12th Edition

ISBN: 9780078021510

Author: Raymond Chang Dr., Kenneth Goldsby Professor

Publisher: McGraw-Hill Education

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Quantum chemistry deals with the properties of chemical systems and their reactions. The branch of chemistry which is more concerned with quantum chemistry is physical chemistry. It is a more sophisticated field of theoretical physics which is concerned …

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Chapter 7, Problem 7.11QP

The SI unit of time is the second, which is defined as 9,192,631,770 cycles of radiation associated with a certain emission process in the cesium atom. Calculate the wavelength of this radiation (to three significant figures). In which region of the electromagnetic spectrum is this wavelength found?

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Chapter 7, Problem 7.10QP

Chapter 7, Problem 7.12QP

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Chapter 7 Solutions

Chemistry

Ch. 7.1 - Which of the waves (a)(c) has (i) the highest...Ch. 7.1 - What is the wavelength (in meters) of an...Ch. 7.1 - Why is radiation only in the UV but not the...Ch. 7.2 - The energy of a photon is 5.87 1020 J. What is...Ch. 7.2 - The work function of titanium metal is 6.93 1019...Ch. 7.2 - A clean metal surface is irradiated with light of...Ch. 7.3 - What is the wavelength (in nanometers) of a photon...Ch. 7.3 - Which transition in the hydrogen atom would emit...Ch. 7.4 - Calculate the wavelength (in nanometers) of a H...Ch. 7.4 - Which quantity in Equation (7.8) is responsible...

Ch. 7.5 - Estimate the uncertainty in the speed of an oxygen...Ch. 7.5 - What is the difference between and 2 for the...Ch. 7.6 - Give the four quantum numbers for each of the two...Ch. 7.7 - Give the values of the quantum numbers associated...Ch. 7.7 - What is the total number of orbitals associated...Ch. 7.7 - Why is it not possible to have a 2d orbital, but a...Ch. 7.8 - Write the four quantum numbers for an electron in...Ch. 7.8 - Prob. 10PE Ch. 7.8 - Write a complete set of quantum numbers for each...Ch. 7.8 - The ground-state electron configuration of an atom...Ch. 7.9 - Prob. 12PE Ch. 7.9 - Identify the element that has the following...Ch. 7 - What is a wave? 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Explain the...Ch. 7 - Prob. 7.24QP Ch. 7 - Explain why elements produce their own...Ch. 7 - Prob. 7.26QP Ch. 7 - Prob. 7.27QP Ch. 7 - Explain how astronomers are able to tell which...Ch. 7 - Consider the following energy levels of a...Ch. 7 - Prob. 7.30QP Ch. 7 - Calculate the wavelength (in nm) of a photon...Ch. 7 - Calculate the frequency (Hz) and wavelength (nm)...Ch. 7 - Prob. 7.33QP Ch. 7 - An electron in the hydrogen atom makes a...Ch. 7 - Explain the statement, Matter and radiation have a...Ch. 7 - How does de Broglies hypothesis account for the...Ch. 7 - Why is Equation (7.8) meaningful only for...Ch. 7 - (a) If a H atom and a He atom are traveling at the...Ch. 7 - Prob. 7.39QP Ch. 7 - Protons can be accelerated to speeds near that of...Ch. 7 - What is the de Broglie wavelength, in centimeters,...Ch. 7 - What is the de Broglie wavelength (in nm)...Ch. 7 - What are the inadequacies of Bohrs theory?Ch. 7 - What is the Heisenberg uncertainty principle? 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Which...Ch. 7 - Which of the four quantum numbers (n, , m, ms)...Ch. 7 - Prob. 7.55QP Ch. 7 - An electron in an atom is in the n = 3 quantum...Ch. 7 - Give the values of the quantum numbers associated...Ch. 7 - Give the values of the four quantum numbers of an...Ch. 7 - Prob. 7.59QP Ch. 7 - What is the difference between a 2px and a 2py...Ch. 7 - Prob. 7.61QP Ch. 7 - List all the possible subshells and orbitals...Ch. 7 - Calculate the total number of electrons that can...Ch. 7 - Prob. 7.64QP Ch. 7 - Prob. 7.65QP Ch. 7 - Indicate the total number of (a) p electrons in N...Ch. 7 - Make a chart of all allowable orbitals in the...Ch. 7 - Why do the 3s, 3p, and 3d orbitals have the same...Ch. 7 - For each of the following pairs of hydrogen...Ch. 7 - Which orbital in each of the following pairs is...Ch. 7 - What is electron configuration? Describe the roles...Ch. 7 - Prob. 7.72QP Ch. 7 - Prob. 7.73QP Ch. 7 - What is meant by the term shielding of electrons...Ch. 7 - Indicate which of the following sets of quantum...Ch. 7 - The ground-state electron configurations listed...Ch. 7 - The atomic number of an element is 73. Is this...Ch. 7 - Indicate the number of unpaired electrons present...Ch. 7 - State the Aufbau principle and explain the role it...Ch. 7 - Prob. 7.80QP Ch. 7 - What is the noble gas core? How does it simplify...Ch. 7 - What are the group and period of the element...Ch. 7 - Prob. 7.83QP Ch. 7 - Explain why the ground-state electron...Ch. 7 - Prob. 7.85QP Ch. 7 - Comment on the correctness of the following...Ch. 7 - Prob. 7.87QP Ch. 7 - Use the Aufbau principle to obtain the...Ch. 7 - Prob. 7.89QP Ch. 7 - Prob. 7.90QP Ch. 7 - The electron configuration of a neutral atom is...Ch. 7 - Which of the following species has the most...Ch. 7 - A sample tube consisted of atomic hydrogens in...Ch. 7 - A laser produces a beam of light with a wavelength...Ch. 7 - When a compound containing cesium ion is heated in...Ch. 7 - Prob. 7.96QP Ch. 7 - Prob. 7.97QP Ch. 7 - Prob. 7.98QP Ch. 7 - Identify the following individuals and their...Ch. 7 - What properties of electrons are used in the...Ch. 7 - A certain pitchers fastballs have been clocked at...Ch. 7 - A student carried out a photoelectric experiment...Ch. 7 - (a) What is the lowest possible value of the...Ch. 7 - Considering only the ground-state electron...Ch. 7 - A ruby laser produces radiation of wavelength 633...Ch. 7 - A 368-g sample of water absorbs infrared radiation...Ch. 7 - Photodissociation of water H2O(l)+hvH2(g)+12O2(g)...Ch. 7 - Prob. 7.109QP Ch. 7 - An atom moving at its root-mean-square speed at...Ch. 7 - Prob. 7.111QP Ch. 7 - The He+ ion contains only one electron and is...Ch. 7 - Ozone (O3) in the stratosphere absorbs the harmful...Ch. 7 - The retina of a human eye can detect light when...Ch. 7 - A helium atom and a xenon atom have the same...Ch. 7 - Prob. 7.116QP Ch. 7 - Prob. 7.117QP Ch. 7 - A photoelectric experiment was performed by...Ch. 7 - Draw the shapes (boundary surfaces) of the...Ch. 7 - The electron configurations described in this...Ch. 7 - Draw orbital diagrams for atoms with the following...Ch. 7 - Prob. 7.122QP Ch. 7 - Scientists have found interstellar hydrogen atoms...Ch. 7 - Prob. 7.124QP Ch. 7 - Ionization energy is the minimum energy required...Ch. 7 - An electron in a hydrogen atom is excited from the...Ch. 7 - Prob. 7.127QP Ch. 7 - Prob. 7.128QP Ch. 7 - Prob. 7.129QP Ch. 7 - Shown are portions of orbital diagrams...Ch. 7 - The UV light that is responsible for tanning the...Ch. 7 - The sun is surrounded by a white circle of gaseous...Ch. 7 - Prob. 7.133QP Ch. 7 - Prob. 7.134QP Ch. 7 - Prob. 7.135QP Ch. 7 - In an electron microscope, electrons are...Ch. 7 - Prob. 7.137QP Ch. 7 - The radioactive Co-60 isotope is used in nuclear...Ch. 7 - (a) An electron in the ground state of the...Ch. 7 - One wavelength in the hydrogen emission spectrum...Ch. 7 - Owls have good night vision because their eyes can...Ch. 7 - For hydrogenlike ions, that is, ions containing...Ch. 7 - When two atoms collide, some of their kinetic...Ch. 7 - Calculate the energies needed to remove an...Ch. 7 - The de Broglie wavelength of an accelerating...Ch. 7 - The minimum uncertainty in the position of a...Ch. 7 - According to Einsteins special theory of...Ch. 7 - The mathematical equation for studying the...Ch. 7 - In the beginning of the twentieth century, some...Ch. 7 - Blackbody radiation is the term used to describe...Ch. 7 - Prob. 7.151QP Ch. 7 - The wave function for the 2s orbital in the...Ch. 7 - A student placed a large unwrapped chocolate bar...Ch. 7 - The wave properties of matter can generally be...Ch. 7 - Atoms of an element have only two accessible...Ch. 7 - Prob. 7.156IME Ch. 7 - Only a fraction of the electrical energy supplied...Ch. 7 - Prob. 7.158IME Ch. 7 - A typical red laser pointer has a power of 5 mW....Ch. 7 - Referring to the Chemistry in Action essay Quantum...

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Solution Summary: The author explains that the wavelength of the given radiation should be identified using the relation between speed, wavelength and frequency of a wave.

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