EBK PHYSICAL CHEMISTRY
EBK PHYSICAL CHEMISTRY
3rd Edition
ISBN: 9780133556094
Author: Reid
Publisher: YUZU
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Chapter 7, Problem 7.10NP
Interpretation Introduction

Interpretation : The work done in the process should be calculated using the ideal gas and van der Waals equation of state. The percentage of the work done by the Van der Waal gas arises from attractive potential should be calculated.

Concept Introduction :

For ideal gas,

  w=nRTlnVfVi

Here,

  w work donen number of molesR universal gas constantT temperatureVf final volumeVi initial volume

For the van der Waals gas,

  w=ViVf( nRT Vnb n 2 a V 2 )dV=[nRTln( Vnb)+ a n 2 V]ViVf

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