The configuration of the chiral center must be assigned to the substrate. Concept Introduction : The absolute configuration of a chiral center depends on the nature of substituents. The absolute configuration is determined using CIP (Cahn-Ingold-Prelog) priority rule according to which priority of a group is higher if the atomic number is higher.

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Answer 1

Question

Chapter 7, Problem 53PP

(a)

Interpretation Introduction

Interpretation:

The configuration of the chiral center must be assigned to the substrate.

Concept Introduction :

The absolute configuration of a chiral center depends on the nature of substituents. The absolute configuration is determined using CIP (Cahn-Ingold-Prelog) priority rule according to which priority of a group is higher if the atomic number is higher.

(b)

Interpretation Introduction

Interpretation:

The configuration of the chiral center must be assigned in the product.

Concept Introduction :

The absolute configuration of a chiral center depends on the nature of substituents. The absolute configuration is determined using CIP (Cahn-Ingold-Prelog) priority rule according to which priority of a group is higher if atomic number is higher.

(c)

Interpretation Introduction

Interpretation:

Whether the given S_N2 reaction proceeds with inversion of configuration must be explained.

Concept Introduction :

The S_N2 reaction involves back side attack of the nucleophile which results in inversion of configuration.

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MISSED THIS? Read Section 19.9 (Pages 878-881); Watch IWE 19.10 Consider the following reaction: CH3OH(g) CO(g) + 2H2(g) (Note that AG,CH3OH(g) = -162.3 kJ/mol and AG,co(g)=-137.2 kJ/mol.) Part A Calculate AG for this reaction at 25 °C under the following conditions: PCH₂OH Pco PH2 0.815 atm = 0.140 atm 0.170 atm Express your answer in kilojoules to three significant figures. Ο ΑΣΦ AG = -150 Submit Previous Answers Request Answer □? kJ × Incorrect; Try Again; 2 attempts remaining Calculate the free energy change under nonstandard conditions (AGrxn) by using the following relationship: AGrxn = AGrxn + RTInQ, AGxn+RTInQ, where AGxn is the standard free energy change, R is the ideal gas constant, T is the temperature in kelvins, a is the reaction quotient. Provide Feedback Next >

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Answer 2

Question

Chapter 7, Problem 53PP

(a)

Interpretation Introduction

Interpretation:

The configuration of the chiral center must be assigned to the substrate.

Concept Introduction :

The absolute configuration of a chiral center depends on the nature of substituents. The absolute configuration is determined using CIP (Cahn-Ingold-Prelog) priority rule according to which priority of a group is higher if the atomic number is higher.

(b)

Interpretation Introduction

Interpretation:

The configuration of the chiral center must be assigned in the product.

Concept Introduction :

The absolute configuration of a chiral center depends on the nature of substituents. The absolute configuration is determined using CIP (Cahn-Ingold-Prelog) priority rule according to which priority of a group is higher if atomic number is higher.

(c)

Interpretation Introduction

Interpretation:

Whether the given S_N2 reaction proceeds with inversion of configuration must be explained.

Concept Introduction :

The S_N2 reaction involves back side attack of the nucleophile which results in inversion of configuration.

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Answer 3

Question

Chapter 7, Problem 53PP

(a)

Interpretation Introduction

Interpretation:

The configuration of the chiral center must be assigned to the substrate.

Concept Introduction :

The absolute configuration of a chiral center depends on the nature of substituents. The absolute configuration is determined using CIP (Cahn-Ingold-Prelog) priority rule according to which priority of a group is higher if the atomic number is higher.

(b)

Interpretation Introduction

Interpretation:

The configuration of the chiral center must be assigned in the product.

Concept Introduction :

The absolute configuration of a chiral center depends on the nature of substituents. The absolute configuration is determined using CIP (Cahn-Ingold-Prelog) priority rule according to which priority of a group is higher if atomic number is higher.

(c)

Interpretation Introduction

Interpretation:

Whether the given S_N2 reaction proceeds with inversion of configuration must be explained.

Concept Introduction :

The S_N2 reaction involves back side attack of the nucleophile which results in inversion of configuration.

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Answer 4

Question

Chapter 7, Problem 53PP

(a)

Interpretation Introduction

Interpretation:

The configuration of the chiral center must be assigned to the substrate.

Concept Introduction :

The absolute configuration of a chiral center depends on the nature of substituents. The absolute configuration is determined using CIP (Cahn-Ingold-Prelog) priority rule according to which priority of a group is higher if the atomic number is higher.

(b)

Interpretation Introduction

Interpretation:

The configuration of the chiral center must be assigned in the product.

Concept Introduction :

The absolute configuration of a chiral center depends on the nature of substituents. The absolute configuration is determined using CIP (Cahn-Ingold-Prelog) priority rule according to which priority of a group is higher if atomic number is higher.

(c)

Interpretation Introduction

Interpretation:

Whether the given S_N2 reaction proceeds with inversion of configuration must be explained.

Concept Introduction :

The S_N2 reaction involves back side attack of the nucleophile which results in inversion of configuration.

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Answer 5

Chapter 7, Problem 53PP

(a)

Interpretation Introduction

Interpretation:

The configuration of the chiral center must be assigned to the substrate.

Concept Introduction :

The absolute configuration of a chiral center depends on the nature of substituents. The absolute configuration is determined using CIP (Cahn-Ingold-Prelog) priority rule according to which priority of a group is higher if the atomic number is higher.

(b)

Interpretation Introduction

Interpretation:

The configuration of the chiral center must be assigned in the product.

Concept Introduction :

The absolute configuration of a chiral center depends on the nature of substituents. The absolute configuration is determined using CIP (Cahn-Ingold-Prelog) priority rule according to which priority of a group is higher if atomic number is higher.

(c)

Interpretation Introduction

Interpretation:

Whether the given S_N2 reaction proceeds with inversion of configuration must be explained.

Concept Introduction :

The S_N2 reaction involves back side attack of the nucleophile which results in inversion of configuration.

Answer 6

Chapter 7, Problem 53PP

(a)

Interpretation Introduction

Interpretation:

The configuration of the chiral center must be assigned to the substrate.

Concept Introduction :

The absolute configuration of a chiral center depends on the nature of substituents. The absolute configuration is determined using CIP (Cahn-Ingold-Prelog) priority rule according to which priority of a group is higher if the atomic number is higher.

Answer 7

Chapter 7, Problem 53PP

(a)

Interpretation Introduction

Interpretation:

The configuration of the chiral center must be assigned to the substrate.

Concept Introduction :

The absolute configuration of a chiral center depends on the nature of substituents. The absolute configuration is determined using CIP (Cahn-Ingold-Prelog) priority rule according to which priority of a group is higher if the atomic number is higher.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The configuration of the chiral center must be assigned in the product.

Concept Introduction :

The absolute configuration of a chiral center depends on the nature of substituents. The absolute configuration is determined using CIP (Cahn-Ingold-Prelog) priority rule according to which priority of a group is higher if atomic number is higher.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The configuration of the chiral center must be assigned in the product.

Concept Introduction :

The absolute configuration of a chiral center depends on the nature of substituents. The absolute configuration is determined using CIP (Cahn-Ingold-Prelog) priority rule according to which priority of a group is higher if atomic number is higher.

Answer 10

(c)

Interpretation Introduction

Interpretation:

Whether the given S_N2 reaction proceeds with inversion of configuration must be explained.

Concept Introduction :

The S_N2 reaction involves back side attack of the nucleophile which results in inversion of configuration.

Answer 11

(c)

Interpretation Introduction

Interpretation:

Whether the given S_N2 reaction proceeds with inversion of configuration must be explained.

Concept Introduction :

The S_N2 reaction involves back side attack of the nucleophile which results in inversion of configuration.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 7.2 - Prob. 1CC Ch. 7.3 - Prob. 2CC Ch. 7.3 - Prob. 1LTS Ch. 7.3 - Prob. 3PTS Ch. 7.3 - Prob. 4ATS Ch. 7.3 - Prob. 2LTS Ch. 7.3 - Prob. 5PTS Ch. 7.3 - Prob. 6ATS Ch. 7.3 - Prob. 7CC Ch. 7.4 - Prob. 8CC

Solution Summary: The author explains that the absolute configuration of a chiral center depends on the nature of substituents.

Interpretation:

Whether the given S_N2 reaction proceeds with inversion of configuration must be explained.

Concept Introduction :

The S_N2 reaction involves back side attack of the nucleophile which results in inversion of configuration.

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Chapter 7 Solutions

Solution Summary: The author explains that the absolute configuration of a chiral center depends on the nature of substituents.

Interpretation: Whether the given SN2 reaction proceeds with inversion of configuration must be explained. Concept Introduction : The SN2 reaction involves back side attack of the nucleophile which results in inversion of configuration.

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Chapter 7 Solutions

Interpretation:

Whether the given S_N2 reaction proceeds with inversion of configuration must be explained.

Concept Introduction :

The S_N2 reaction involves back side attack of the nucleophile which results in inversion of configuration.