BURDGE CHEMISTRY VALUE ED (LL)
4th Edition
ISBN: 9781259995958
Author: VALUE EDITION
Publisher: MCG CUSTOM
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Chapter 6, Problem 67QP
Interpretation Introduction
Interpretation:
The similarities and differences between the
Concept introduction:
A three-dimensional space in an atom, where the probability of finding an electron is the maximum, is called its atomic orbital. An atomic orbital can only accommodate
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Part VII. The H-NMR of a compound with molecular formula C5 H 10 O2 is given below.
Find the following:
(a) The no. of protons corresponding to each signal in the spectra
(6) Give the structure of the compound and assign the signals to each
proton in the compound.
a
70.2
Integration Values
C5H10O2
b
47.7
C
46.5
d
69.5
3.6 3.5
3.4 3.3 3.2 3.1 3.0
2.9 2.8
2.7
2.6 2.5
2.4 2.3 2.2 2.1 2.0
Chemical Shift (ppm)
1.9
1.8
1.7 1.6
1.5
1.4 1.3 1.2
1.1 1.0
0.9 0.8
Part 111. 1 H-NMR spectrum of a compound with integration values in red is given below.
Answer the following:
(a) write the signals in the 'H-NMR spectrum to the corresponding protons on the structure
of the molecule below.
(b) Identify the theoretical multiplicities for each proton in the compound. Also give the possible.
complex splitting patterns assuming J values are not similar.
там
Br
22
2
3
6
4 7.2 7.0 6.8 6.6 6.4 6.2 6.0 5.8 5.6 5.4 5.2 5.0 4.8 4.6 4.4 4.2 4.0 3.8 3.6 3.4 3.2 3.0 2.8 2.6 2.4 2.2 2.0 1.8 1.6 1.4 1.2 1.0 0.8 0
Chemical Shift (ppm)
ra.
Br
2
3
6
6
2.5
2.4
2.3
2.2
2.1
2.0
1.9
1.8
1.7
1.6
1.5
1.4
1.3
1.2
1.1
1.0
0.9
0.8
Chemical Shift (ppm)
2
2
Br
7.3
7.2
7.1
7.0 6.9
6.7 6.6 6.5
6.4
6.3
6.2
6.1
6.0
Chemical Shift (ppm)
5.9
5.8 5.7
5.5 5.4 5.3 5.2
5.0 4.9
1600°
1538°C
1493°C
In the diagram, the letter L indicates
that it is a liquid. Indicate its
components in the upper region
where only L is indicated.
The
iron-iron carbide phase
diagram.
Temperature (°C)
1400
8
1394°C
y+L
1200
2.14
y, Austenite
10000
912°C
800a
0.76
0.022
600
400
(Fe)
a, Ferrite
Composition (at% C)
15
1147°C
a + Fe3C
2
3
Composition (wt% C)
L
2500
4.30
2000
y + Fe3C
727°C
1500
Cementite (Fe3C)
1000
4
5
6
6.70
Temperature (°F)
Chapter 6 Solutions
BURDGE CHEMISTRY VALUE ED (LL)
Ch. 6.1 - Practice ProblemATTEMPT What is the frequency (in...Ch. 6.1 - Prob. 1PPBCh. 6.1 - Practice Problem CONCEPTUALIZE
Which of the...Ch. 6.1 - Prob. 1CPCh. 6.1 - Calculate the frequency of light with wavelength...Ch. 6.1 - Prob. 3CPCh. 6.1 - Prob. 4CPCh. 6.2 - Practice Problem ATTEMPT
Calculate the difference...Ch. 6.2 - Prob. 1PPBCh. 6.2 - Prob. 1PPC
Ch. 6.2 - Prob. 1CPCh. 6.2 - Prob. 2CPCh. 6.2 - Prob. 3CPCh. 6.2 - Prob. 4CPCh. 6.3 - Prob. 1PPACh. 6.3 - Practice Problem BUILD
(a) Calculate the...Ch. 6.3 - Prob. 1PPCCh. 6.3 - Prob. 1CPCh. 6.3 - Prob. 2CPCh. 6.3 - Prob. 3CPCh. 6.3 - Prob. 4CPCh. 6.4 - Prob. 1PPACh. 6.4 - Prob. 1PPBCh. 6.4 - Prob. 1PPCCh. 6.4 - Prob. 1CPCh. 6.4 - Prob. 2CPCh. 6.5 - Practice ProblemATTEMPT Calculate the de Broglie...Ch. 6.5 - Prob. 1PPBCh. 6.5 - Prob. 1PPCCh. 6.5 - What is the minimum uncertainty in the position of...Ch. 6.5 - Prob. 2CPCh. 6.6 - Prob. 1PPACh. 6.6 - Prob. 1PPBCh. 6.6 - Prob. 1PPCCh. 6.6 - Prob. 1CPCh. 6.6 - Prob. 2CPCh. 6.6 - Prob. 3CPCh. 6.6 - Prob. 4CPCh. 6.7 - Practice Problem ATTEMPT
(a) What are the possible...Ch. 6.7 - Practice ProblemBUILD (a) What is the lowest...Ch. 6.7 - Practice Problem CONCEPTUALIZE
Imagine a cobbler's...Ch. 6.7 - Prob. 1CPCh. 6.7 - Prob. 2CPCh. 6.7 - Prob. 3CPCh. 6.7 - Prob. 4CPCh. 6.8 - Prob. 1PPACh. 6.8 - Prob. 1PPBCh. 6.8 - Prob. 1PPCCh. 6.8 - Prob. 1CPCh. 6.8 - What element is represented by the following...Ch. 6.8 - Which orbital diagram is correct for the...Ch. 6.9 - Practice Problem ATTEMPT
Write the electron...Ch. 6.9 - Prob. 1PPBCh. 6.9 - Prob. 1PPCCh. 6.9 - Prob. 1CPCh. 6.9 - Prob. 2CPCh. 6.9 - 6.9.3 Which of the following is a d-block element?...Ch. 6.9 - Prob. 4CPCh. 6.10 - Practice ProblemATTEMPT Without referring to...Ch. 6.10 - Practice ProblemBUILD Without referring to Figure...Ch. 6.10 - Practice ProblemCONCEPTUALIZE Consider again the...Ch. 6 - Key Skills Problems What is the noble gas core for...Ch. 6 - Which of the following electron configurations...Ch. 6 - What element is represented by the electron...Ch. 6 - What is the electron configuration of the Lu atom?...Ch. 6 - What is a wave? Using a diagram, define the...Ch. 6 - 6.2 What are the units for wavelength and...Ch. 6 - List the types of electromagnetic radiation having...Ch. 6 - 6.4 Give the high and low wavelength values that...Ch. 6 - (a) What is the wavelength (in nm) of light having...Ch. 6 - 6.6 (a) What is the frequency of light having a...Ch. 6 - 6.7 The SI unit of time is the second, which is...Ch. 6 - 6.8 How many minutes would it take a radio wave to...Ch. 6 - The average distance between Mars and Earth is...Ch. 6 - 6.10 Four waves represent light in four different...Ch. 6 - Briefly explain Planck’s quantum theory and...Ch. 6 - Prob. 12QPCh. 6 - 6.13 Explain what is meant by the photoelectric...Ch. 6 - 6.14 What are photons? What role did Einstein’s...Ch. 6 - A photon has a wavelength of 705 nm. Calculate the...Ch. 6 - The blue color of the sky results from the...Ch. 6 - 6.17 A photon has a frequency of . (a) Convert...Ch. 6 - What is the wavelength (in nm) of radiation that...Ch. 6 - When copper is bombarded with high energy...Ch. 6 - 6.20 A particular form of electromagnetic...Ch. 6 - The retina of a human eye can detect light when...Ch. 6 - The radioactive 60 Co isotope is used in nuclear...Ch. 6 - Photosynthesis makes use of visible light or bring...Ch. 6 - A red light was shined onto a metal sample and the...Ch. 6 - A photoelectric experiment was performed by...Ch. 6 - What are emission spectra? How do line spectra...Ch. 6 - What is an energy level? Explain the difference...Ch. 6 - Briefly describe Bohr's theory of the hydrogen...Ch. 6 - The first line of the Balmer series occurs at a...Ch. 6 - 6.30 Calculate the wavelength (in nm) of a photon...Ch. 6 - Calculate the frequency (Hz) and wavelength (nm)...Ch. 6 - Careful spectral analysis shows that the familiar...Ch. 6 - 6.33 An electron in the hydrogen atom makes a...Ch. 6 - 6.34 Consider the following energy levels of a...Ch. 6 - Some copper compounds emit green light when they...Ch. 6 - Is it possible for a fluorescent material to emit...Ch. 6 - Explain how astronomers are able to tell which...Ch. 6 - How does do Broglie's hypothesis account for the...Ch. 6 - 6.39 Why is Equation 6.9 meaningful only for...Ch. 6 - Does a baseball in flight possess wave properties?...Ch. 6 - 6.41 Thermal neutrons are neutrons that move at...Ch. 6 - Protons can be accelerated to speeds near that of...Ch. 6 - 6.43 What is the de Broglie wavelength (in cm) of...Ch. 6 - 6.44 What is the de Broglie wavelength (in nm)...Ch. 6 - Prob. 45QPCh. 6 - Prob. 46QPCh. 6 - Prob. 47QPCh. 6 - How is the concept of electron density used to...Ch. 6 - 6.49 What is an atomic orbital? How does an atomic...Ch. 6 - 6.50 Alveoli are tiny sacs of air in the lungs....Ch. 6 - 6.51 The speed of a thermal neutron (see Problem...Ch. 6 - 6.52 In the beginning of the twentieth century,...Ch. 6 - Prob. 53QPCh. 6 - Prob. 54QPCh. 6 - Which quantum number defines a shell? Which...Ch. 6 - Prob. 56QPCh. 6 - Prob. 57QPCh. 6 - Prob. 58QPCh. 6 - Prob. 59QPCh. 6 - Prob. 60QPCh. 6 - Prob. 61QPCh. 6 - 6.62 List the hydrogen orbitals in increasing...Ch. 6 - Prob. 63QPCh. 6 - Prob. 64QPCh. 6 - Prob. 65QPCh. 6 - Give the values of the four quantum numbers of an...Ch. 6 - Prob. 67QPCh. 6 - Prob. 68QPCh. 6 - Why do the 3s, 3p, and 3d orbitals have the same...Ch. 6 - Prob. 70QPCh. 6 - Prob. 71QPCh. 6 - Prob. 72QPCh. 6 - Prob. 73QPCh. 6 - Prob. 74QPCh. 6 - Prob. 75QPCh. 6 - Prob. 76QPCh. 6 - Prob. 77QPCh. 6 - Prob. 78QPCh. 6 - Prob. 79QPCh. 6 - Prob. 80QPCh. 6 - Prob. 81QPCh. 6 - Prob. 82QPCh. 6 - Indicate the number of unpaired electrons present...Ch. 6 - Prob. 84QPCh. 6 - Prob. 85QPCh. 6 - Prob. 86QPCh. 6 - Describe the characteristics of transition metals.Ch. 6 - What is the noble gas core? How does it simplify...Ch. 6 - Prob. 89QPCh. 6 - Prob. 90QPCh. 6 - 6.91 Explain why the ground-state electron...Ch. 6 - 6.92 Write the electron configuration of a xenon...Ch. 6 - Prob. 93QPCh. 6 - Prob. 94QPCh. 6 - Prob. 95QPCh. 6 - Prob. 96QPCh. 6 - 6.97 Write the ground-state electron...Ch. 6 - Prob. 98APCh. 6 - Discuss the current view of the correctness of the...Ch. 6 - Distinguish carefully between the following terms:...Ch. 6 - Prob. 101APCh. 6 - Identify the following individuals and their...Ch. 6 - Prob. 103APCh. 6 - Prob. 104APCh. 6 - Prob. 105APCh. 6 - Prob. 106APCh. 6 - Prob. 107APCh. 6 - 6.108 Ionization energy is the minimum energy...Ch. 6 - Prob. 109APCh. 6 - Prob. 110APCh. 6 - Prob. 111APCh. 6 - All molecules undergo vibrational motions. Quantum...Ch. 6 - When an electron makes a transition between energy...Ch. 6 - Prob. 114APCh. 6 - Prob. 115APCh. 6 - Prob. 116APCh. 6 - 6.11 The wave function for the is orbital in the...Ch. 6 - Prob. 118APCh. 6 - Prob. 119APCh. 6 - Prob. 120APCh. 6 - 6.121 Calculate the wavelength and frequency of an...Ch. 6 - Prob. 122APCh. 6 - 6.123 In a photoelectric experiment a student uses...Ch. 6 - Prob. 124APCh. 6 - Prob. 125APCh. 6 - Prob. 126APCh. 6 - Prob. 127APCh. 6 - Prob. 128APCh. 6 - Prob. 129APCh. 6 - Prob. 130APCh. 6 - Prob. 131APCh. 6 - Prob. 132APCh. 6 - 6.133 Blackbody radiation is the term used to...Ch. 6 - Prob. 134APCh. 6 - Prob. 135APCh. 6 - How many photons at 586 nm must be absorbed to...Ch. 6 - Prob. 137APCh. 6 - Prob. 1SEPPCh. 6 - Prob. 2SEPPCh. 6 - What is the energy of a photon with wavelength λ...Ch. 6 - The visible region of the electromagnetic spectrum...
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