EBK PHYSICAL CHEMISTRY
EBK PHYSICAL CHEMISTRY
3rd Edition
ISBN: 9780133556094
Author: Reid
Publisher: YUZU
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Chapter 7, Problem 7.19NP
Interpretation Introduction

Interpretation : The critical volume for ethane using the data for Tc and Pc should be calculated assuming the ideal gas equation and the van der Waals equation of state.

Concept Introduction :

Ideal gas law,

  Vc=RTcPc

Vc − critical volume

R − universal gas constant

Tc − critical temperature

Pc − critical pressure

Van der Waals equation of state;

  Pc=RTcVcbaVc2

a − correction for intermolecular forces

b − correction for volume

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