
Organic Chemistry, Books a la Carte Edition (8th Edition)
8th Edition
ISBN: 9780134074580
Author: Bruice, Paula Yurkanis
Publisher: PEARSON
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Chapter 7, Problem 35P
(a)
Interpretation Introduction
Interpretation:
The structure, common name and systematic names for
Concept Introduction:
- If the ‘ane’ ending of the
alkane is replaced by ‘yne’ ending, the name of alkyne is obtained. - Select the longest chain which contain the triple bond in such a way to get lowest value for the
functional group . - Two types of alkynes will be there according to the position of triple bond. Terminal alkyne is the one which contain triple bond at the end of the chain and internal alkyne is the one which contain triple bond not at the end but present in any other positions in the chain.
- When the counting is done from either sides of triple bond in a compound which contain same number for the functional group suffix, the correct name will be the one which have lowest substituent number. In the case of more than one substituent, alphabetical order should be followed.
Skeletal structure: When the atoms bonded in a compound is drawn in a series it can be called as a skeletal structure. In the skeletal structure, we can show the branches, chains, rings or any other hetero atom other than carbon or hydrogen.
Condensed structure: In the condensed structure, atoms or group of atoms are expressed in a line. But it does not contain any vertical bonds and also the horizontal single bonds.
(b)
Interpretation Introduction
Interpretation:
The number of isomers possible if stereoisomers are included should be determined.
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Draw the corresponding structures in each of the boxes below:
Ester Name
Methyl butyrate
(Example)
Alcohol Structure
H3C-OH
Acid Structure
Ester Structure
Isoamyl acetate
Ethyl butyrate
Propyl acetate
Methyl salicylate
Octyl acetate
Isobutyl
propionate
Benzyl butyrate
Benzyl acetate
Ethyl acetate
H₂C
OH
HC
2) For each of the following reactions:
(i)
(ii)
Fill in the missing reactant, reagent, or product (s), indicating stereochemistry where
appropriate using dashed and wedged bonds.
If the reaction forms a racemic mixture, draw both structures in the box and write the
word "racemic".
(a)
(b)
1) R₂BH
2) H₂O2,
NaOH (aq)
HBr
Br
racemic
Br
+
Br Br
racemic
For each of the following reactions: Fill in the missing reactant, reagent, or product (s), indicating stereochemistry where appropriate using dashed and wedged bonds. If the reaction forms a racemic mixture, draw both structures in the box and write the word “racemic”.
Chapter 7 Solutions
Organic Chemistry, Books a la Carte Edition (8th Edition)
Ch. 7.1 - Prob. 1PCh. 7.1 - Name the following:Ch. 7.1 - What is the molecular formula for a monocyclic...Ch. 7.1 - Draw the condensed and skeletal structures for...Ch. 7.1 - Draw the structure and give the common and...Ch. 7.2 - Prob. 6PCh. 7.2 - Name the following:Ch. 7.3 - What orbitals are used to form the carbon-carbon ...Ch. 7.4 - Prob. 9PCh. 7.4 - Why does cis-2-butene have a higher boiling point...
Ch. 7.6 - Prob. 12PCh. 7.6 - Prob. 13PCh. 7.7 - Prob. 14PCh. 7.7 - Which alkyne should be used for the synthesis of...Ch. 7.7 - Prob. 16PCh. 7.8 - Prob. 17PCh. 7.8 - Only one alkyne forms an aldehyde when it...Ch. 7.9 - Describe the alkyne you should start with and the...Ch. 7.9 - Prob. 20PCh. 7.10 - Prob. 21PCh. 7.10 - Prob. 22PCh. 7.10 - Prob. 23PCh. 7.10 - Rank the following from strongest base to weakest...Ch. 7.10 - Prob. 26PCh. 7.12 - Prob. 28PCh. 7 - What is the major product obtained from the...Ch. 7 - Draw a condensed structure for each of the...Ch. 7 - A student was given the structural formula of...Ch. 7 - Prob. 32PCh. 7 - What is each compounds systematic name?Ch. 7 - What reagents should be used to carry out the...Ch. 7 - Prob. 35PCh. 7 - Draw the mechanism for the following reaction:Ch. 7 - Prob. 37PCh. 7 - Prob. 38PCh. 7 - What is the major product of the reaction of 1 mol...Ch. 7 - Answer Problem 39, parts a-b, using 2-butyne as...Ch. 7 - What is each compounds systematic name? a....Ch. 7 - What is the molecular formula of a hydrocarbon...Ch. 7 - a. Starting with 3-methyl 1-butyne, how can you...Ch. 7 - Prob. 44PCh. 7 - Which of the following pairs are keto-enol...Ch. 7 - Prob. 46PCh. 7 - Do the equilibria of the following acid-base...Ch. 7 - What is each compounds systematic name?Ch. 7 - What stereoisomers are obtained when 2-butyne...Ch. 7 - Prob. 50PCh. 7 - Draw the keto tautomer for each of the following:Ch. 7 - Show how each of the following compounds can be...Ch. 7 - A chemist is planning to synthesize 3-octyne by...Ch. 7 - Prob. 54PCh. 7 - What stereoisomers are obtained from the following...Ch. 7 - Prob. 56PCh. 7 - Prob. 57PCh. 7 - Prob. 58PCh. 7 - Show how the following compound can be prepared...Ch. 7 - Prob. 60P
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