CHEMISTRY:MOLECULAR...V.2 W/ACCESS
9th Edition
ISBN: 9781265927103
Author: SILBERBERG
Publisher: MCG CUSTOM
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Question
Chapter 6.1, Problem 6.2BFP
Interpretation Introduction
Interpretation:
Work done by the gas that expands from
Concept introduction:
Work
Here,
The conversion factor to convert
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Understanding how substituents activate
Rank each of the following substituted benzene molecules in order of which will react fastest (1) to slowest (4) by electrophilic
aromatic substitution.
Explanation
HN
NH2
Check
X
(Choose one)
(Choose one)
(Choose one)
(Choose one)
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Identifying electron-donating and electron-withdrawing effects on benzene
For each of the substituted benzene molecules below, determine the inductive and resonance effects the substituent will have on the
benzene ring, as well as the overall electron-density of the ring compared to unsubstituted benzene.
Inductive Effects
Resonance Effects
Overall Electron-Density
Molecule
CF3
O donating
O donating
O withdrawing
O withdrawing
O no inductive effects
O no resonance effects
electron-rich
electron-deficient
O similar to benzene
CH3
O donating
O withdrawing
O no inductive effects
O donating
O withdrawing
Ono resonance effects
O electron-rich
O electron-deficient
O similar to benzene
Explanation
Check
Х
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* Hint: Think back to Chem 1 solubility rules.
Follow Up Questions for Part B
12. What impact do the following disturbances to a system at equilibrium have on k, the rate constant
for the forward reaction? Explain. (4 pts)
a) Changing the concentration of a reactant or product. (2 pts)
b) Changing the temperature of an exothermic reaction. (2 pts)
of
Chapter 6 Solutions
CHEMISTRY:MOLECULAR...V.2 W/ACCESS
Ch. 6.1 - A sample of liquid absorbs 13.5 kJ of heat and...Ch. 6.1 - Prob. 6.1BFPCh. 6.1 - Prob. 6.2AFPCh. 6.1 - A gas-producing reaction occurs in a container...Ch. 6.2 - Nitroglycerine decomposes through a violent...Ch. 6.2 - Prob. 6.3BFPCh. 6.3 - Prob. 6.4AFPCh. 6.3 - Prob. 6.4BFPCh. 6.3 - Prob. 6.5AFPCh. 6.3 - A 33.2-g titanium bicycle part is added to 75.0 g...
Ch. 6.3 - When 25.0 mL of 2.00 M HNO3 and 50.0 mL of 1.00 M...Ch. 6.3 - Prob. 6.6BFPCh. 6.3 - Prob. 6.7AFPCh. 6.3 - Prob. 6.7BFPCh. 6.4 - Prob. 6.8AFPCh. 6.4 - Prob. 6.8BFPCh. 6.5 - Prob. 6.9AFPCh. 6.5 - Prob. 6.9BFPCh. 6.6 - Prob. 6.10AFPCh. 6.6 - Prob. 6.10BFPCh. 6.6 - Prob. 6.11AFPCh. 6.6 - Prob. 6.11BFPCh. 6 - Prob. 6.1PCh. 6 - Prob. 6.2PCh. 6 - Prob. 6.3PCh. 6 - Prob. 6.4PCh. 6 - Prob. 6.5PCh. 6 - Prob. 6.6PCh. 6 - Prob. 6.7PCh. 6 - Prob. 6.8PCh. 6 - Prob. 6.9PCh. 6 - A system releases 255 cal of heat to the...Ch. 6 - What is the change in internal energy (in J) of a...Ch. 6 - Prob. 6.12PCh. 6 - Prob. 6.13PCh. 6 - Thermal decomposition of 5.0 metric tons of...Ch. 6 - Prob. 6.15PCh. 6 - The external pressure on a gas sample is 2660...Ch. 6 - The nutritional calorie (Calorie) is equivalent to...Ch. 6 - If an athlete expends 1950 kJ/h, how long does it...Ch. 6 - Prob. 6.19PCh. 6 - Hot packs used by skiers produce heat via the...Ch. 6 - Prob. 6.21PCh. 6 - Prob. 6.22PCh. 6 - For each process, state whether ΔH is less than...Ch. 6 - Prob. 6.24PCh. 6 - Prob. 6.25PCh. 6 - Prob. 6.26PCh. 6 - Prob. 6.27PCh. 6 - Prob. 6.28PCh. 6 - Prob. 6.29PCh. 6 - Prob. 6.30PCh. 6 - Prob. 6.31PCh. 6 - Prob. 6.32PCh. 6 - What data do you need to determine the specific...Ch. 6 - Is the specific heat capacity of a substance an...Ch. 6 - Prob. 6.35PCh. 6 - Both a coffee-cup calorimeter and a bomb...Ch. 6 - Find q when 22.0 g of water is heated from 25.0°C...Ch. 6 - Calculate q when 0.10 g of ice is cooled from...Ch. 6 - A 295-g aluminum engine part at an initial...Ch. 6 - Prob. 6.40PCh. 6 - Two iron bolts of equal mass—one at 100.°C, the...Ch. 6 - Prob. 6.42PCh. 6 - Prob. 6.43PCh. 6 - Prob. 6.44PCh. 6 - Prob. 6.45PCh. 6 - A 30.5-g sample of an alloy at 93.0°C is placed...Ch. 6 - When 25.0 mL of 0.500 M H2SO4 is added to 25.0 mL...Ch. 6 - Prob. 6.48PCh. 6 - Prob. 6.49PCh. 6 - A chemist places 1.750 g of ethanol, C2H6O, in a...Ch. 6 - High-purity benzoic acid (C6H5COOH; ΔH for...Ch. 6 - Two aircraft rivets, one iron and the other...Ch. 6 - A chemical engineer burned 1.520 g of a...Ch. 6 - Prob. 6.54PCh. 6 - Prob. 6.55PCh. 6 - Prob. 6.56PCh. 6 - Consider the following balanced thermochemical...Ch. 6 - Prob. 6.58PCh. 6 - Prob. 6.59PCh. 6 - When 1 mol of KBr(s) decomposes to its elements,...Ch. 6 - Prob. 6.61PCh. 6 - Compounds of boron and hydrogen are remarkable for...Ch. 6 - Prob. 6.63PCh. 6 - Prob. 6.64PCh. 6 - Prob. 6.65PCh. 6 - Prob. 6.66PCh. 6 - Prob. 6.67PCh. 6 - Prob. 6.68PCh. 6 - Prob. 6.69PCh. 6 - Prob. 6.70PCh. 6 - Prob. 6.71PCh. 6 - Write the balanced overall equation (equation 3)...Ch. 6 - Prob. 6.73PCh. 6 - Prob. 6.74PCh. 6 - Prob. 6.75PCh. 6 - Prob. 6.76PCh. 6 - Prob. 6.77PCh. 6 - Prob. 6.78PCh. 6 - Prob. 6.79PCh. 6 - Prob. 6.80PCh. 6 - Prob. 6.81PCh. 6 - Prob. 6.82PCh. 6 - Calculatefor each of the following:
SiO2(s) +...Ch. 6 - Prob. 6.84PCh. 6 - Prob. 6.85PCh. 6 - The common lead-acid car battery produces a large...Ch. 6 - Prob. 6.87PCh. 6 - Prob. 6.88PCh. 6 - Prob. 6.89PCh. 6 - Prob. 6.90PCh. 6 - Prob. 6.91PCh. 6 - Prob. 6.92PCh. 6 - The following scenes represent a gaseous reaction...Ch. 6 - Prob. 6.94PCh. 6 - Prob. 6.95PCh. 6 - Prob. 6.96PCh. 6 - Prob. 6.97PCh. 6 - Prob. 6.98PCh. 6 - Prob. 6.99PCh. 6 - Prob. 6.100PCh. 6 - Prob. 6.101PCh. 6 - Prob. 6.102PCh. 6 - Prob. 6.103PCh. 6 - Prob. 6.104PCh. 6 - Prob. 6.105PCh. 6 - Prob. 6.106PCh. 6 - Liquid methanol (CH3OH) canbe used as an...Ch. 6 - Prob. 6.108P
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