General, Organic, and Biochemistry
10th Edition
ISBN: 9781260506198
Author: Denniston, Katherine
Publisher: MCGRAW-HILL HIGHER EDUCATION
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Chapter 6, Problem 6.82QP
Interpretation Introduction
Interpretation:
Concept introduction:
The passage of solvent molecule occurs across the semi-permeable membrane due to the difference in osmotic pressure of solution and pure solvent. Osmotic pressure is directly proportional to the concentration of the solute. That is, whenever there is a concentration gradient setup between the semi-permeable membrane, the solvent will move from its higher concentration to the lower.
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Part VII. The H-NMR of a compound with molecular formula C5 H 10 O2 is given below.
Find the following:
(a) The no. of protons corresponding to each signal in the spectra
(6) Give the structure of the compound and assign the signals to each
proton in the compound.
a
70.2
Integration Values
C5H10O2
b
47.7
C
46.5
d
69.5
3.6 3.5
3.4 3.3 3.2 3.1 3.0
2.9 2.8
2.7
2.6 2.5
2.4 2.3 2.2 2.1 2.0
Chemical Shift (ppm)
1.9
1.8
1.7 1.6
1.5
1.4 1.3 1.2
1.1 1.0
0.9 0.8
Part 111. 1 H-NMR spectrum of a compound with integration values in red is given below.
Answer the following:
(a) write the signals in the 'H-NMR spectrum to the corresponding protons on the structure
of the molecule below.
(b) Identify the theoretical multiplicities for each proton in the compound. Also give the possible.
complex splitting patterns assuming J values are not similar.
там
Br
22
2
3
6
4 7.2 7.0 6.8 6.6 6.4 6.2 6.0 5.8 5.6 5.4 5.2 5.0 4.8 4.6 4.4 4.2 4.0 3.8 3.6 3.4 3.2 3.0 2.8 2.6 2.4 2.2 2.0 1.8 1.6 1.4 1.2 1.0 0.8 0
Chemical Shift (ppm)
ra.
Br
2
3
6
6
2.5
2.4
2.3
2.2
2.1
2.0
1.9
1.8
1.7
1.6
1.5
1.4
1.3
1.2
1.1
1.0
0.9
0.8
Chemical Shift (ppm)
2
2
Br
7.3
7.2
7.1
7.0 6.9
6.7 6.6 6.5
6.4
6.3
6.2
6.1
6.0
Chemical Shift (ppm)
5.9
5.8 5.7
5.5 5.4 5.3 5.2
5.0 4.9
1600°
1538°C
1493°C
In the diagram, the letter L indicates
that it is a liquid. Indicate its
components in the upper region
where only L is indicated.
The
iron-iron carbide phase
diagram.
Temperature (°C)
1400
8
1394°C
y+L
1200
2.14
y, Austenite
10000
912°C
800a
0.76
0.022
600
400
(Fe)
a, Ferrite
Composition (at% C)
15
1147°C
a + Fe3C
2
3
Composition (wt% C)
L
2500
4.30
2000
y + Fe3C
727°C
1500
Cementite (Fe3C)
1000
4
5
6
6.70
Temperature (°F)
Chapter 6 Solutions
General, Organic, and Biochemistry
Ch. 6.1 - Describe how you would distinguish experimentally...Ch. 6.1 - Prob. 6.2QCh. 6.1 - Explain why, over time, a bottle of soft drink...Ch. 6.1 - Prob. 6.4QCh. 6.1 - Prob. 6.5QCh. 6.1 - Prob. 6.6QCh. 6.2 - Calculate the % (m/V) of 0.0600 L of solution...Ch. 6.2 - Prob. 6.2PPCh. 6.2 - Prob. 6.3PPCh. 6.2 - Prob. 6.4PP
Ch. 6.3 - Prob. 6.5PPCh. 6.3 - Prob. 6.6PPCh. 6.3 - Prob. 6.7PPCh. 6.3 - Prob. 6.7QCh. 6.3 - Prob. 6.8QCh. 6.3 - Prob. 6.8PPCh. 6.3 - Prob. 6.9PPCh. 6.4 - Prob. 6.9QCh. 6.4 - Comparing pure water and a 0.10 m glucose...Ch. 6.4 - Prob. 6.10PPCh. 6.4 - Prob. 6.11PPCh. 6.4 - Prob. 6.12PPCh. 6.4 - Prob. 6.13PPCh. 6.4 - Prob. 6.11QCh. 6.4 - Prob. 6.12QCh. 6.5 - Prob. 6.14PPCh. 6.5 - Prob. 6.15PPCh. 6.5 - Prob. 6.16PPCh. 6.5 - Prob. 6.13QCh. 6.5 - Prob. 6.14QCh. 6 - Prob. 6.15QPCh. 6 - Prob. 6.16QPCh. 6 - Which of the following solute(s) would form an...Ch. 6 - Prob. 6.18QPCh. 6 - Prob. 6.19QPCh. 6 - Prob. 6.20QPCh. 6 - Prob. 6.21QPCh. 6 - Prob. 6.22QPCh. 6 - Prob. 6.23QPCh. 6 - Prob. 6.24QPCh. 6 - Prob. 6.25QPCh. 6 - Prob. 6.26QPCh. 6 - Prob. 6.27QPCh. 6 - Prob. 6.28QPCh. 6 - The Henry’s law constant, k, for O2 in aqueous...Ch. 6 - The Henry’s law constant, k, for N2 in aqueous...Ch. 6 - Calculate the composition of each of the following...Ch. 6 - Calculate the composition of each of the following...Ch. 6 - Calculate the composition of each of the following...Ch. 6 - Calculate the composition of each of the following...Ch. 6 - Prob. 6.35QPCh. 6 - Calculate the composition of each of the following...Ch. 6 - Prob. 6.37QPCh. 6 - Prob. 6.38QPCh. 6 - Prob. 6.39QPCh. 6 - Prob. 6.40QPCh. 6 - Prob. 6.41QPCh. 6 - Prob. 6.42QPCh. 6 - Prob. 6.43QPCh. 6 - Prob. 6.44QPCh. 6 - Which solution is more concentrated: a 0.04% (m/m)...Ch. 6 - Which solution is more concentrated: a 20 ppt...Ch. 6 - Prob. 6.47QPCh. 6 - Prob. 6.48QPCh. 6 - Prob. 6.49QPCh. 6 - Prob. 6.50QPCh. 6 - Why is it often necessary to dilute solutions in...Ch. 6 - Write the dilution expression and define each...Ch. 6 - Prob. 6.53QPCh. 6 - Prob. 6.54QPCh. 6 - Prob. 6.55QPCh. 6 - Prob. 6.56QPCh. 6 - Calculate the volume of a 0.500 M sucrose solution...Ch. 6 - Calculate the volume of a 1.00 × 10−2 M KOH...Ch. 6 - It is desired to prepare 0.500 L of a 0.100 M...Ch. 6 - A 50.0-mL sample of a 0.250 M sucrose solution was...Ch. 6 - A 50.0-mL portion of a stock solution was diluted...Ch. 6 - Prob. 6.62QPCh. 6 - Prob. 6.63QPCh. 6 - Prob. 6.64QPCh. 6 - Prob. 6.65QPCh. 6 - Prob. 6.66QPCh. 6 - Prob. 6.67QPCh. 6 - Prob. 6.68QPCh. 6 - Prob. 6.69QPCh. 6 - Prob. 6.70QPCh. 6 - Prob. 6.71QPCh. 6 - Prob. 6.72QPCh. 6 - Prob. 6.73QPCh. 6 - Prob. 6.74QPCh. 6 - Prob. 6.75QPCh. 6 - Prob. 6.76QPCh. 6 - Prob. 6.77QPCh. 6 - Prob. 6.78QPCh. 6 - Answer Questions 6.79–6.82 based on the following...Ch. 6 - Answer Questions 6.79–6.82 based on the following...Ch. 6 - Answer Questions 6.79–6.82 based on the following...Ch. 6 - Answer Questions 6.79–6.82 based on the following...Ch. 6 - Prob. 6.83QPCh. 6 - Prob. 6.84QPCh. 6 - Prob. 6.85QPCh. 6 - Prob. 6.86QPCh. 6 - Prob. 6.87QPCh. 6 - Prob. 6.88QPCh. 6 - Prob. 6.89QPCh. 6 - Prob. 6.90QPCh. 6 - Prob. 6.91QPCh. 6 - Prob. 6.92QPCh. 6 - Prob. 6.93QPCh. 6 - Prob. 6.94QPCh. 6 - Prob. 6.95QPCh. 6 - Name the two most important cations in biological...Ch. 6 - Prob. 6.97QPCh. 6 - Explain why a dialysis solution must have an...Ch. 6 - Prob. 6.99QPCh. 6 - Prob. 6.100QPCh. 6 - Prob. 6.101QPCh. 6 - Prob. 6.102QPCh. 6 - Prob. 6.103QPCh. 6 - What type of solute dissolves readily in benzene...Ch. 6 - Prob. 6.105QPCh. 6 - Prob. 6.106QPCh. 6 - Prob. 6.107QPCh. 6 - Prob. 6.108QPCh. 6 - Prob. 6.109QPCh. 6 - Prob. 6.110QPCh. 6 - Prob. 6.111QPCh. 6 - Prob. 6.112QPCh. 6 - Prob. 6.113QPCh. 6 - Prob. 6.114QPCh. 6 - Prob. 1MCPCh. 6 - Prob. 2MCPCh. 6 - Prob. 3MCPCh. 6 - Prob. 4MCPCh. 6 - Prob. 5MCPCh. 6 - Prob. 6MCPCh. 6 - Prob. 7MCPCh. 6 - Prob. 8MCPCh. 6 - Prob. 9MCPCh. 6 - Prob. 10MCP
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