Introductory Chemistry: Foundation - Text (Looseleaf)
9th Edition
ISBN: 9781337399623
Author: ZUMDAHL
Publisher: Cengage
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Chapter 6, Problem 66AP
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13. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the
molecule depicted below.
Bond B
Bond A
Bond C
a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in
appropriate boxes.
Weakest
Bond
Strongest
Bond
b. (4pts) Consider the relative stability of all cleavage products that form when bonds A,
B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B,
and C are all carbon radicals.
i. Which ONE cleavage product is the most stable? A condensed or bond line
representation is fine.
ii. Which ONE cleavage product is the least stable? A condensed or bond line
representation is fine.
c. (5pts) Use principles discussed in lecture, supported by relevant structures, to
succinctly explain the why your part b (i) radical is more stable than your part b(ii)
radical. Written explanation can be no more than one-two succinct sentence(s)!
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Statifically more chances to abstract one of these 6H
11. (10pts total) Consider the radical chlorination of 1,3-diethylcyclohexane depicted below. 4
4th total
• 6H total
래
• 4H total
21 total
ZH
2H
Statistical
H < 3° C-H weakest
-
product
abstraction here
bund
leads to thermo favored
a) (6pts) How many unique mono-chlorinated products can be formed and what are the
structures for the thermodynamically and statistically favored products?
Product
6
Number of Unique
Mono-Chlorinated Products
Thermodynamically
Favored Product
Statistically
Favored Product
b) (4pts) Draw the arrow pushing mechanism for the FIRST propagation step (p-1) for the
formation of the thermodynamically favored product. Only draw the p-1 step. You do
not need to include lone pairs of electrons. No enthalpy calculation necessary
H
H-Cl
Waterfox
10. (5pts) Provide the complete arrow pushing mechanism for the chemical transformation →
depicted below
Use proper curved arrow notation that explicitly illustrates all bonds being broken, and
all bonds formed in the transformation.
Also, be sure to include all lone pairs and formal charges on all atoms involved in the
flow of electrons.
CH3O
II
HA
H
CH3O-H
H
①
Chapter 6 Solutions
Introductory Chemistry: Foundation - Text (Looseleaf)
Ch. 6.2 - Prob. 6.1SCCh. 6.3 - Prob. 1CTCh. 6.3 - One part of the problem-solving strategy for...Ch. 6.3 - Prob. 6.2SCCh. 6.3 - Prob. 6.3SCCh. 6 - The following are actual student responses to the...Ch. 6 - Prob. 2ALQCh. 6 - Given the equation for the reaction:N2+H2NH3 ,...Ch. 6 - Prob. 4ALQCh. 6 - Can the subscripts in a chemical formula be...
Ch. 6 - Prob. 6ALQCh. 6 - Changing the subscripts of chemicals can...Ch. 6 - Table 6.1 lists some clues that a chemical...Ch. 6 - Use molecular-level drawings to show the...Ch. 6 - It is stated in Section 6.3 of the text that to...Ch. 6 - Prob. 11ALQCh. 6 - Consider the generic chemical equationaA+bBcC+dD...Ch. 6 - Prob. 13ALQCh. 6 - Which of the following correctly describes the...Ch. 6 - Which of the following correctly balances the...Ch. 6 - The reaction of an element X() with element Y() is...Ch. 6 - Prob. 1QAPCh. 6 - Prob. 2QAPCh. 6 - Although these days many people have...Ch. 6 - Prob. 4QAPCh. 6 - You have probably had the unpleasant experience of...Ch. 6 - If you’ve ever left bread in a toaster too long,...Ch. 6 - What are the substances to theleftof the arrow in...Ch. 6 - Prob. 8QAPCh. 6 - In a chemical reaction, the total number of atoms...Ch. 6 - Prob. 10QAPCh. 6 - Prob. 11QAPCh. 6 - The notation “(l)” after a substance’s formula...Ch. 6 - A common experiment to determine the relative...Ch. 6 - A common lecture demonstration called “elephant’s...Ch. 6 - If a sample of pure hydrogen gas is ignited very...Ch. 6 - Liquid hydrazine, has been used as a fuel for...Ch. 6 - If electricity of sufficient voltage is passed...Ch. 6 - Silver oxide may be decomposed by strong heating...Ch. 6 - Elemental boron is produced in one industrial...Ch. 6 - Many over-the-counter antacid tablets are now...Ch. 6 - Phosphorus trichloride is used in the manufacture...Ch. 6 - Pure silicon, which is needed in the manufacturing...Ch. 6 - Nitrous oxide gas (systematic name: dinitrogen...Ch. 6 - Solid zinc is added to an aqueous solution...Ch. 6 - Acetylene gas (C2H2) is often used by plumbers,...Ch. 6 - The burning of high-sulfur fuels has been shown to...Ch. 6 - The Group 2 metals (Ba, Ca, Sr) can be produced in...Ch. 6 - There are fears that the protective ozone layer...Ch. 6 - Carbon tetrachloride was widely used for many...Ch. 6 - When elemental phosphorus, P4, burns in oxygen...Ch. 6 - Calcium oxide is sometimes very challenging to...Ch. 6 - Prob. 32QAPCh. 6 - The element tin often occurs in nature as the...Ch. 6 - Nitric acid, HNO3 , can be produced by reacting...Ch. 6 - When balancing chemical equations, beginning...Ch. 6 - The “Chemistry in Focus” segment The Beetle That...Ch. 6 - Balance each of the following chemical equations....Ch. 6 - Balance the equations for the reaction of...Ch. 6 - Balance each of the following chemical equations....Ch. 6 - Balance each of the following chemical equations....Ch. 6 - Balance each of the following chemical equations....Ch. 6 - Prob. 42QAPCh. 6 - Prob. 43QAPCh. 6 - Prob. 44QAPCh. 6 - Acetylene gas, C2H2 , is used in welding because...Ch. 6 - When balancing a chemical equation, which of the...Ch. 6 - Crude gunpowders often contain a mixture of...Ch. 6 - The following demonstration takes place in a...Ch. 6 - Methanol (methyl alcohol), CH3OH , is a very...Ch. 6 - The Hall process is an important method by which...Ch. 6 - Iron oxide ores, commonly a mixture of FeO and...Ch. 6 - True or false? Coefficients can be fractions when...Ch. 6 - When steel wool (iron) is heated in pure oxygen...Ch. 6 - One method of producing hydrogen peroxide is to...Ch. 6 - When elemental boron, B, is burned in oxygen gas,...Ch. 6 - A common experiment in introductory chemistry...Ch. 6 - A common demonstration in chemistry courses...Ch. 6 - Write a balanced chemical equation for the...Ch. 6 - Prob. 59APCh. 6 - Prob. 60APCh. 6 - If you had a “sour stomach,” you might try an...Ch. 6 - When iron wire is heated in the presence of...Ch. 6 - When finely divided solid sodium is dropped into a...Ch. 6 - If aqueous solutions of potassium chromate and...Ch. 6 - When hydrogen sulfide, H2S , gas is bubbled...Ch. 6 - If an electric current is passed through aqueous...Ch. 6 - When a strip of magnesium metal is heated in...Ch. 6 - Prob. 68APCh. 6 - When solid red phosphorus, is burned in air, the...Ch. 6 - When copper (II) oxide is boiled in an aqueous...Ch. 6 - When lead(II) sulfide is heated lo high...Ch. 6 - Which of the following statements about chemical...Ch. 6 - Prob. 73APCh. 6 - Prob. 74APCh. 6 - Prob. 75APCh. 6 - Using different shapes to distinguish between...Ch. 6 - Which of the following statements about chemical...Ch. 6 - Prob. 78CPCh. 6 - Balance the following chemical equations....
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- Do the Lone Pairs get added bc its valence e's are a total of 6 for oxygen and that completes it or due to other reasons. How do we know the particular indication of such.arrow_forwardNGLISH b) Identify the bonds present in the molecule drawn (s) above. (break) State the function of the following equipments found in laboratory. Omka) a) Gas mask b) Fire extinguisher c) Safety glasses 4. 60cm³ of oxygen gas diffused through a porous hole in 50 seconds. How long w 80cm³ of sulphur(IV) oxide to diffuse through the same hole under the same conditions (S-32.0.0-16.0) (3 m 5. In an experiment, a piece of magnesium ribbon was cleaned with steel w clean magnesium ribbon was placed in a crucible and completely burnt in oxy cooling the product weighed 4.0g a) Explain why it is necessary to clean magnesium ribbon. Masterclass Holiday assignmen PB 2arrow_forwardHi!! Please provide a solution that is handwritten. Ensure all figures, reaction mechanisms (with arrows and lone pairs please!!), and structures are clearly drawn to illustrate the synthesis of the product as per the standards of a third year organic chemistry course. ****the solution must include all steps, mechanisms, and intermediate structures as required. Please hand-draw the mechanisms and structures to support your explanation. Don’t give me AI-generated diagrams or text-based explanations, no wordy explanations on how to draw the structures I need help with the exact mechanism hand drawn by you!!! I am reposting this—ensure all parts of the question are straightforward and clear or please let another expert handle it thanks!!arrow_forward
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- Hi!! Please provide a solution that is handwritten. this is an inorganic chemistry question please answer accordindly!! its just one question with parts JUST ONE QUESTION with its parts spread out till part (g), please answer EACH part till the end and dont just provide wordy explanations wherever asked for structures, please DRAW DRAW them on a paper and post clearly!! answer the full question with all calculations step by step EACH PART CLEARLY please thanks!! im reposting this please solve all parts and drawit not just word explanations!!arrow_forwardHi!! Please provide a solution that is handwritten. this is an inorganic chemistry question please answer accordindly!! its just one question with parts JUST ONE QUESTION, please answer EACH part PART A AND PART B!!!!! till the end and dont just provide wordy explanations wherever asked for structures, please DRAW DRAW them on a paper and post clearly!! answer the full question with all details EACH PART CLEARLY please thanks!! im reposting this please solve all parts and drawit not just word explanations!!arrow_forwardHi!! Please provide a solution that is handwritten. this is an inorganic chemistry question please answer accordindly!! its just one question with parts JUST ONE QUESTION, please answer EACH part till the end and dont just provide wordy explanations wherever asked for structures, please DRAW DRAW them on a paper and post clearly!! answer the full question with all details EACH PART CLEARLY please thanks!! im reposting this please solve all parts and drawit not just word explanations!!arrow_forward
- 8b. Explain, using key intermediates, why the above two products are formed instead of the 1,2-and 1,4- products shown in the reaction below. CIarrow_forward(5pts) Provide the complete arrow pushing mechanism for the chemical transformation depicted below Use proper curved arrow notation that explicitly illustrates all bonds being broken, and all bonds formed in the transformation. Also, be sure to include all lone pairs and formal charges on all atoms involved in the flow of electrons. CH3O H I I CH3O-H H I ① Harrow_forward6. Draw the products) formed from the following reactions. (a) HIarrow_forward
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