Student Solutions Manual For Masterton/hurley's Chemistry: Principles And Reactions, 8th
8th Edition
ISBN: 9781305095236
Author: Maria Cecilia D. De Mesa, Thomas D. Mcgrath
Publisher: Cengage Learning
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Chapter 7, Problem 36QAP
Predict the geometry of the following species:
(a) ClF5
(b) XeF4
(c) SiF62-
(d) Pcl5
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Which of the following molecules does not have a dipole moment?
(a) CH3Cl
(b) CH2Cl2
(c) CFCl3
(d) CHCl3
(a) Complete the Lewis structure for the molecule below. How many lone pairs are there?
HHH
H-Ca Cb C-N=C=S
H
(b) For the structure shown, give the hybridizations of the following atoms:
(i) Ca
(i) Ca-Cb-C
(ii) Cb
(iii) N
(ii) H-Ca-C b
(c) Give approximate values of the bond angles for the following:
(iv) S
(iii) C-N-C
Draw the Lewis structures and describe the geometry for the following:(a) PF4+(b) PF5(c) PF6−(d) POF3
Chapter 7 Solutions
Student Solutions Manual For Masterton/hurley's Chemistry: Principles And Reactions, 8th
Ch. 7 - Prob. 1QAPCh. 7 - Prob. 2QAPCh. 7 - Follow the directions of Question 1 for (a) IO2-...Ch. 7 - Follow the directions of Question 1 for (a) CIF4-...Ch. 7 - Follow the directions of Question 1 for (a) OCl2...Ch. 7 - Follow the directions of Question 1 for (a) C22-...Ch. 7 - Oxalic acid, H2C2O4, is a poisonous compound found...Ch. 7 - Radio astronomers have detected the isoformyl ion,...Ch. 7 - Draw Lewis structures for the following species....Ch. 7 - Follow the directions of Question 9 for the...
Ch. 7 - Dinitrogen pentoxide, N2O5, when bubbled into...Ch. 7 - Formic acid is the irritating substance that gets...Ch. 7 - Two different molecules have the formula C2H2Cl2....Ch. 7 - Two different molecules have the formula C2H6O....Ch. 7 - Prob. 15QAPCh. 7 - Prob. 16QAPCh. 7 - Write a Lewis structure for (a) XeF3+ (b) PCl4+...Ch. 7 - Write a Lewis structure for (a) BCl4 (b) ClO- (c)...Ch. 7 - Write reasonable Lewis structures for the...Ch. 7 - Write reasonable Lewis structures for the...Ch. 7 - Prob. 21QAPCh. 7 - Draw resonance structures for (a) SeO3 (b) CS32-...Ch. 7 - Prob. 23QAPCh. 7 - Prob. 24QAPCh. 7 - The skeleton structure for disulfur dinitride,...Ch. 7 - Borazine, B3N3H6, has the skeleton Draw the...Ch. 7 - What is the formal charge on the indicated atom in...Ch. 7 - Prob. 28QAPCh. 7 - Below are two different Lewis structures for...Ch. 7 - Below are two different Lewis structures for the...Ch. 7 - Predict the geometry of the following species: (a)...Ch. 7 - Predict the geometry of the following species: (a)...Ch. 7 - Predict the geometry of the following species: (a)...Ch. 7 - Predict the geometry of the following species: (a)...Ch. 7 - Predict the geometry of the following species: (a)...Ch. 7 - Predict the geometry of the following species: (a)...Ch. 7 - Give all the ideal bond angles (109.5, 120, or...Ch. 7 - Prob. 38QAPCh. 7 - Prob. 39QAPCh. 7 - An objectionable component of smog is acetyl...Ch. 7 - The uracil molecule is one of the bases in DNA....Ch. 7 - Niacin is one of the B vitamins (B3). Estimate the...Ch. 7 - Which of the species with octets in Question 31...Ch. 7 - Which of the species with octets in Question 32...Ch. 7 - Which of the species with octets in Question 33...Ch. 7 - Prob. 46QAPCh. 7 - There are three compounds with the formula...Ch. 7 - There are two different molecules with the formula...Ch. 7 - Give the hybridization of the central atom in each...Ch. 7 - Give the hybridization of the central atom in each...Ch. 7 - Give the hybridization of the central atom in each...Ch. 7 - Give the hybridization of the central atom in each...Ch. 7 - Give the hybridization of the central atom in each...Ch. 7 - Give the hybridization of the central atom in each...Ch. 7 - In each of the following polyatomic ions, the...Ch. 7 - Follow the directions of Question 55 for the...Ch. 7 - Give the hybridization of each atom (except H) in...Ch. 7 - Acrylonitrile, C3H3N is the building mer Orlon....Ch. 7 - What is the hybridization of nitrogen inCh. 7 - What is the hybridization of carbon inCh. 7 - Give the hybridization of the central atom...Ch. 7 - Give the hybridization of the central atom...Ch. 7 - Give the number of sigma and pi bonds in the...Ch. 7 - Give the number of sigma and pi bonds in the...Ch. 7 - Give the number of sigma and pi bonds in each...Ch. 7 - Give the number of sigma and pi bonds in each...Ch. 7 - In which of the following molecules does the...Ch. 7 - Consider the pyrosulfate ion, S2O72-. It has no...Ch. 7 - Consider acetyl salicylic acid, better known as...Ch. 7 - Complete the table on next page.Ch. 7 - Given the following electro negativities...Ch. 7 - Based on the concept of formal charge, what is the...Ch. 7 - Describe the geometry of the species in which...Ch. 7 - Consider the following molecules: SiH4, PH3, H2S....Ch. 7 - Prob. 75QAPCh. 7 - In each of the following molecules, a central atom...Ch. 7 - Prob. 77QAPCh. 7 - A compound of chlorine and fluorine, CIFx, reacts...Ch. 7 - Draw the Lewis structure and describe the geometry...Ch. 7 - Consider the polyatomic ion IO65-. How many pairs...Ch. 7 - It is possible to write a simple Lewis structure...Ch. 7 - Phosphoryl chloride, POCl3, has the skeleton...
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- For each of the following molecules or molecular ions, give the steric number, sketch and name the approximate molecular geometry, and describe the direction of any distortions from the approximate geometry due to lone pairs. In each case, the central atom is listed first and the other atoms are all bonded directly to it. (a) TeH2 (c) PCI (b) AsF3 (d) XeFarrow_forwardExplain why(a) XeF2 has a linear molecular structure and not a bent one.(b) ClF3 has a T-shaped structure and not a trigonal-planar one.arrow_forwardDetermine the electron-group arrangement, molecular shape, and ideal bond angle(s) for each of the following:(a) O₃(b) H₃O⁺(c) NF₃arrow_forward
- 3. (a) Complete the Lewis structure for the molecule below. How many lone pairs are there? I HO I ။ H-Ca-Cb-N H H H (b) For the structure shown, give the hybridizations of the following atoms: (i) Ca (i) Ca-C b-N (ii) C b (c) Give approximate values of the bond angles for the following: (iii) O (ii) Cb-N-H (iv) N (iii) H-Ca-C barrow_forward(a) Methane (CH4) and the perchlorate ion (ClO4- ) are bothdescribed as tetrahedral. What does this indicate about theirbond angles? (b) The NH3 molecule is trigonal pyramidal, while BF3 is trigonal planar. Which of these molecules is flat?arrow_forwardThe sulfate ion can be represented with four S-O bonds or with two S-O and two So=O bonds.(a) Which representation is better from the standpoint of formal charges?(b) What is the shape of the sulfate ion, and what hybrid orbitals of S are postulated for the σ bonding?(c) In view of the answer to part (b), what orbitals of S must be used for the π bonds? What orbitals of O?(d) Draw a diagram to show how one atomic orbital from S and one from O overlap to form a π bond.arrow_forward
- (a) Predict the geometry of the SbCl52- ion, using theVSEPR method.(b) The ion SbCl63- is prepared from SbCl52-by treatment with Cl2. Determine the steric number of thecentral antimony atom in this ion, and discuss theextension of the VSEPR theory that would be neededfor the prediction of its molecular geometry.arrow_forwardPredict whether each of the following has a dipole moment. Show shifting of electron density. (a) HBr (b) AlCl3 (c) CBr4arrow_forwardPredict the electron pair geometry and the molecular structure of each of the following ions:(a) H3O+(b) PCl4−(c) SnCl3−(d) BrCl4−(e) ICl3(f) XeF4(g) SF2arrow_forward
- Which compound would be expected to have the largest dipole moment? (A)CO2 (linear) (B)SO2 (bent) (C)BF3 (trigonal planar) (D)CF4 (tetrahedral) Could you explain which answer is correct and why?arrow_forwardBecause both tin and carbon are members of Group 4A(14), they form structurally similar compounds. However, tin exhibits a greater variety of structures because it forms several ionic species. Predict the shapes and ideal bond angles, including any deviations, for the following:(a) Sn(CH3)2 (b) SnCl3- (c) Sn(CH3)4 (d) SnF5- (e) SnF62-arrow_forwardBecause both tin and carbon are members of Group 4A(14), they form structurally similar compounds. However, tin exhibits a greater variety of structures because it forms several ionic species. Predict the shapes and ideal bond angles, including any deviations, for the following: (a) Sn(CH3)2 (b) SnCl3- (c) Sn(CH3)4(d) SnF5- (e) SnF62-arrow_forward
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