitution.

(b)

Interpretation Introduction

Interpretation:

The reagent must be provided to achieve the given transformation of alcohol to cyano compound.

Concept Introduction :

The OH group is a bad leaving group which can be displaced by cyanide after converting the OH to a good leaving group.

(c)

Interpretation Introduction

Interpretation:

The reagents must be provided for the conversion of tertiary alcohol to tertiary bromide.

Concept Introduction :

The tertiary alcohols can undergo acid catalyzed S_N1 substitution.

(d)

Interpretation Introduction

Interpretation:

A suitable reagent must be provided for the conversion of chloro to thiol with inversion of configuration.

Concept Introduction :

The less hindered haloalkanes undergo nucleophilic substitution reaction with inversion of configuration. This is the S_N2 pathway.

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Answer 3

Question

Chapter 7, Problem 71PP

(a)

Interpretation Introduction

Interpretation:

The reagent must be provided to achieve the given transformation.

Concept Introduction :

The OTs group is a good leaving group which can be displaced by simple nucleophilic substitution.

(b)

Interpretation Introduction

Interpretation:

The reagent must be provided to achieve the given transformation of alcohol to cyano compound.

Concept Introduction :

The OH group is a bad leaving group which can be displaced by cyanide after converting the OH to a good leaving group.

(c)

Interpretation Introduction

Interpretation:

The reagents must be provided for the conversion of tertiary alcohol to tertiary bromide.

Concept Introduction :

The tertiary alcohols can undergo acid catalyzed S_N1 substitution.

(d)

Interpretation Introduction

Interpretation:

A suitable reagent must be provided for the conversion of chloro to thiol with inversion of configuration.

Concept Introduction :

The less hindered haloalkanes undergo nucleophilic substitution reaction with inversion of configuration. This is the S_N2 pathway.

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Answer 4

Question

Chapter 7, Problem 71PP

(a)

Interpretation Introduction

Interpretation:

The reagent must be provided to achieve the given transformation.

Concept Introduction :

The OTs group is a good leaving group which can be displaced by simple nucleophilic substitution.

(b)

Interpretation Introduction

Interpretation:

The reagent must be provided to achieve the given transformation of alcohol to cyano compound.

Concept Introduction :

The OH group is a bad leaving group which can be displaced by cyanide after converting the OH to a good leaving group.

(c)

Interpretation Introduction

Interpretation:

The reagents must be provided for the conversion of tertiary alcohol to tertiary bromide.

Concept Introduction :

The tertiary alcohols can undergo acid catalyzed S_N1 substitution.

(d)

Interpretation Introduction

Interpretation:

A suitable reagent must be provided for the conversion of chloro to thiol with inversion of configuration.

Concept Introduction :

The less hindered haloalkanes undergo nucleophilic substitution reaction with inversion of configuration. This is the S_N2 pathway.

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Answer 5

Chapter 7, Problem 71PP

(a)

Interpretation Introduction

Interpretation:

The reagent must be provided to achieve the given transformation.

Concept Introduction :

The OTs group is a good leaving group which can be displaced by simple nucleophilic substitution.

(b)

Interpretation Introduction

Interpretation:

The reagent must be provided to achieve the given transformation of alcohol to cyano compound.

Concept Introduction :

The OH group is a bad leaving group which can be displaced by cyanide after converting the OH to a good leaving group.

(c)

Interpretation Introduction

Interpretation:

The reagents must be provided for the conversion of tertiary alcohol to tertiary bromide.

Concept Introduction :

The tertiary alcohols can undergo acid catalyzed S_N1 substitution.

(d)

Interpretation Introduction

Interpretation:

A suitable reagent must be provided for the conversion of chloro to thiol with inversion of configuration.

Concept Introduction :

The less hindered haloalkanes undergo nucleophilic substitution reaction with inversion of configuration. This is the S_N2 pathway.

Answer 6

Chapter 7, Problem 71PP

(a)

Interpretation Introduction

Interpretation:

The reagent must be provided to achieve the given transformation.

Concept Introduction :

The OTs group is a good leaving group which can be displaced by simple nucleophilic substitution.

Answer 7

Chapter 7, Problem 71PP

(a)

Interpretation Introduction

Interpretation:

The reagent must be provided to achieve the given transformation.

Concept Introduction :

The OTs group is a good leaving group which can be displaced by simple nucleophilic substitution.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The reagent must be provided to achieve the given transformation of alcohol to cyano compound.

Concept Introduction :

The OH group is a bad leaving group which can be displaced by cyanide after converting the OH to a good leaving group.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The reagent must be provided to achieve the given transformation of alcohol to cyano compound.

Concept Introduction :

The OH group is a bad leaving group which can be displaced by cyanide after converting the OH to a good leaving group.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The reagents must be provided for the conversion of tertiary alcohol to tertiary bromide.

Concept Introduction :

The tertiary alcohols can undergo acid catalyzed S_N1 substitution.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The reagents must be provided for the conversion of tertiary alcohol to tertiary bromide.

Concept Introduction :

The tertiary alcohols can undergo acid catalyzed S_N1 substitution.

Answer 12

(d)

Interpretation Introduction

Interpretation:

A suitable reagent must be provided for the conversion of chloro to thiol with inversion of configuration.

Concept Introduction :

The less hindered haloalkanes undergo nucleophilic substitution reaction with inversion of configuration. This is the S_N2 pathway.

Answer 13

(d)

Interpretation Introduction

Interpretation:

A suitable reagent must be provided for the conversion of chloro to thiol with inversion of configuration.

Concept Introduction :

The less hindered haloalkanes undergo nucleophilic substitution reaction with inversion of configuration. This is the S_N2 pathway.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 7.2 - Prob. 1CC Ch. 7.3 - Prob. 2CC Ch. 7.3 - Prob. 1LTS Ch. 7.3 - Prob. 3PTS Ch. 7.3 - Prob. 4ATS Ch. 7.3 - Prob. 2LTS Ch. 7.3 - Prob. 5PTS Ch. 7.3 - Prob. 6ATS Ch. 7.3 - Prob. 7CC Ch. 7.4 - Prob. 8CC

The reagent must be provided to achieve the given transformation. Concept Introduction : The OTs group is a good leaving group which can be displaced by simple nucleophilic substitution.

Solution Summary: The author explains that the reagent must be provided to achieve the transformation of tertiary alcohol to cyano compound.

Interpretation:

The reagent must be provided to achieve the given transformation.

Concept Introduction :

The OTs group is a good leaving group which can be displaced by simple nucleophilic substitution.

Interpretation:

The reagent must be provided to achieve the given transformation of alcohol to cyano compound.

Concept Introduction :

The OH group is a bad leaving group which can be displaced by cyanide after converting the OH to a good leaving group.

Interpretation:

The reagents must be provided for the conversion of tertiary alcohol to tertiary bromide.

Concept Introduction :

The tertiary alcohols can undergo acid catalyzed S_N1 substitution.

Interpretation:

A suitable reagent must be provided for the conversion of chloro to thiol with inversion of configuration.

Concept Introduction :

The less hindered haloalkanes undergo nucleophilic substitution reaction with inversion of configuration. This is the S_N2 pathway.

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Chapter 7 Solutions

The reagent must be provided to achieve the given transformation. Concept Introduction : The OTs group is a good leaving group which can be displaced by simple nucleophilic substitution.

Solution Summary: The author explains that the reagent must be provided to achieve the transformation of tertiary alcohol to cyano compound.

Interpretation: The reagent must be provided to achieve the given transformation. Concept Introduction : The OTs group is a good leaving group which can be displaced by simple nucleophilic substitution.

Interpretation: The reagent must be provided to achieve the given transformation of alcohol to cyano compound. Concept Introduction : The OH group is a bad leaving group which can be displaced by cyanide after converting the OH to a good leaving group.

Interpretation: The reagents must be provided for the conversion of tertiary alcohol to tertiary bromide. Concept Introduction : The tertiary alcohols can undergo acid catalyzed SN1 substitution.

Interpretation: A suitable reagent must be provided for the conversion of chloro to thiol with inversion of configuration. Concept Introduction : The less hindered haloalkanes undergo nucleophilic substitution reaction with inversion of configuration. This is the SN2 pathway.

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Chapter 7 Solutions

Interpretation:

The reagent must be provided to achieve the given transformation.

Concept Introduction :

The OTs group is a good leaving group which can be displaced by simple nucleophilic substitution.

Interpretation:

The reagent must be provided to achieve the given transformation of alcohol to cyano compound.

Concept Introduction :

The OH group is a bad leaving group which can be displaced by cyanide after converting the OH to a good leaving group.

Interpretation:

The reagents must be provided for the conversion of tertiary alcohol to tertiary bromide.

Concept Introduction :

The tertiary alcohols can undergo acid catalyzed S_N1 substitution.

Interpretation:

A suitable reagent must be provided for the conversion of chloro to thiol with inversion of configuration.

Concept Introduction :

The less hindered haloalkanes undergo nucleophilic substitution reaction with inversion of configuration. This is the S_N2 pathway.