INTRODUCTION TO CHEMISTRY(LL)-W/CONNECT
5th Edition
ISBN: 9781260264920
Author: BAUER
Publisher: MCG
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Chapter 7, Problem 46QP
Complete the following orbital diagrams for the ground- state electron arrangement for aluminum, chlorine, and sulfur. Be sure the follow the three orbital filling rules: the aufbau principle, the pauli exclusion principal, and Hud’s rule.
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206 Pb
82
Express your answers as integers. Enter your answers separated by a comma.
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VAΣ
ΜΕ ΑΣΦ
Np, N₁ = 82,126
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?
protons, neutrons
Please draw the inverted chair forms of the products for the two equilibrium reactions
shown below. Circle the equilibrium reaction that would have a AG = 0, i.e., the relative energy of
the reactant (to the left of the equilibrium arrows) equals the relative energy of the product? [No
requirement to show or do calculations.]
CH3
CH3
HH
CH3
1
-CH3
5.
Please consider the Newman projection of tartaric acid drawn below as an eclipsed
conformer (1). Please draw the most stable conformer and two intermediate energy conformers
noting that staggered conformers are lower in energy than eclipsed forms even if the staggered
conformers have gauche relationships between groups. [Draw the substituents H and OH on the front
carbons and H, OH and CO₂H on the back carbons based on staggered forms. -CO₂H is larger than -OH.]
OH
COH
ICOOH
COOH
COOH
1
2
COOH
COOH
3
4
Staggered
Staggered
Staggered (most stable)
Indicate the number of each conformer above (1, 2, 3 and 4) that corresponds to the relative energies
below.
Ref=0
Rotation
6. (60 points)
a. Are compounds 1 and 2 below enantiomers, diastereomers or identical?
OH
OH
HO
HO
LOH
HO
HO
OH
2
OH
OH
b. Please complete the zig-zag conformation of the compound
(3R,4S)-3,4-dichloro-2,5-dimethylhexane by writing the respective atoms in the boxes.
3.
Chapter 7 Solutions
INTRODUCTION TO CHEMISTRY(LL)-W/CONNECT
Ch. 7 - Prob. 1QCCh. 7 - Prob. 2QCCh. 7 - Prob. 3QCCh. 7 - Prob. 4QCCh. 7 - Prob. 5QCCh. 7 - Prob. 6QCCh. 7 - Prob. 7QCCh. 7 - Prob. 1PPCh. 7 - Prob. 2PPCh. 7 - Prob. 3PP
Ch. 7 - Prob. 4PPCh. 7 - Prob. 5PPCh. 7 - Prob. 6PPCh. 7 - Prob. 7PPCh. 7 - Prob. 8PPCh. 7 - Prob. 9PPCh. 7 - Prob. 10PPCh. 7 - Prob. 11PPCh. 7 - Prob. 1QPCh. 7 - Match the key terms with the descriptions...Ch. 7 - Prob. 3QPCh. 7 - Prob. 4QPCh. 7 - Prob. 5QPCh. 7 - Prob. 6QPCh. 7 - Prob. 7QPCh. 7 - Prob. 8QPCh. 7 - Prob. 9QPCh. 7 - Prob. 10QPCh. 7 - Prob. 11QPCh. 7 - Prob. 12QPCh. 7 - Prob. 13QPCh. 7 - Prob. 14QPCh. 7 - Prob. 15QPCh. 7 - Prob. 16QPCh. 7 - Prob. 17QPCh. 7 - Prob. 18QPCh. 7 - Prob. 19QPCh. 7 - Prob. 20QPCh. 7 - Prob. 21QPCh. 7 - Prob. 22QPCh. 7 - Bohr proposed that the electron in a hydrogen atom...Ch. 7 - Prob. 24QPCh. 7 - Prob. 25QPCh. 7 - Prob. 26QPCh. 7 - Prob. 27QPCh. 7 - Prob. 28QPCh. 7 - Prob. 29QPCh. 7 - Prob. 30QPCh. 7 - Prob. 31QPCh. 7 - In the Bohr model, which of the following electron...Ch. 7 - Prob. 33QPCh. 7 - Prob. 34QPCh. 7 - Prob. 35QPCh. 7 - Prob. 36QPCh. 7 - Prob. 37QPCh. 7 - Prob. 38QPCh. 7 - Prob. 39QPCh. 7 - Prob. 40QPCh. 7 - Prob. 41QPCh. 7 - Prob. 42QPCh. 7 - Prob. 43QPCh. 7 - Prob. 44QPCh. 7 - Prob. 45QPCh. 7 - Complete the following orbital diagrams for the...Ch. 7 - Prob. 47QPCh. 7 - Prob. 48QPCh. 7 - Prob. 49QPCh. 7 - Prob. 50QPCh. 7 - Prob. 51QPCh. 7 - Prob. 52QPCh. 7 - Prob. 53QPCh. 7 - Prob. 54QPCh. 7 - Prob. 55QPCh. 7 - Prob. 56QPCh. 7 - Prob. 57QPCh. 7 - Prob. 58QPCh. 7 - Prob. 59QPCh. 7 - Prob. 60QPCh. 7 - Prob. 61QPCh. 7 - Prob. 62QPCh. 7 - Prob. 63QPCh. 7 - Prob. 64QPCh. 7 - Prob. 65QPCh. 7 - Prob. 66QPCh. 7 - Prob. 67QPCh. 7 - Prob. 68QPCh. 7 - Prob. 69QPCh. 7 - Prob. 70QPCh. 7 - Prob. 71QPCh. 7 - Prob. 72QPCh. 7 - Prob. 73QPCh. 7 - Prob. 74QPCh. 7 - Prob. 75QPCh. 7 - Prob. 76QPCh. 7 - Prob. 77QPCh. 7 - Prob. 78QPCh. 7 - Prob. 79QPCh. 7 - Prob. 80QPCh. 7 - Prob. 81QPCh. 7 - Write the complete and abbreviated electron...Ch. 7 - Prob. 83QPCh. 7 - Prob. 84QPCh. 7 - Prob. 85QPCh. 7 - Prob. 86QPCh. 7 - Prob. 87QPCh. 7 - Prob. 88QPCh. 7 - Prob. 89QPCh. 7 - Prob. 90QPCh. 7 - Prob. 91QPCh. 7 - Prob. 92QPCh. 7 - Prob. 93QPCh. 7 - Prob. 94QPCh. 7 - Prob. 95QPCh. 7 - Prob. 96QPCh. 7 - Prob. 97QPCh. 7 - Prob. 98QPCh. 7 - Prob. 99QPCh. 7 - Prob. 100QPCh. 7 - Prob. 101QPCh. 7 - Prob. 102QPCh. 7 - Prob. 103QPCh. 7 - Prob. 104QPCh. 7 - Prob. 105QPCh. 7 - Prob. 106QPCh. 7 - Which is the larger ion, K+orCa2+? Explain.Ch. 7 - Prob. 108QPCh. 7 - Prob. 109QPCh. 7 - Prob. 110QPCh. 7 - Prob. 111QPCh. 7 - Prob. 112QPCh. 7 - Prob. 113QPCh. 7 - Prob. 114QPCh. 7 - Prob. 115QPCh. 7 - Prob. 116QPCh. 7 - Prob. 117QPCh. 7 - Prob. 118QPCh. 7 - Prob. 119QPCh. 7 - Prob. 120QPCh. 7 - Prob. 121QPCh. 7 - Prob. 122QPCh. 7 - Prob. 123QPCh. 7 - Prob. 124QPCh. 7 - Prob. 125QPCh. 7 - Prob. 126QPCh. 7 - Prob. 127QPCh. 7 - Prob. 128QPCh. 7 - Prob. 129QPCh. 7 - Prob. 130QPCh. 7 - Prob. 131QPCh. 7 - Prob. 132QPCh. 7 - Prob. 133QPCh. 7 - How many unpaired electrons are in a single atom...Ch. 7 - Prob. 135QPCh. 7 - Which element has a ground-state electron...Ch. 7 - Which of the following is the correct abbreviated...Ch. 7 - Prob. 138QPCh. 7 - Prob. 139QPCh. 7 - Prob. 140QPCh. 7 - Prob. 141QPCh. 7 - Prob. 142QP
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