Experimental Organic Chemistry: A Miniscale & Microscale Approach (Cengage Learning Laboratory Series for Organic Chemistry)
6th Edition
ISBN: 9781305080461
Author: John C. Gilbert, Stephen F. Martin
Publisher: Brooks Cole
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Chapter 6.3, Problem 6E
Interpretation Introduction
Interpretation: The compound’s affinity needs to be explained for the mobile phase relative to the stationary phase based on the principle of like dissolves like.
Concept introduction: Column chromatography is a large scale solid-liquid adsorption chromatographic technique that can separate multigram amounts of mixtures. This is a preparative version of thin layer chromatography that permits separation and isolation of products by collection of eluted fractions.
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Predicting the qualitative acid-base properties of salts
Consider the following data on some weak acids and weak bases:
base
acid
Κα
Kb
name
formula
name
formula
hydrocyanic acid
- 10
HCN
4.9 × 10
pyridine
C₂H₂N 1.7 × 10 9
acetic acid
HCH3CO2 1.8 × 10
5
hydroxylamine HONH2 1.1 × 10¯
8
Use this data to rank the following solutions in order of increasing pH. In other words, select a '1' next to the solution that will have the lowest pH, a '2' next to
the solution that will have the next lowest pH, and so on.
0.1 M KCN
solution
pH
choose one ✓
0.1 M C5H5NHCI
choose one ✓
0.1 M NaCH3CO2
choose one ✓
0.1 M HONH3Br
✓ choose one
1 (lowest)
2
3
4 (highest)
For this question please solve the first question. Please explain your thought process, the steps you took, and how you would tackle a similar problem. Thank you for your help!
Part C
A solution that is 0.040 M in HCIO4 and 0.046 M in HCI
Express your answer numerically to two decimal places.
ΜΕ ΑΣΦ
?
pH =
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Part D
A solution that is 1.08% HCl by mass (with a density of 1.01 g/mL)
Express your answer numerically to three decimal places.
ΜΕ ΑΣΦ
->
0
?
pH =
Chapter 6 Solutions
Experimental Organic Chemistry: A Miniscale & Microscale Approach (Cengage Learning Laboratory Series for Organic Chemistry)
Ch. 6.2 - Prob. 1ECh. 6.2 - Prob. 2ECh. 6.2 - Prob. 3ECh. 6.2 - Prob. 4ECh. 6.2 - Prob. 5ECh. 6.2 - Prob. 6ECh. 6.2 - Prob. 7ECh. 6.2 - Prob. 8ECh. 6.2 - Prob. 9ECh. 6.3 - Prob. 1E
Ch. 6.3 - Prob. 2ECh. 6.3 - Prob. 3ECh. 6.3 - Prob. 4ECh. 6.3 - Prob. 5ECh. 6.3 - Prob. 6ECh. 6.3 - Prob. 7ECh. 6.3 - Prob. 8ECh. 6.3 - Prob. 9ECh. 6.3 - Prob. 10ECh. 6.3 - Prob. 11ECh. 6.3 - Prob. 12ECh. 6.3 - Prob. 13ECh. 6.3 - Prob. 14ECh. 6.3 - Prob. 15ECh. 6.3 - Prob. 16ECh. 6.3 - Prob. 17ECh. 6.3 - Prob. 18ECh. 6.3 - Prob. 19ECh. 6.3 - Prob. 20ECh. 6.4 - Prob. 1ECh. 6.4 - Prob. 2ECh. 6.4 - Prob. 3ECh. 6.4 - Prob. 4ECh. 6.4 - Prob. 5E
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