Chemistry: The Molecular Nature of Matter
7th Edition
ISBN: 9781118516461
Author: Neil D. Jespersen, Alison Hyslop
Publisher: WILEY
expand_more
expand_more
format_list_bulleted
Videos
Textbook Question
Chapter 7, Problem 135RQ
Choose the larger particle in each pair:
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
la) For each of the following pairs indicate which element you would expect to have the larger
First Ionization Energy and which one would have the larger radius:
(a) Ca and Cl;
(b) Sn and Tl;
(c) Ba and Bi
(d) Fr and Cs
b) For each pair indicate which Ion you would expect to have the largest Radius:
(a) 0²- and O; (b) N³ and Mg²+ (c) Al3* and Al
ne Ele
b) For each pair indicate which Ion you would expect to have the largest Radius:
(a) 02 and O; (b) N³ and Mg2+ (c) Al3* and Al
Identify each statement as true or false: (a) Cations are largerthan their corresponding neutral atoms. (b) Li+ is smallerthan Li. (c) Cl- is bigger than I-.
Chapter 7 Solutions
Chemistry: The Molecular Nature of Matter
Ch. 7 - Practice Exercise 7.1
Helium derives its name from...Ch. 7 - Practice Exercise 7.2
Radio station KRED in...Ch. 7 - Calculate the wavelength in micrometers, m, of...Ch. 7 - Practice Exercise 7.4
Calculate the wavelength in...Ch. 7 - What is the energy of the radiation emitted when...Ch. 7 - Practice Exercise 7.6
If the energy of light...Ch. 7 - Calculate the energy of an electron in its lowest...Ch. 7 - Practice Exercise 7.8
If an electron moves from a...Ch. 7 - Practice Exercise 7.9
What are the values of n and...Ch. 7 - What subshells would be found in the shells with...
Ch. 7 - Without looking at the tables in the text, how...Ch. 7 - Prob. 12PECh. 7 - Practice Exercise 7.13
Draw orbital diagrams for...Ch. 7 - Practice Exercise 7.14
Use Figure 7.18 to predict...Ch. 7 - Can an dement with an even atomic number be...Ch. 7 - Practice Exercise 7.16
Use orbital diagrams to...Ch. 7 - Practice Exercise 7.17
Use the periodic table to...Ch. 7 - Use the periodic table to predict the electron...Ch. 7 - Practice Exercise 7.19
Write shorthand...Ch. 7 - Write shorthand configurations and abbreviated...Ch. 7 - Practice Exercise 7.21
Give an example of a...Ch. 7 - Prob. 22PECh. 7 - Prob. 23PECh. 7 - Practice Exercise 7.24
Use the periodic table to...Ch. 7 - Use the periodic table to select the atom with the...Ch. 7 - Prob. 26PECh. 7 - In general terms, why do we call light...Ch. 7 - In general, what does the term frequency imply?...Ch. 7 - What is meant by the term wavelength of light?...Ch. 7 - 7.4 Sketch a picture of a wave and label its...Ch. 7 - Which property of light waves is a measure of the...Ch. 7 - Arrange the following regions of the...Ch. 7 - 7.7 What wavelength range is covered by the...Ch. 7 - Arrange the following colors of visible light in...Ch. 7 - What is the equation that relates the wavelength...Ch. 7 - How is the frequency of a particular type of...Ch. 7 - 7.11 What is a photon?
Ch. 7 - Show that the energy of a photon is given by the...Ch. 7 - Examine each of the following pairs and state...Ch. 7 - What is a quantum of energy?Ch. 7 - Prob. 15RQCh. 7 - Prob. 16RQCh. 7 - Describe Niels Bohrs model of the structure of the...Ch. 7 - Prob. 18RQCh. 7 - Why does the equation for the energy of an...Ch. 7 - In what way was Bohrs theory a success? How...Ch. 7 - 7.21 How does the behavior of very small particles...Ch. 7 - Describe the phenomenon called diffraction. How...Ch. 7 - What experiment could you perform to determine...Ch. 7 - 7.24 What is wave/particle duality?
Ch. 7 - Prob. 25RQCh. 7 - What is the collapsing atom paradox?Ch. 7 - How does quantum mechanics resolve the collapsing...Ch. 7 - What are the names used to refer to the theories...Ch. 7 - What is the term used to describe a particular...Ch. 7 - What are the three properties of orbitals in which...Ch. 7 - What are the allowed values of the principal...Ch. 7 - What information does each type of quantum number...Ch. 7 - How does the value of n in the Rydberg equation...Ch. 7 - Why is (a) the d subshell in the Period 4...Ch. 7 - Why does every shell contain an s subshell?Ch. 7 - How many orbitals are found in (a) an s subshell,...Ch. 7 - 7.37 If the value of for an electron in an atom...Ch. 7 - 7.38 What physical property of electrons leads us...Ch. 7 - Explain the two magnetic properties that are...Ch. 7 - What is the Pauli exclusion principle? What effect...Ch. 7 - What are the possible values of the spin quantum...Ch. 7 - Suppose an electron in an atom has the following...Ch. 7 - Prob. 43RQCh. 7 - Prob. 44RQCh. 7 - Within any given shell, how do the energies of the...Ch. 7 - Prob. 46RQCh. 7 - Give the electron configurations of the elements...Ch. 7 - 7.48 Using your own words, describe how to use the...Ch. 7 - Give the correct electron configurations of (a) Cr...Ch. 7 - What is the correct electron configuration of...Ch. 7 - How are the electron configurations of the...Ch. 7 - Define the terms valence shell and valence...Ch. 7 - Why do we use probabilities when we discuss the...Ch. 7 - Sketch the approximate shape of (a) a 1s orbital...Ch. 7 - How does the size of a given type of orbital vary...Ch. 7 - How are the p orbitals of a given p subshell...Ch. 7 - What is a nodalplane? How are the number of nodal...Ch. 7 - What is a radial node? How are the number of...Ch. 7 - 7.59 How many nodal planes does a p orbital have?...Ch. 7 - On appropriate coordinate axes, sketch the shape...Ch. 7 - What is the meaning of effective nuclear charge?...Ch. 7 - *7.62 Explain why a 3s electron in Al experiences...Ch. 7 - Explain why the atomic size varies across the...Ch. 7 - Explain why cations are smaller than their...Ch. 7 - Prob. 65RQCh. 7 - Going from left to right in the periodic table,...Ch. 7 - Prob. 67RQCh. 7 - Prob. 68RQCh. 7 - Explain why ionization energy increases from left...Ch. 7 - Prob. 70RQCh. 7 - Prob. 71RQCh. 7 - Prob. 72RQCh. 7 - Why does phosphorus have a larger first ionization...Ch. 7 - Prob. 74RQCh. 7 - 7.75 For sulfur, write an equation for the change...Ch. 7 - 7.76 Why does Cl have a more exothermic electron...Ch. 7 - Prob. 77RQCh. 7 - How is electron affinity related, to effective...Ch. 7 - 7.79 What is the frequency in hertz of blue light...Ch. 7 - Ultraviolet light with a wavelength of more than...Ch. 7 - Ozone protects the earths inhabitants from the...Ch. 7 - The meter is defined as the length of the path...Ch. 7 - In New York City, radio station WCBS broadcasts...Ch. 7 - Sodium vapor lamps are often used in residential...Ch. 7 - 7.85 Calculate the energy in joules of a photon of...Ch. 7 - Calculate the energy in joules of a photon of...Ch. 7 - In the spectrum of hydrogen, there is a line with...Ch. 7 - 7.88 In the spectrum of sodium, there is a line...Ch. 7 - Use the Rydberg equation to calculate the...Ch. 7 - 7.90 Use the Rydberg equation to calculate the...Ch. 7 - Calculate the wavelength and energy in joules of...Ch. 7 - Calculate the energy in joules and the wavelength...Ch. 7 - What is the letter code for a subshell with...Ch. 7 - 7.94 What is the letter code for a subshell with...Ch. 7 - What is the value of l for (a) an f orbital and...Ch. 7 - 7.96 What is the value of for (a) a p orbital and...Ch. 7 - What are the values of n and l for the subshells:...Ch. 7 - Give the values of n and l for the subshells: (a)...Ch. 7 - For the shell with n = 6, what are the possible...Ch. 7 - 7.100 What values of are possible for a shell with...Ch. 7 - In a particular shell, the largest value of l is...Ch. 7 - What is the value of n for a shell if the largest...Ch. 7 - What are the possible values of ml for a subshell...Ch. 7 - If the value of l for an electron in an atom is 5,...Ch. 7 - If the value of ml for an electron in an atom is...Ch. 7 - How many orbitals are there in an h subshell...Ch. 7 - 7.107 Give the complete set of quantum numbers for...Ch. 7 - 7.108 Give the complete set of quantum numbers for...Ch. 7 - *7.109 In an antimony atom, how many electrons...Ch. 7 - Prob. 110RQCh. 7 - Give the electron configurations of...Ch. 7 - 7.112 Write the electron configurations of (a) As,...Ch. 7 - 7.113 Which of the following atoms in their ground...Ch. 7 - Which of the following atoms in their ground...Ch. 7 - Prob. 115RQCh. 7 - Prob. 116RQCh. 7 - Write the abbreviated electron configurations for...Ch. 7 - Write the abbreviated electron configurations for...Ch. 7 - Draw complete orbital diagrams for (a) Mg and (b)...Ch. 7 - Draw complete orbital diagrams for (a) As and (b)...Ch. 7 - 7.121 Draw orbital diagrams for the abbreviated...Ch. 7 - Draw orbital diagrams for the abbreviated...Ch. 7 - What is the value of n for the valence shells of...Ch. 7 - What is the value of n for the valence shells of...Ch. 7 - Give the configuration of the valence shell for...Ch. 7 - Give the configuration of the valence shell for...Ch. 7 - Draw the orbital diagram for the valence shell of...Ch. 7 - Draw the orbital diagram for the valence shell of...Ch. 7 - Prob. 129RQCh. 7 - Prob. 130RQCh. 7 - 7.131 Choose the larger atom in each pair: (a) Mg...Ch. 7 - Choose the larger atom in each pair: (a) Al or Ar;...Ch. 7 - Prob. 133RQCh. 7 - Place the following in order of increasing size:...Ch. 7 - Choose the larger particle in each pair:...Ch. 7 - Choose the larger particle in each pair:...Ch. 7 - Choose the atom with the larger ionization energy...Ch. 7 - Choose the atom with the larger ionization energy...Ch. 7 - Choose the atom with the more exothermic electron...Ch. 7 - Choose the atom with the more exothermic electron...Ch. 7 - 7.141 Use the periodic table to select the element...Ch. 7 - Use the periodic table to select the element in...Ch. 7 - The human ear is sensitive to sound ranging from...Ch. 7 - *7.144 Microwaves are used to heat food in...Ch. 7 - In the spectrum of hydrogen, there is a line with...Ch. 7 - *7.146 Calculate the wavelength in nanometers of...Ch. 7 - Which of the following electronic transitions...Ch. 7 - Calculate the wavelength of an electron moving at...Ch. 7 - 7.149 What, if anything, is wrong with the...Ch. 7 - 7.150 Suppose students gave the following orbital...Ch. 7 - 7.151 How many electrons are in p orbitals in an...Ch. 7 - What are the quantum numbers of the electrons that...Ch. 7 - 7.153 The removal of an electron from the hydrogen...Ch. 7 - Use orbital diagrams to illustrate what happens...Ch. 7 - *7.155 From the data available in this chapter,...Ch. 7 - 7.156 For an oxygen atom, which requires more...Ch. 7 - Write out the orbital diagram of N in the ground...Ch. 7 - The ions He+andLi2+ have line spectra that can be...Ch. 7 - A neon sign is a gas discharge tube in which...Ch. 7 - How many grams of water could have its temperature...Ch. 7 - 7.161 It has been found that when the chemical...Ch. 7 - *7.162 Using the ionization energy for sodium,...Ch. 7 - *7.163 Using photons with a wavelength of 23.7 nm,...Ch. 7 - 7.164 Our understanding of the quantum mechanical...Ch. 7 - When a copper atom loses an electron to become a...Ch. 7 - 7.166 Paired electrons cancel each others magnetic...Ch. 7 - Prob. 167RQ
Additional Science Textbook Solutions
Find more solutions based on key concepts
23. Give the symbol and name for (a) an isotope with a mass number of 37 and an atomic number of 17 and (b) an ...
Chemistry For Changing Times (14th Edition)
Which element is a maingroup metal with an even atomic number? a. K b. Ca c. Cr d. Se
Introductory Chemistry (6th Edition)
Consider the following half-reactions and Eo values: SW Ag+(aq)+eAg(s)Eo=0.80V Cu2+(aq)+2eCu(s)Eo=0.30V Pb2+(aq...
CHEMISTRY-TEXT
PRACTICE 1.1 Express the following quantities in scientific no-
tation and then express the number and unit wi...
Chemistry (7th Edition)
For Practice 1.1
Is each change physical or chemical? Which kind of property (chemical or physical) is demonst...
Principles of Chemistry: A Molecular Approach (3rd Edition)
8.63 Two flasks of equal volume and at the same temperature contain different gases. One flask contains 10.0 g ...
Chemistry: An Introduction to General, Organic, and Biological Chemistry (13th Edition)
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Look up the van der Waals constants, b, for H2, N2, O2, and Cl2. Based on the periodic table, predict atomic radii for H, N, O, and Cl. Use these values to explain the sizes of the b constants.arrow_forwardWhat is the electron configuration of the Ba3+ ion? Suggest a reason why this ion is not normally found in nature.arrow_forwardGive the ground-state electron configurations of the following elements: (a) P (b) Tc (c) Hoarrow_forward
- Which of the four atoms Na, P, Cl, or K (a) has the largest atomic radius? (b) has the highest ionization energy? (c) is the most electronegative?arrow_forward5. The atoms and ions Ne, N³-, F, Mg2+, and Si4+ are part of an isoelectronic series. (a) Which of these will have the smallest effective nuclear charge acting on the outermost electron? (b) Which one possess the greatest effective nuclear charge? (c) Which ion will be the largest in size? Explain why.arrow_forwardBoron, atomic number 5, occurs naturally as two isotopes, 10B and 11B, with natural abundances of 19.9% and 80.1%, respectively. (a) In what ways do the two isotopes differ from each other? Does the electronic configuration of 10B differ from that of 11B? (b) Draw the orbital diagram for an atom of 11B. Which electrons are the valence electrons? (c) Indicate three ways in which the 1s electrons in boron differ from its 2s electrons. (d) Elemental boron reacts with fluorine to form BF3, a gas. Write a balanced chemical equation for the reaction of solid boron with fluorine gas. (e) ΔHf° for BF3(g) is -1135.6 kj/mol. Calculate the standard enthalpy change in the reaction of boron with fluorine. (f) Will the mass percentage of F be the same in 10BF3 and 11BF3? If not, why is that the case?arrow_forward
- 2. (a) What is the smallest atom in group 13?(b) What is the smallest atom of the atoms Te, In, Sr, Po, Sb? Why is that?arrow_forwardBoron, atomic number 5, occurs naturally as two isotopes, 10B and 11B, with natural abundances of 19.9% and 80.1%, respectively.(a) In what ways do the two isotopes differ from each other? Does the electronic configuration of 10B differ from that of 11B? (b) Drawthe orbital diagram for an atom of 11B. Which electrons are the valence electrons? (c) Indicate three ways in which the 1s electrons inboron differ from its 2s electrons. (d) Elemental boron reacts with fluorine to form BF3, a gas. Write a balanced chemical equation forthe reaction of solid boron with fluorine gas. (e) ΔHf° for BF31g2 is -1135.6 kJ>mol. Calculate the standard enthalpy change in thereaction of boron with fluorine. (f) Will the mass percentage of F be the same in 10BF3 and 11BF3? If not, why is that the case?arrow_forward4. As you move across the periodic table, from left to right, (A) do the atoms get smaller or larger? (B) are the ionization energies increasing or decreasing? (C) are the metals becoming more or less reactive?arrow_forward
- A hydrogen-like ion is an ion containing only one electron. The energies of the electron in a hydrogen-like ion are given by (2.180 × 10-¹5 1) 2² (1) J) E = kJ where n is the principal quantum number, and Z is the atomic number of the element. Calculate the ionization energy, in your answer to 4 significant digits. mol Note: Reference the Fundamental constants table for additional information. ·2+ of the Li²+ ion. Round Iarrow_forward(a) Write the electron configuration for Li and estimate theeffective nuclear charge experienced by the valence electron.(b) The energy of an electron in a one-electron atom or ion equals (-2.18 x 10-18 J) aZ2/n2 b, where Z is the nuclear chargeand n is the principal quantum number of the electron. Estimatethe first ionization energy of Li. (c) Compare the resultof your calculation with the value reported in Table 7.4 andexplain the difference. (d) What value of the effective nuclearcharge gives the proper value for the ionization energy? Doesthis agree with your explanation in part (c)?arrow_forward4 Indicate which one of the two species in each of the following pairs is smaller: (a) For F; (b) Kor K ; (c) O- or S ; (d) Mg- or Al-arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Introductory Chemistry: A FoundationChemistryISBN:9781337399425Author:Steven S. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
Chemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage Learning
Principles of Modern ChemistryChemistryISBN:9781305079113Author:David W. Oxtoby, H. Pat Gillis, Laurie J. ButlerPublisher:Cengage Learning
Chemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage Learning
Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage Learning
Chemistry: Matter and ChangeChemistryISBN:9780078746376Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl WistromPublisher:Glencoe/McGraw-Hill School Pub Co
Introductory Chemistry: A Foundation
Chemistry
ISBN:9781337399425
Author:Steven S. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
Principles of Modern Chemistry
Chemistry
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:Cengage Learning
Chemistry: Principles and Practice
Chemistry
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Cengage Learning
Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning
Chemistry: Matter and Change
Chemistry
ISBN:9780078746376
Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom
Publisher:Glencoe/McGraw-Hill School Pub Co
Quantum Numbers, Atomic Orbitals, and Electron Configurations; Author: Professor Dave Explains;https://www.youtube.com/watch?v=Aoi4j8es4gQ;License: Standard YouTube License, CC-BY
QUANTUM MECHANICAL MODEL/Atomic Structure-21E; Author: H to O Chemistry;https://www.youtube.com/watch?v=mYHNUy5hPQE;License: Standard YouTube License, CC-BY