Chemistry: Atoms First
Chemistry: Atoms First
18th Edition
ISBN: 9781938168154
Author: Richard Langley, Klaus Theopold, Paul Flowers
Publisher: OpenStax College
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Chapter 7, Problem 18E

Determine the oxidation states of the elements in the compounds listed. None of the oxygen-containing compounds are peroxides or superoxides.

(a) H 2 SO 4

(b) Ca ( OH ) 2

(C) BrOH

(d) ClNO 2

(e) TiCl 4

(f) NaH

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Decide whether these proposed Lewis structures are reasonable. proposed Lewis structure Is the proposed Lewis structure reasonable? Yes. :0: Cl C C1: 0=0: : 0 : : 0 : H C N No, it has the wrong number of valence electrons. The correct number is: ☐ No, it has the right number of valence electrons but doesn't satisfy the octet rule. The symbols of the problem atoms are:* ☐ Yes. No, it has the wrong number of valence electrons. The correct number is: ☐ No, it has the right number of valence electrons but doesn't satisfy the octet rule. The symbols of the problem atoms are:* Yes. ☐ No, it has the wrong number of valence electrons. The correct number is: ☐ No, it has the right number of valence electrons but doesn't satisfy the octet rule. The symbols of the problem atoms are:* | * If two or more atoms of the same element don't satisfy the octet rule, just enter the chemical symbol as many times as necessary. For example, if two oxygen atoms don't satisfy the octet rule, enter "0,0".
Draw the Lewis structure for the polyatomic trisulfide anion. Be sure to include all resonance structures that satisfy the octet rule. с [ ] - G
1. Calculate the accurate monoisotopic mass (using all 1H, 12C, 14N, 160 and 35CI) for your product using the table in your lab manual. Don't include the Cl, since you should only have [M+H]*. Compare this to the value you see on the LC-MS printout. How much different are they? 2. There are four isotopic peaks for the [M+H]* ion at m/z 240, 241, 242 and 243. For one point of extra credit, explain what each of these is and why they are present. 3. There is a fragment ion at m/z 184. For one point of extra credit, identify this fragment and confirm by calculating the accurate monoisotopic mass. 4. The UV spectrum is also at the bottom of your printout. For one point of extra credit, look up the UV spectrum of bupropion on Google Images and compare to your spectrum. Do they match? Cite your source. 5. For most of you, there will be a second chromatographic peak whose m/z is 74 (to a round number). For one point of extra credit, see if you can identify this molecule as well and confirm by…

Chapter 7 Solutions

Chemistry: Atoms First

Ch. 7 - From the balanced molecular equations, write the...Ch. 7 - Use the following equations to answer the next...Ch. 7 - Indicate what type, or types, of reaction each of...Ch. 7 - Indicate what type, or types, of reaction each of...Ch. 7 - Silver can be separated from gold because silver...Ch. 7 - Determine the oxidation states of the elements in...Ch. 7 - Determine the oxidation states of the elements in...Ch. 7 - Determine the oxidation states of the elements in...Ch. 7 - Classify the following as acid-base reactions or...Ch. 7 - Identify the atoms that are oxidized and reduced,...Ch. 7 - Complete and balance the following acid-base...Ch. 7 - Complete and balance the following acid-base...Ch. 7 - Complete and balance the following...Ch. 7 - Complete and balance the following...Ch. 7 - Complete and balance the equations for the...Ch. 7 - When heated to 700—800 C, diamonds, which are pure...Ch. 7 - The military has experimented with lasers that...Ch. 7 - Write the molecular, total ionic, and net ionic...Ch. 7 - Great Lakes Chemical Company produces bromine,...Ch. 7 - In a common experiment in the general chemistry...Ch. 7 - Lithium hydroxide may be used to absorb carbon...Ch. 7 - Calcium propionate is sometimes added to bread to...Ch. 7 - Complete and balance the equations of the...Ch. 7 - Copper(II) sulfide is oxidized by molecular oxygen...Ch. 7 - Write balanced chemical equations for the...Ch. 7 - Calcium cyclamate Ca(C6H 11 NHSO3)2 is an...Ch. 7 - Complete and balance each of the following...Ch. 7 - Complete and balance each of the following...Ch. 7 - Balance each of the following equations according...Ch. 7 - Balance each of the following equations according...Ch. 7 - Balance each of the following equations according...Ch. 7 - Write the balanced equation, then outline the...Ch. 7 - Determine the number of moles and the mass...Ch. 7 - Write the balanced equation, then outline the...Ch. 7 - Determine the number of moles and the mass...Ch. 7 - H2 is produced by the reaction of 118.5 mL of a...Ch. 7 - Gallium chloride is formed by the reaction of 2.6...Ch. 7 - I2 is produced by the reaction of 0.4235 mol of...Ch. 7 - Silver is often extracted from ores such as...Ch. 7 - What mass of silver oxide, Ag2O, is required to...Ch. 7 - Carborundum is silicon carbide, SiC, a very hard...Ch. 7 - Automotive air bags inflate when a sample of...Ch. 7 - Urea, CO( NH2)2, is manufactured on a large scale...Ch. 7 - In an accident, a solution containing 2.5 kg of...Ch. 7 - A compact car gets 37.5 miles per gallon on the...Ch. 7 - What volume of 0.750 M hydrochloric acid solution...Ch. 7 - What volume of a 0.2089 M Kl solution contains...Ch. 7 - A mordant is a substance that combines with a dye...Ch. 7 - The toxic pigment called white lead, Pb3(OH)2(...Ch. 7 - The following quantities are placed in a...Ch. 7 - What is the limiting reactant in a reaction that...Ch. 7 - Which of the postulates of Dalton’s atomic theory...Ch. 7 - A student isolated 25 g of a compound following a...Ch. 7 - A sample of 0.53 g of carbon dioxide was obtained...Ch. 7 - Freon-12, CCl2F2, is prepared from CCl4 by...Ch. 7 - Citric acid, C6H5CH3, a component of jams,...Ch. 7 - Toluene, C6H5CH3, is oxidized by air under...Ch. 7 - In a laboratory experiment, the reaction of 3.0...Ch. 7 - Outline the steps needed to solve the following...Ch. 7 - Outline the steps needed to determine the limiting...Ch. 7 - Outline the steps needed to determine the limiting...Ch. 7 - What is the limiting reactant when 1.50 g of...Ch. 7 - Uranium can be isolated from its ores by...Ch. 7 - How many molecules of C2H4Cl2 can be prepared from...Ch. 7 - How many molecules of the sweetener saccharin can...Ch. 7 - The phosphorus pentoxide used to produce...Ch. 7 - Would you agree to buy 1 trillion...Ch. 7 - What volume of 0.0105-M HBr solution is required...Ch. 7 - Titration of a 20.0-mL sample of acid rain...Ch. 7 - What is the concentration of NaCl in a solution if...Ch. 7 - In a common medical laboratory determination of...Ch. 7 - Potatoes can be peeled commercially by soaking...Ch. 7 - A sample of gallium bromide, GaBr3, weighing 0....Ch. 7 - The principal component of mothballs is...Ch. 7 - A 0.025-g sample of a compound composed of boron...Ch. 7 - Sodium bicarbonate (baking soda), NaHCO3, can be...Ch. 7 - What volume of 0.600 M HCl is required to react...Ch. 7 - What volume of 0.08892 M HNO3 is required to react...Ch. 7 - What volume of a 0.3300-M solution of sodium...Ch. 7 - What volume of a 0.00945-M solution of potassium...Ch. 7 - A sample of solid calcium hydroxide, Ca(OH)2, is...Ch. 7 - What mass of Ca(OH)2 will react with 25.0 g of...Ch. 7 - How many milliliters of a 0.1500-M solution of KOH...Ch. 7 - Potassium acid phthalate, KNaC8H4O4, or KHP, is...Ch. 7 - The reaction of WCl6 with Al at ~400 C gives black...
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