Synthesis method of the given compound has to be given from the compound which have the same number of carbon atoms. Concept Introduction: Addition of water to alkynes in presence of acid: Under acidic conditions, alkyne reacts with water to produce an enol which then immediately converts into ketone . For terminal alkynes, there is a need of catalyst which is mercury. The formed enol and ketone are called keto-enol tautomers. Tautomerization: It is the process of inter conversion of tautomers and therefore the process can also be called as keto-enol tautomerization. Hydroboration reaction: It is the reaction in which an internal alkyne is converted into ketone. The reagents used for the hydroboration oxidation reaction is either BH 3 or R 2 BH .

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Answer 1

Question

Chapter 7, Problem 37P

(a)

Interpretation Introduction

Interpretation:

Synthesis method of the given compound has to be given from the compound which have the same number of carbon atoms.

Concept Introduction:

Addition of water to alkynes in presence of acid:

Under acidic conditions, alkyne reacts with water to produce an enol which then immediately converts into ketone. For terminal alkynes, there is a need of catalyst which is mercury.

The formed enol and ketone are called keto-enol tautomers.

Tautomerization: It is the process of inter conversion of tautomers and therefore the process can also be called as keto-enol tautomerization.

Hydroboration reaction:

It is the reaction in which an internal alkyne is converted into ketone. The reagents used for the hydroboration oxidation reaction is either BH3 or R2BH.

(b)

Interpretation Introduction

Interpretation:

Synthesis method of the given compound has to be given from the compound which have the same number of carbon atoms.

Concept Introduction:

Addition of water to alkynes in presence of acid:

Under acidic conditions, alkyne reacts with water to produce an enol which then immediately converts into ketone. For terminal alkynes, there is a need of catalyst which is mercury.

The formed enol and ketone are called keto-enol tautomers.

Tautomerization: It is the process of inter conversion of tautomers and therefore the process can also be called as keto-enol tautomerization.

Hydroboration reaction:

It is the reaction in which an internal alkyne is converted into ketone. The reagents used for the hydroboration oxidation reaction is either BH3 or R2BH.

(c)

Interpretation Introduction

Interpretation:

Synthesis method of the given compound has to be given from the compound which have the same number of carbon atoms.

Concept Introduction:

Addition of water to alkynes in presence of acid:

Under acidic conditions, alkyne reacts with water to produce an enol which then immediately converts into ketone. For terminal alkynes, there is a need of catalyst which is mercury.

The formed enol and ketone are called keto-enol tautomers.

Tautomerization: It is the process of inter conversion of tautomers and therefore the process can also be called as keto-enol tautomerization.

Hydroboration reaction:

It is the reaction in which an internal alkyne is converted into ketone. The reagents used for the hydroboration oxidation reaction is either BH3 or R2BH.

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a) Draw the octahedral mer-[FeCl3(CN)3] complex and determine its point group. Use proper wedges and dashes in order to illustrate 3 dimensional details. Use the point group to determine if the complex has a resulting net dipole moment and describe its allowed direction with respect to its symmetry elements (if applicable). ード M 4- b) Substitute one chlorido ligand in mer-[FeCl3(CN)3] 4 with one fluorido ligand. Determine all possible isomers and their corresponding point groups. Use the point groups to determine if the complexes have resulting net dipole moments and describe their allowed direction with respect to its symmetry elements (if applicable). The number of complex sketches below is not necessarily indicative of the number of isomers. 4- 4- ☐☐☐ c) Substitute two chlorido ligands in mer-[FeCl3 (CN)3] 4 with two fluorido ligands. Determine all possible isomers and their corresponding point groups.. Use the point groups to determine if the complexes have resulting net dipole…

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Differentiate electron spin and electron spin moment.

Answer 2

Question

Chapter 7, Problem 37P

(a)

Interpretation Introduction

Interpretation:

Synthesis method of the given compound has to be given from the compound which have the same number of carbon atoms.

Concept Introduction:

Addition of water to alkynes in presence of acid:

Under acidic conditions, alkyne reacts with water to produce an enol which then immediately converts into ketone. For terminal alkynes, there is a need of catalyst which is mercury.

The formed enol and ketone are called keto-enol tautomers.

Tautomerization: It is the process of inter conversion of tautomers and therefore the process can also be called as keto-enol tautomerization.

Hydroboration reaction:

It is the reaction in which an internal alkyne is converted into ketone. The reagents used for the hydroboration oxidation reaction is either BH3 or R2BH.

(b)

Interpretation Introduction

Interpretation:

Synthesis method of the given compound has to be given from the compound which have the same number of carbon atoms.

Concept Introduction:

Addition of water to alkynes in presence of acid:

Under acidic conditions, alkyne reacts with water to produce an enol which then immediately converts into ketone. For terminal alkynes, there is a need of catalyst which is mercury.

The formed enol and ketone are called keto-enol tautomers.

Tautomerization: It is the process of inter conversion of tautomers and therefore the process can also be called as keto-enol tautomerization.

Hydroboration reaction:

It is the reaction in which an internal alkyne is converted into ketone. The reagents used for the hydroboration oxidation reaction is either BH3 or R2BH.

(c)

Interpretation Introduction

Interpretation:

Synthesis method of the given compound has to be given from the compound which have the same number of carbon atoms.

Concept Introduction:

Addition of water to alkynes in presence of acid:

Under acidic conditions, alkyne reacts with water to produce an enol which then immediately converts into ketone. For terminal alkynes, there is a need of catalyst which is mercury.

The formed enol and ketone are called keto-enol tautomers.

Tautomerization: It is the process of inter conversion of tautomers and therefore the process can also be called as keto-enol tautomerization.

Hydroboration reaction:

It is the reaction in which an internal alkyne is converted into ketone. The reagents used for the hydroboration oxidation reaction is either BH3 or R2BH.

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Answer 3

Question

Chapter 7, Problem 37P

(a)

Interpretation Introduction

Interpretation:

Synthesis method of the given compound has to be given from the compound which have the same number of carbon atoms.

Concept Introduction:

Addition of water to alkynes in presence of acid:

Under acidic conditions, alkyne reacts with water to produce an enol which then immediately converts into ketone. For terminal alkynes, there is a need of catalyst which is mercury.

The formed enol and ketone are called keto-enol tautomers.

Tautomerization: It is the process of inter conversion of tautomers and therefore the process can also be called as keto-enol tautomerization.

Hydroboration reaction:

It is the reaction in which an internal alkyne is converted into ketone. The reagents used for the hydroboration oxidation reaction is either BH3 or R2BH.

(b)

Interpretation Introduction

Interpretation:

Synthesis method of the given compound has to be given from the compound which have the same number of carbon atoms.

Concept Introduction:

Addition of water to alkynes in presence of acid:

Under acidic conditions, alkyne reacts with water to produce an enol which then immediately converts into ketone. For terminal alkynes, there is a need of catalyst which is mercury.

The formed enol and ketone are called keto-enol tautomers.

Tautomerization: It is the process of inter conversion of tautomers and therefore the process can also be called as keto-enol tautomerization.

Hydroboration reaction:

It is the reaction in which an internal alkyne is converted into ketone. The reagents used for the hydroboration oxidation reaction is either BH3 or R2BH.

(c)

Interpretation Introduction

Interpretation:

Synthesis method of the given compound has to be given from the compound which have the same number of carbon atoms.

Concept Introduction:

Addition of water to alkynes in presence of acid:

Under acidic conditions, alkyne reacts with water to produce an enol which then immediately converts into ketone. For terminal alkynes, there is a need of catalyst which is mercury.

The formed enol and ketone are called keto-enol tautomers.

Tautomerization: It is the process of inter conversion of tautomers and therefore the process can also be called as keto-enol tautomerization.

Hydroboration reaction:

It is the reaction in which an internal alkyne is converted into ketone. The reagents used for the hydroboration oxidation reaction is either BH3 or R2BH.

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Answer 4

Question

Chapter 7, Problem 37P

(a)

Interpretation Introduction

Interpretation:

Synthesis method of the given compound has to be given from the compound which have the same number of carbon atoms.

Concept Introduction:

Addition of water to alkynes in presence of acid:

Under acidic conditions, alkyne reacts with water to produce an enol which then immediately converts into ketone. For terminal alkynes, there is a need of catalyst which is mercury.

The formed enol and ketone are called keto-enol tautomers.

Tautomerization: It is the process of inter conversion of tautomers and therefore the process can also be called as keto-enol tautomerization.

Hydroboration reaction:

It is the reaction in which an internal alkyne is converted into ketone. The reagents used for the hydroboration oxidation reaction is either BH3 or R2BH.

(b)

Interpretation Introduction

Interpretation:

Synthesis method of the given compound has to be given from the compound which have the same number of carbon atoms.

Concept Introduction:

Addition of water to alkynes in presence of acid:

Under acidic conditions, alkyne reacts with water to produce an enol which then immediately converts into ketone. For terminal alkynes, there is a need of catalyst which is mercury.

The formed enol and ketone are called keto-enol tautomers.

Tautomerization: It is the process of inter conversion of tautomers and therefore the process can also be called as keto-enol tautomerization.

Hydroboration reaction:

It is the reaction in which an internal alkyne is converted into ketone. The reagents used for the hydroboration oxidation reaction is either BH3 or R2BH.

(c)

Interpretation Introduction

Interpretation:

Synthesis method of the given compound has to be given from the compound which have the same number of carbon atoms.

Concept Introduction:

Addition of water to alkynes in presence of acid:

Under acidic conditions, alkyne reacts with water to produce an enol which then immediately converts into ketone. For terminal alkynes, there is a need of catalyst which is mercury.

The formed enol and ketone are called keto-enol tautomers.

Tautomerization: It is the process of inter conversion of tautomers and therefore the process can also be called as keto-enol tautomerization.

Hydroboration reaction:

It is the reaction in which an internal alkyne is converted into ketone. The reagents used for the hydroboration oxidation reaction is either BH3 or R2BH.

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Answer 5

Chapter 7, Problem 37P

(a)

Interpretation Introduction

Interpretation:

Synthesis method of the given compound has to be given from the compound which have the same number of carbon atoms.

Concept Introduction:

Addition of water to alkynes in presence of acid:

Under acidic conditions, alkyne reacts with water to produce an enol which then immediately converts into ketone. For terminal alkynes, there is a need of catalyst which is mercury.

The formed enol and ketone are called keto-enol tautomers.

Tautomerization: It is the process of inter conversion of tautomers and therefore the process can also be called as keto-enol tautomerization.

Hydroboration reaction:

It is the reaction in which an internal alkyne is converted into ketone. The reagents used for the hydroboration oxidation reaction is either BH3 or R2BH.

(b)

Interpretation Introduction

Interpretation:

Synthesis method of the given compound has to be given from the compound which have the same number of carbon atoms.

Concept Introduction:

Addition of water to alkynes in presence of acid:

Under acidic conditions, alkyne reacts with water to produce an enol which then immediately converts into ketone. For terminal alkynes, there is a need of catalyst which is mercury.

The formed enol and ketone are called keto-enol tautomers.

Tautomerization: It is the process of inter conversion of tautomers and therefore the process can also be called as keto-enol tautomerization.

Hydroboration reaction:

It is the reaction in which an internal alkyne is converted into ketone. The reagents used for the hydroboration oxidation reaction is either BH3 or R2BH.

(c)

Interpretation Introduction

Interpretation:

Synthesis method of the given compound has to be given from the compound which have the same number of carbon atoms.

Concept Introduction:

Addition of water to alkynes in presence of acid:

Under acidic conditions, alkyne reacts with water to produce an enol which then immediately converts into ketone. For terminal alkynes, there is a need of catalyst which is mercury.

The formed enol and ketone are called keto-enol tautomers.

Tautomerization: It is the process of inter conversion of tautomers and therefore the process can also be called as keto-enol tautomerization.

Hydroboration reaction:

It is the reaction in which an internal alkyne is converted into ketone. The reagents used for the hydroboration oxidation reaction is either BH3 or R2BH.

Answer 6

Chapter 7, Problem 37P

(a)

Interpretation Introduction

Interpretation:

Synthesis method of the given compound has to be given from the compound which have the same number of carbon atoms.

Concept Introduction:

Addition of water to alkynes in presence of acid:

Under acidic conditions, alkyne reacts with water to produce an enol which then immediately converts into ketone. For terminal alkynes, there is a need of catalyst which is mercury.

The formed enol and ketone are called keto-enol tautomers.

Tautomerization: It is the process of inter conversion of tautomers and therefore the process can also be called as keto-enol tautomerization.

Hydroboration reaction:

It is the reaction in which an internal alkyne is converted into ketone. The reagents used for the hydroboration oxidation reaction is either BH3 or R2BH.

Answer 7

Chapter 7, Problem 37P

(a)

Interpretation Introduction

Interpretation:

Synthesis method of the given compound has to be given from the compound which have the same number of carbon atoms.

Concept Introduction:

Addition of water to alkynes in presence of acid:

Under acidic conditions, alkyne reacts with water to produce an enol which then immediately converts into ketone. For terminal alkynes, there is a need of catalyst which is mercury.

The formed enol and ketone are called keto-enol tautomers.

Tautomerization: It is the process of inter conversion of tautomers and therefore the process can also be called as keto-enol tautomerization.

Hydroboration reaction:

It is the reaction in which an internal alkyne is converted into ketone. The reagents used for the hydroboration oxidation reaction is either BH3 or R2BH.

Answer 8

(b)

Interpretation Introduction

Interpretation:

Synthesis method of the given compound has to be given from the compound which have the same number of carbon atoms.

Concept Introduction:

Addition of water to alkynes in presence of acid:

Under acidic conditions, alkyne reacts with water to produce an enol which then immediately converts into ketone. For terminal alkynes, there is a need of catalyst which is mercury.

The formed enol and ketone are called keto-enol tautomers.

Tautomerization: It is the process of inter conversion of tautomers and therefore the process can also be called as keto-enol tautomerization.

Hydroboration reaction:

It is the reaction in which an internal alkyne is converted into ketone. The reagents used for the hydroboration oxidation reaction is either BH3 or R2BH.

Answer 9

(b)

Interpretation Introduction

Interpretation:

Synthesis method of the given compound has to be given from the compound which have the same number of carbon atoms.

Concept Introduction:

Addition of water to alkynes in presence of acid:

Under acidic conditions, alkyne reacts with water to produce an enol which then immediately converts into ketone. For terminal alkynes, there is a need of catalyst which is mercury.

The formed enol and ketone are called keto-enol tautomers.

Tautomerization: It is the process of inter conversion of tautomers and therefore the process can also be called as keto-enol tautomerization.

Hydroboration reaction:

It is the reaction in which an internal alkyne is converted into ketone. The reagents used for the hydroboration oxidation reaction is either BH3 or R2BH.

Answer 10

(c)

Interpretation Introduction

Interpretation:

Synthesis method of the given compound has to be given from the compound which have the same number of carbon atoms.

Concept Introduction:

Addition of water to alkynes in presence of acid:

Under acidic conditions, alkyne reacts with water to produce an enol which then immediately converts into ketone. For terminal alkynes, there is a need of catalyst which is mercury.

The formed enol and ketone are called keto-enol tautomers.

Tautomerization: It is the process of inter conversion of tautomers and therefore the process can also be called as keto-enol tautomerization.

Hydroboration reaction:

It is the reaction in which an internal alkyne is converted into ketone. The reagents used for the hydroboration oxidation reaction is either BH3 or R2BH.

Answer 11

(c)

Interpretation Introduction

Interpretation:

Synthesis method of the given compound has to be given from the compound which have the same number of carbon atoms.

Concept Introduction:

Addition of water to alkynes in presence of acid:

Under acidic conditions, alkyne reacts with water to produce an enol which then immediately converts into ketone. For terminal alkynes, there is a need of catalyst which is mercury.

The formed enol and ketone are called keto-enol tautomers.

Tautomerization: It is the process of inter conversion of tautomers and therefore the process can also be called as keto-enol tautomerization.

Hydroboration reaction:

It is the reaction in which an internal alkyne is converted into ketone. The reagents used for the hydroboration oxidation reaction is either BH3 or R2BH.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 7.1 - Prob. 1P Ch. 7.1 - Name the following:Ch. 7.1 - What is the molecular formula for a monocyclic...Ch. 7.1 - Draw the condensed and skeletal structures for...Ch. 7.1 - Draw the structure and give the common and...Ch. 7.2 - Prob. 6P Ch. 7.2 - Name the following:Ch. 7.3 - What orbitals are used to form the carbon-carbon ...Ch. 7.4 - Prob. 9P Ch. 7.4 - Why does cis-2-butene have a higher boiling point...

Solution Summary: The author explains that the hydroboration reaction is the reaction in which an internal alkyne is converted into ketone.

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