INTRODUCTION TO CHEMISTRY(LL)-W/CONNECT
INTRODUCTION TO CHEMISTRY(LL)-W/CONNECT
5th Edition
ISBN: 9781260264920
Author: BAUER
Publisher: MCG
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Chapter 7, Problem 91QP
Interpretation Introduction

Interpretation:

The given statement, “More energy is required to remove an electron from a lithium atom than from a sodium atom� is to be interpreted on the basis of their electronic configuration.

Concept Introduction:

The minimum amount of energy required to remove the most loosely bound electron from an isolated gaseous atom so as to convert it into gaseous cation is called ionization energy.

Ionization energy increases across the period, as across the group electron starts getting added which increases the effective nuclear charge on the last electron. Hence, a large amount of energy is required to remove the electron.

Ionization energy decreases down the group, as down the group a new shell is getting added which increases the distance of the last electron from the nucleus. Hence, a low amount of energy is required to remove the electron.

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2. Predict the NMR spectra for each of these two compounds by listing, in the NMR tables below, the chemical shift, the splitting, and the number of hydrogens associated with each predicted peak. Sort the peaks from largest chemical shift to lowest. **Not all slots must be filled** Peak Chemical Shift (d) 5.7 1 Multiplicity multiplate .......... 5.04 double of doublet 2 4.98 double of doublet 3 4.05 doublet of quartet 4 5 LO 3.80 quartet 1.3 doublet 6 Peak Chemical Shift (d) Multiplicity
Interpreting NMR spectra is a skill that often requires some amount of practice, which, in turn, necessitates access to a collection of NMR spectra. Beyond Labz Organic Synthesis and Organic Qualitative Analysis have spectral libraries containing over 700 1H NMR spectra. In this assignment, you will take advantage of this by first predicting the NMR spectra for two closely related compounds and then checking your predictions by looking up the actual spectra in the spectra library. After completing this assignment, you may wish to select other compounds for additional practice. 1. Write the IUPAC names for the following two structures: Question 2 Question 3 2. Predict the NMR spectra for each of these two compounds by listing, in the NMR tables below, the chemical shift, the splitting, and the number of hydrogens associated with each predicted peak. Sort the peaks from largest chemical shift to lowest. **Not all slots must be filled**
11:14 ... worksheets.beyondlabz.com 3. To check your predictions, click this link for Interpreting NMR Spectra 1. You will see a list of all the - compounds in the spectra library in alphabetical order by IUPAC name. Hovering over a name in the list will show the structure on the chalkboard. The four buttons on the top of the Spectra tab in the tray are used to select the different spectroscopic techniques for the selected compound. Make sure the NMR button has been selected. 4. Scroll through the list of names to find the names for the two compounds you have been given and click on the name to display the NMR spectrum for each. In the NMR tables below, list the chemical shift, the splitting, and the number of hydrogens associated with each peak for each compound. Compare your answers to your predictions. **Not all slots must be filled** Peak Chemical Shift (d) Multiplicity 1 2 3 4 5

Chapter 7 Solutions

INTRODUCTION TO CHEMISTRY(LL)-W/CONNECT

Ch. 7 - Prob. 4PPCh. 7 - Prob. 5PPCh. 7 - Prob. 6PPCh. 7 - Prob. 7PPCh. 7 - Prob. 8PPCh. 7 - Prob. 9PPCh. 7 - Prob. 10PPCh. 7 - Prob. 11PPCh. 7 - Prob. 1QPCh. 7 - Match the key terms with the descriptions...Ch. 7 - Prob. 3QPCh. 7 - Prob. 4QPCh. 7 - Prob. 5QPCh. 7 - Prob. 6QPCh. 7 - Prob. 7QPCh. 7 - Prob. 8QPCh. 7 - Prob. 9QPCh. 7 - Prob. 10QPCh. 7 - Prob. 11QPCh. 7 - Prob. 12QPCh. 7 - Prob. 13QPCh. 7 - Prob. 14QPCh. 7 - Prob. 15QPCh. 7 - Prob. 16QPCh. 7 - Prob. 17QPCh. 7 - Prob. 18QPCh. 7 - Prob. 19QPCh. 7 - Prob. 20QPCh. 7 - Prob. 21QPCh. 7 - Prob. 22QPCh. 7 - Bohr proposed that the electron in a hydrogen atom...Ch. 7 - Prob. 24QPCh. 7 - Prob. 25QPCh. 7 - Prob. 26QPCh. 7 - Prob. 27QPCh. 7 - Prob. 28QPCh. 7 - Prob. 29QPCh. 7 - Prob. 30QPCh. 7 - Prob. 31QPCh. 7 - In the Bohr model, which of the following electron...Ch. 7 - Prob. 33QPCh. 7 - Prob. 34QPCh. 7 - Prob. 35QPCh. 7 - Prob. 36QPCh. 7 - Prob. 37QPCh. 7 - Prob. 38QPCh. 7 - Prob. 39QPCh. 7 - Prob. 40QPCh. 7 - Prob. 41QPCh. 7 - Prob. 42QPCh. 7 - Prob. 43QPCh. 7 - Prob. 44QPCh. 7 - Prob. 45QPCh. 7 - Complete the following orbital diagrams for the...Ch. 7 - Prob. 47QPCh. 7 - Prob. 48QPCh. 7 - Prob. 49QPCh. 7 - Prob. 50QPCh. 7 - Prob. 51QPCh. 7 - Prob. 52QPCh. 7 - Prob. 53QPCh. 7 - Prob. 54QPCh. 7 - Prob. 55QPCh. 7 - Prob. 56QPCh. 7 - Prob. 57QPCh. 7 - Prob. 58QPCh. 7 - Prob. 59QPCh. 7 - Prob. 60QPCh. 7 - Prob. 61QPCh. 7 - Prob. 62QPCh. 7 - Prob. 63QPCh. 7 - Prob. 64QPCh. 7 - Prob. 65QPCh. 7 - Prob. 66QPCh. 7 - Prob. 67QPCh. 7 - Prob. 68QPCh. 7 - Prob. 69QPCh. 7 - Prob. 70QPCh. 7 - Prob. 71QPCh. 7 - Prob. 72QPCh. 7 - Prob. 73QPCh. 7 - Prob. 74QPCh. 7 - Prob. 75QPCh. 7 - Prob. 76QPCh. 7 - Prob. 77QPCh. 7 - Prob. 78QPCh. 7 - Prob. 79QPCh. 7 - Prob. 80QPCh. 7 - Prob. 81QPCh. 7 - Write the complete and abbreviated electron...Ch. 7 - Prob. 83QPCh. 7 - Prob. 84QPCh. 7 - Prob. 85QPCh. 7 - Prob. 86QPCh. 7 - Prob. 87QPCh. 7 - Prob. 88QPCh. 7 - Prob. 89QPCh. 7 - Prob. 90QPCh. 7 - Prob. 91QPCh. 7 - Prob. 92QPCh. 7 - Prob. 93QPCh. 7 - Prob. 94QPCh. 7 - Prob. 95QPCh. 7 - Prob. 96QPCh. 7 - Prob. 97QPCh. 7 - Prob. 98QPCh. 7 - Prob. 99QPCh. 7 - Prob. 100QPCh. 7 - Prob. 101QPCh. 7 - Prob. 102QPCh. 7 - Prob. 103QPCh. 7 - Prob. 104QPCh. 7 - Prob. 105QPCh. 7 - Prob. 106QPCh. 7 - Which is the larger ion, K+orCa2+? Explain.Ch. 7 - Prob. 108QPCh. 7 - Prob. 109QPCh. 7 - Prob. 110QPCh. 7 - Prob. 111QPCh. 7 - Prob. 112QPCh. 7 - Prob. 113QPCh. 7 - Prob. 114QPCh. 7 - Prob. 115QPCh. 7 - Prob. 116QPCh. 7 - Prob. 117QPCh. 7 - Prob. 118QPCh. 7 - Prob. 119QPCh. 7 - Prob. 120QPCh. 7 - Prob. 121QPCh. 7 - Prob. 122QPCh. 7 - Prob. 123QPCh. 7 - Prob. 124QPCh. 7 - Prob. 125QPCh. 7 - Prob. 126QPCh. 7 - Prob. 127QPCh. 7 - Prob. 128QPCh. 7 - Prob. 129QPCh. 7 - Prob. 130QPCh. 7 - Prob. 131QPCh. 7 - Prob. 132QPCh. 7 - Prob. 133QPCh. 7 - How many unpaired electrons are in a single atom...Ch. 7 - Prob. 135QPCh. 7 - Which element has a ground-state electron...Ch. 7 - Which of the following is the correct abbreviated...Ch. 7 - Prob. 138QPCh. 7 - Prob. 139QPCh. 7 - Prob. 140QPCh. 7 - Prob. 141QPCh. 7 - Prob. 142QP
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