CHEMISTRY-TEXT
8th Edition
ISBN: 9780134856230
Author: Robinson
Publisher: PEARSON
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Textbook Question
Chapter 6, Problem 6.88SP
Calculate the overall energy change in kilojoules per mole for the formation of CaCl(s) from the elements. The following data are needed:
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Students have asked these similar questions
Given the following information, construct a Born-Haber
cycle to calculate the lattice energy of CrCl₂I(s):
Net energy change for the formation of CrCl₂I(s) =
-420 kJ/mol
Bond dissociation energy for I2(g)
=
+243 kJ/mol
Bond dissociation energy for Cl2(g)
for Cl2(g)
for 12(g) = +151 kJ/mol
Heat of sublimation for I2(s) = +62 kJ/mol
Heat of sublimation for Cr(s) = +397 kJ/mol
=
E₁₁ for Cr(g)
=
652 kJ/mol
E₁₂ for Cr(g)
==
1588 kJ/mol
E₁3 for Cr(g)
=
2882 kJ/mol
Eea for Cl(g)=-349 kJ/mol
===
Eea for I(g) = -295 kJ/mol
Given the following enthalpy values for Na and Cl, calculate the lattice energy of NaCl using the Born-
Haber cycle.
for Na = 107.5 kJ/mole
for Na = 495.8 kJ/mole
for Cl, = 242.6 kJ/mole
AHO
sublimation
AH
ionization energy
AHO
dissociation energy
ΔΗΡ
electron affinity TOr Cl, = -348.6 kJ/mole
AH
formation
for NaCl(s) = -4l1.2 kJ/mole
Which of the following combination of elements is the most reactive?
Cs and I
Na and Br
Cs and Br
K and I
Chapter 6 Solutions
CHEMISTRY-TEXT
Ch. 6 - Prob. 6.1PCh. 6 - APPLY 6.2 Which of the following sets of ions are...Ch. 6 - Which atom or ion has the largest radius:...Ch. 6 - Conceptual APPLY 6.4 Which of the following...Ch. 6 - Use the periodic table to order the elements from...Ch. 6 - Given the orbital filling diagrams for the valence...Ch. 6 - Which has the largest third ionization energy: Be,...Ch. 6 - Conceptual APPLY 6.8 The figure on the right...Ch. 6 - Order the following elements from least to most...Ch. 6 - Conceptual APPLY 6.10 Which of the indicated three...
Ch. 6 - What electron configuration does the strontium...Ch. 6 - Prob. 6.12ACh. 6 - Prob. 6.13PCh. 6 - APPLY 6.14 Calculate the energy of electrostatic...Ch. 6 - Which substance has the largest lattice energy:...Ch. 6 - One of the following pictures represents NaCl and...Ch. 6 - Prob. 6.17PCh. 6 - What structural features do ionic liquids havethat...Ch. 6 - PROBLEM 6.18 Compare the following two ionic...Ch. 6 - PROBLEM 6.19 An ionic liquid consisting of a bulky...Ch. 6 - Where on the periodic table would you find the...Ch. 6 - Which of the following spheres is likely to...Ch. 6 - Circle the approximate part or parts of the...Ch. 6 - Prob. 6.24CPCh. 6 - This figure represents the successive ionization...Ch. 6 - In the following drawings, red spheres represent...Ch. 6 - Which of the following drawings is more likely to...Ch. 6 - Prob. 6.28CPCh. 6 - Which of the following alkali metal halides has...Ch. 6 - Which of the following alkali metal halides has...Ch. 6 - Three binary compounds are represented on the...Ch. 6 - Prob. 6.32CPCh. 6 - Prob. 6.33CPCh. 6 - What is the difference between a covalent bond and...Ch. 6 - Prob. 6.35SPCh. 6 - What is the difference between a molecule and an...Ch. 6 - Prob. 6.37SPCh. 6 - How many protons and electrons are in each of the...Ch. 6 - What is the identity of the element X in the...Ch. 6 - Prob. 6.40SPCh. 6 - Prob. 6.41SPCh. 6 - Prob. 6.42SPCh. 6 - Prob. 6.43SPCh. 6 - What doubly positive ion has the following...Ch. 6 - Prob. 6.45SPCh. 6 - Prob. 6.46SPCh. 6 - Which element in the transition-metal series Sc...Ch. 6 - Prob. 6.48SPCh. 6 - Prob. 6.49SPCh. 6 - Order the following ions from smallest to largest:...Ch. 6 - Order the following ions from smallest to largest:...Ch. 6 - Which ion has a larger atomic radius, Cu+ or Cu2+...Ch. 6 - Which ion hasa larger atomic radius, Fe2+ or Fe3+...Ch. 6 - The following ions all have the same number of...Ch. 6 - Which of the ions Se2,F,O2 and Rb+ has the largest...Ch. 6 - Which group of elements in the periodic table has...Ch. 6 - Prob. 6.57SPCh. 6 - Which element in each of the following sets has...Ch. 6 - Order the elements in each set from the smallest...Ch. 6 - (a) Which has the smaller second ionization...Ch. 6 - (a) Which has the smaller fourth ionization...Ch. 6 - Three atoms have the following electron...Ch. 6 - Three atoms have the following electron...Ch. 6 - The first four ionization energies in kJ/mol of a...Ch. 6 - The first four ionization energies in kJ/mol of a...Ch. 6 - Prob. 6.66SPCh. 6 - Prob. 6.67SPCh. 6 - Prob. 6.68SPCh. 6 - Prob. 6.69SPCh. 6 - Why is energy usually released when an electron is...Ch. 6 - Why does ionization energy increase regularly...Ch. 6 - No element has a negative second electron...Ch. 6 - Why does phosphorus have a less negative electron...Ch. 6 - Prob. 6.74SPCh. 6 - What noble-gas configurations and charge are the...Ch. 6 - Each of the following pairs of elements will react...Ch. 6 - Each of the following pairs of elements will react...Ch. 6 - Element X reacts with element Y to give a product...Ch. 6 - Element X reacts with element Y to give a product...Ch. 6 - Calculate the energy change in kilojoules per mole...Ch. 6 - Prob. 6.81SPCh. 6 - Find the lattice energy of LiBr(s) in Table 6.3,...Ch. 6 - Look up the lattice energies in Table 6.3, and...Ch. 6 - Born-4-Iaber cycles, such as those shown in...Ch. 6 - Calculate a lattice energy for CaH2(s) in...Ch. 6 - Calculate the overall energy change in kilojoules...Ch. 6 - The estimated lattice energy for CsF2(s) is +2347...Ch. 6 - Calculate the overall energy change in kilojoules...Ch. 6 - Use the data in Problem 6.88 to calculate an...Ch. 6 - Use the data and the result in Problem 6.84 to...Ch. 6 - Prob. 6.91SPCh. 6 - Calculate overall energy changes in kilojoules per...Ch. 6 - Prob. 6.93SPCh. 6 - We saw in Section 6.7 that the reaction of solid...Ch. 6 - Draw a Born—Haber cycle for the reaction of sodium...Ch. 6 - Use the following information plus the data given...Ch. 6 - Prob. 6.97SPCh. 6 - Prob. 6.98SPCh. 6 - Order the following compounds according to their...Ch. 6 - Prob. 6.100MPCh. 6 - Heating elemental cesium and platinum together for...Ch. 6 - Given the following information, construct a...Ch. 6 - Consider the electronic structure of the element...Ch. 6 - Prob. 6.104MPCh. 6 - The ionization energy of an atom can be measured...
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- Given the following information: Li(s) → Li(g) Li(s) = 161 kJ/mol Heat of sublimation of HCI(g) → H(g) + Cl(g) Bond energy of HCI = 427 kJ/mol Li(g) → Li+(g) + e- lonization energy of Li(g) = 520. kJ/mol CI(g) + e- → CI-(g) Electron affinity of Cl(g) = -349 kJ/mol Li+(g) + Cl-(g) →→ LiC(s) Lattice energy of LİCI(s) = -829 kJ/mol H2(g) → 2H(g) Bond energy of H2 = 432 kJ/mol calculate the net change in energy for the reaction 2Li(s) + 2HCI(g) → 2LİCI(s) + H2(g) -179 kJ 362 kJ -70 kJ -572 kJ None esearrow_forwardConsider an ionic compound, MX, composed of generic metal M and generic, gaseous halogen X. • The enthalpy of formation of MX is AH; = -513 kJ/mol. • The enthalpy of sublimation of M is AHsub = 123 kJ/mol. • The ionization energy of M is IE = 465 kJ/mol. • The electron affinity of X is AHEA = -325 kJ/mol. (Refer to the hint). • The bond energy of X, is BE = 187 kJ/mol. Determine the lattice energy of MX. AHjattice -795.5 kJ/mol Incorrectarrow_forwardDraw the energy diagram of the reaction: Li(s) + ½F2 → LiF(s). Enthalpy (kJ/mol) Li(s) → Li(g) +155.2 Li(g) → Li+(g) + e +520 ½F2 →F(g) +75.3 F(g) + e → F-(g) -3arrow_forward
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