Macroscale and Microscale Organic Experiments
Macroscale and Microscale Organic Experiments
7th Edition
ISBN: 9781337329552
Author: Kenneth L. Williamson; Katherine M. Masters
Publisher: Cengage Learning US
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Chapter 6, Problem 8Q
Interpretation Introduction

Interpretation:

Some examples of substances that sublime should be determined.

Concept introduction:

Sublimation is the conversion of a solid phase of a substance to the vapor phase and the vice-versa is known as a deposition. The amount of heat required for this conversion is known as heat of sublimation (ΔHsub). The conversion is as follows:

  GasDepositionSublimationSolid

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32. Consider a two-state system in which the low energy level is 300 J mol 1 and the higher energy level is 800 J mol 1, and the temperature is 300 K. Find the population of each level. Hint: Pay attention to your units. A. What is the partition function for this system? B. What are the populations of each level? Now instead, consider a system with energy levels of 0 J mol C. Now what is the partition function? D. And what are the populations of the two levels? E. Finally, repeat the second calculation at 500 K. and 500 J mol 1 at 300 K. F. What do you notice about the populations as you increase the temperature? At what temperature would you expect the states to have equal populations?
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