ORGANIC CHEMISTRY, WITH SOL. MAN/ STUDY
ORGANIC CHEMISTRY, WITH SOL. MAN/ STUDY
3rd Edition
ISBN: 9781119477617
Author: Klein
Publisher: WILEY
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Chapter 6.8, Problem 3LTS
Interpretation Introduction

Interpretation:

The arrow pushing pattern should be identified for the given reaction.

Concept introduction:

Leaving groups can be neutral molecules or anions, neutral molecules or anions depart with the pair of electron in heterolytic bond cleavage.

Carbocation: Carbocation is a positive charged species and vital intermediate in organic synthesis and its movement depends on the stability of the intermediate and the product formation, this type of rearrangement is called carbocation rearrangement.

Nucleophile: A Nucleophile carries electron pair (negative charged anion) on the molecule. And it attacks the positive charged ions to form a chemical bond in reaction.

Proton transfer: proton transfer is hydride ion ( H+ ) transfer, proton transfer can be intermolecular fashion (between the molecule) or intramolecular fashion (with in the molecule).

According to acid base theory a proton ( H+ ) donor is acid, proton ( H+ ) acceptor is called as base.

The Michael reaction or Michael addition: carbanion or another nucleophile addition of a to an α,β-unsaturated carbonyl compound.

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3. Arrange the different acids in Exercise B # 2 from the strongest (1) to the weakest acid (10). 1. 2. (strongest) 3. 4. 5. 6. 7. 8. 9. 10 10. (weakest)
Name Section Score Date EXERCISE B pH, pOH, pка, AND PKD CALCULATIONS 1. Complete the following table. Solution [H+] [OH-] PH РОН Nature of Solution A 2 x 10-8 M B 1 x 10-7 M C D 12.3 6.8 2. The following table contains the names, formulas, ka or pka for some common acids. Fill in the blanks in the table. (17 Points) Acid Name Formula Dissociation reaction Ka pka Phosphoric acid H₂PO₁ H3PO4 H++ H₂PO 7.08 x 10-3 Dihydrogen H₂PO H₂PO H+ HPO 6.31 x 10-6 phosphate Hydrogen HPO₁ 12.4 phosphate Carbonic acid H2CO3 Hydrogen HCO 6.35 10.3 carbonate or bicarbonate Acetic acid CH,COOH 4.76 Lactic acid CH₂CHOH- COOH 1.38 x 10 Ammonium NH 5.63 x 10-10 Phenol CH₂OH 1 x 10-10 Protonated form CH3NH3* 3.16 x 10-11 of methylamine
Indicate whether it is true that Co(III) complexes are very stable.

Chapter 6 Solutions

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