Given the following information, construct a Born-’Habercycle to calculate the lattice energy of CrCl 2 I ( s ) : Net energy change for the formation of CrCl 2 I ( s ) = − 42 0 kJ/mol Bond dissociation energy for Cl 2 ( g ) = + 243 kJ/mol Bond dissociation energy for I 2 ( g ) = + 151 kJ/mol Heat of sublimation for I 2 ( s ) = + 62 kJ/mol Heat of sublimation for Cr ( s ) = + 397 kJ/mol E i1 for Cr ( g ) = 652 kJ/mol E i2 for Cr ( g ) = 1588 kJ/mol E i3 for Cr ( g ) = 2882 kJ/mol E ea for Cl ( g ) = − 349 kJ/mol E ea for I ( g ) = − 295 kJ/mol
Given the following information, construct a Born-’Habercycle to calculate the lattice energy of CrCl 2 I ( s ) : Net energy change for the formation of CrCl 2 I ( s ) = − 42 0 kJ/mol Bond dissociation energy for Cl 2 ( g ) = + 243 kJ/mol Bond dissociation energy for I 2 ( g ) = + 151 kJ/mol Heat of sublimation for I 2 ( s ) = + 62 kJ/mol Heat of sublimation for Cr ( s ) = + 397 kJ/mol E i1 for Cr ( g ) = 652 kJ/mol E i2 for Cr ( g ) = 1588 kJ/mol E i3 for Cr ( g ) = 2882 kJ/mol E ea for Cl ( g ) = − 349 kJ/mol E ea for I ( g ) = − 295 kJ/mol
Solution Summary: The author describes the steps required to draw Born-Haber cycle of ionic solids from its constituent elements.
Given the following information, construct a Born-’Habercycle to calculate the lattice energy of
CrCl
2
I
(
s
)
:
Net energy change for the formation of CrCl
2
I
(
s
)
=
−
42
0
kJ/mol
Bond dissociation energy for Cl
2
(
g
)
=
+
243 kJ/mol
Bond dissociation energy for I
2
(
g
)
=
+
151 kJ/mol
Heat of sublimation for I
2
(
s
)
=
+
62 kJ/mol
Heat of sublimation for Cr
(
s
)
=
+
397 kJ/mol
E
i1
for Cr
(
g
)
=
652 kJ/mol
E
i2
for Cr
(
g
)
=
1588 kJ/mol
E
i3
for Cr
(
g
)
=
2882 kJ/mol
E
ea
for Cl
(
g
)
=
−
349 kJ/mol
E
ea
for I
(
g
)
=
−
295 kJ/mol
A complete tensile test was performed on a magnesium
specimen of 12 mm diameter and 30 mm length, until breaking.
The specimen is assumed to maintain a constant volume.
Calculate the approximate value of the actual stress at breaking.
TABLE. The tensile force F and the length of the specimen are
represented for each L until breaking.
F/N
L/mm
0
30,0000
30,0296
5000
10000 30,0592
15000 30,0888
20000
30,15
25000 30,51
26500
30,90
27000
31,50
26500
32,10
25000 32,79
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Calorimetry Concept, Examples and Thermochemistry | How to Pass Chemistry; Author: Melissa Maribel;https://www.youtube.com/watch?v=nSh29lUGj00;License: Standard YouTube License, CC-BY