The given pairs of structures should be identified that whether they are resonance contributors or different compounds. Concept Introduction: Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure. Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds. Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

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Answer 1

Question

Chapter 7, Problem 33P

(a)

Interpretation Introduction

Interpretation:

The given pairs of structures should be identified that whether they are resonance contributors or different compounds.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

(b)

Interpretation Introduction

Interpretation:

The given pairs of structures should be identified that whether they are resonance contributors or different compounds.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

(c)

Interpretation Introduction

Interpretation:

The given pairs of structures should be identified that whether they are resonance contributors or different compounds.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

(d)

Interpretation Introduction

Interpretation:

The given pairs of structures should be identified that whether they are resonance contributors or different compounds.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

(e)

Interpretation Introduction

Interpretation:

The given pairs of structures should be identified that whether they are resonance contributors or different compounds.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

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You have now performed a liquid-liquid extraction protocol in Experiment 4. In doing so, you manipulated and exploited the acid-base chemistry of one or more of the compounds in your mixture to facilitate their separation into different phases. The key to understanding how liquid- liquid extractions work is by knowing which layer a compound is in, and in what protonation state. The following liquid-liquid extraction is different from the one you performed in Experiment 4, but it uses the same type of logic. Your task is to show how to separate apart Compound A and Compound B. . Complete the following flowchart of a liquid-liquid extraction. Handwritten work is encouraged. • Draw by hand (neatly) only the appropriate organic compound(s) in the boxes. . Specify the reagent(s)/chemicals (name is fine) and concentration as required in Boxes 4 and 5. • Box 7a requires the solvent (name is fine). • Box 7b requires one inorganic compound. • You can neatly complete this assignment by hand and…

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Answer 2

Question

Chapter 7, Problem 33P

(a)

Interpretation Introduction

Interpretation:

The given pairs of structures should be identified that whether they are resonance contributors or different compounds.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

(b)

Interpretation Introduction

Interpretation:

The given pairs of structures should be identified that whether they are resonance contributors or different compounds.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

(c)

Interpretation Introduction

Interpretation:

The given pairs of structures should be identified that whether they are resonance contributors or different compounds.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

(d)

Interpretation Introduction

Interpretation:

The given pairs of structures should be identified that whether they are resonance contributors or different compounds.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

(e)

Interpretation Introduction

Interpretation:

The given pairs of structures should be identified that whether they are resonance contributors or different compounds.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

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Answer 3

Question

Chapter 7, Problem 33P

(a)

Interpretation Introduction

Interpretation:

The given pairs of structures should be identified that whether they are resonance contributors or different compounds.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

(b)

Interpretation Introduction

Interpretation:

The given pairs of structures should be identified that whether they are resonance contributors or different compounds.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

(c)

Interpretation Introduction

Interpretation:

The given pairs of structures should be identified that whether they are resonance contributors or different compounds.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

(d)

Interpretation Introduction

Interpretation:

The given pairs of structures should be identified that whether they are resonance contributors or different compounds.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

(e)

Interpretation Introduction

Interpretation:

The given pairs of structures should be identified that whether they are resonance contributors or different compounds.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

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Answer 4

Question

Chapter 7, Problem 33P

(a)

Interpretation Introduction

Interpretation:

The given pairs of structures should be identified that whether they are resonance contributors or different compounds.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

(b)

Interpretation Introduction

Interpretation:

The given pairs of structures should be identified that whether they are resonance contributors or different compounds.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

(c)

Interpretation Introduction

Interpretation:

The given pairs of structures should be identified that whether they are resonance contributors or different compounds.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

(d)

Interpretation Introduction

Interpretation:

The given pairs of structures should be identified that whether they are resonance contributors or different compounds.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

(e)

Interpretation Introduction

Interpretation:

The given pairs of structures should be identified that whether they are resonance contributors or different compounds.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

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Answer 5

Chapter 7, Problem 33P

(a)

Interpretation Introduction

Interpretation:

The given pairs of structures should be identified that whether they are resonance contributors or different compounds.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

(b)

Interpretation Introduction

Interpretation:

The given pairs of structures should be identified that whether they are resonance contributors or different compounds.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

(c)

Interpretation Introduction

Interpretation:

The given pairs of structures should be identified that whether they are resonance contributors or different compounds.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

(d)

Interpretation Introduction

Interpretation:

The given pairs of structures should be identified that whether they are resonance contributors or different compounds.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

(e)

Interpretation Introduction

Interpretation:

The given pairs of structures should be identified that whether they are resonance contributors or different compounds.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

Answer 6

Chapter 7, Problem 33P

(a)

Interpretation Introduction

Interpretation:

The given pairs of structures should be identified that whether they are resonance contributors or different compounds.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

Answer 7

Chapter 7, Problem 33P

(a)

Interpretation Introduction

Interpretation:

The given pairs of structures should be identified that whether they are resonance contributors or different compounds.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The given pairs of structures should be identified that whether they are resonance contributors or different compounds.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The given pairs of structures should be identified that whether they are resonance contributors or different compounds.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The given pairs of structures should be identified that whether they are resonance contributors or different compounds.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The given pairs of structures should be identified that whether they are resonance contributors or different compounds.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The given pairs of structures should be identified that whether they are resonance contributors or different compounds.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The given pairs of structures should be identified that whether they are resonance contributors or different compounds.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

Answer 14

(e)

Interpretation Introduction

Interpretation:

The given pairs of structures should be identified that whether they are resonance contributors or different compounds.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

Answer 15

(e)

Interpretation Introduction

Interpretation:

The given pairs of structures should be identified that whether they are resonance contributors or different compounds.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.

Answer 16

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Answer 17

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Answer 18

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Answer 19

Ch. 7.4 - Prob. 1P Ch. 7.5 - Prob. 3P Ch. 7.6 - a. Predict the relative bond lengths of the three...Ch. 7.6 - Prob. 5P Ch. 7.6 - Prob. 6P Ch. 7.7 - Prob. 7P Ch. 7.7 - Prob. 8P Ch. 7.7 - Prob. 9P Ch. 7.7 - Prob. 10P Ch. 7.8 - Which member of each pair is the stronger acid? a....

Solution Summary: The author explains that the pairs of structures should be identified that whether they are resonance contributors or different compounds.

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Chapter 7 Solutions