Concept explainers
(a)
Interpretation: The carbon radical which is formed by homolysis of the
Concept introduction: The formation of carbocation, carbanion and free radical occur due to the heterolysis or homolysis process. Homolysis is opposite to the heterolysis. It forms radical with an unpaired electron.
Resonance is the delocalisation of
(b)
Interpretation: The carbon radical which is formed by homolysis of the
Concept introduction: The formation of carbocation, carbanion and free radical occur due to the heterolysis or homolysis process. Homolysis is opposite to the heterolysis. It forms radical with an unpaired electron.
Resonance is the delocalisation of
(c)
Interpretation: The weaker
Concept introduction: The energy which is released or absorbed in the
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Chapter 6 Solutions
Organic Chemistry
- Draw the simplest mechanism possible for the reaction below. You may need to re-draw structures to show bond lines or lone pairs. Note to advanced students: There may be more than one resonance structure for one of your products. Make sure the mechanism you draw creates the resonance structure that's shown. བྱི “དབྱིན 1:| ཐ ད ན “ 1 ཀྱིས .CN + CN + ח'arrow_forward4. A student wants to make molecule B with the following reaction below. Instead of molecule B, a different molecule is made. Give the structure of this compound. HO HO OH H₂NOH * HO N OH HO B OHarrow_forward10. Draw the most stable resonance form for the intermediate in the following electrophilic substitution reaction.arrow_forward
- 40arrow_forwardDraw the least stable resonance form for the intermediate in the following electrophilic substitution reaction.arrow_forwardCarvone is the major constituent of spearmint oil. Draw the major organic product of the reaction of carvone with HOCH2CH2OH, HCI. Carvone • You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. • Do not include lone pairs in your answer. They will not be considered in the grading. • In cases where there is more than one answer, just draw one. • If no reaction occurs, draw the organic starting material. + Sn 1arrow_forward
- N,N-diethyl-m-toluamide (DEET) is the active ingredient in many insect repellent preparations. Following is one of the steps in its synthesis. In the box below draw the structure of the product of this reaction. H3C MgBr 1. CO2 2. H3O+ product • You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. • Do not include lone pairs in your answer. They will not be considered in the grading. • Draw the Grignard reagent as a covalent magnesium bromide. 90-87 0 + 11 ? n [arrow_forwardNucleophiles will love to attack a nucleus. WHY? Explain how the molecules below are nucleophiles.arrow_forwardWhy is less energy required to break a C-H bond to form a more highly substituted radical? Can somebody summarize the words on this page to make it more understandable?arrow_forward
- The compound below is treated with chlorine in the presence of light. CH3 CH3CHCH₂CH3 Draw the structure for the organic radical species produced by reaction of the compound with a chlorine atom. Assume reaction occurs at the weakest C-H bond. • You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. n [ ]# ?arrow_forwardPredict the products of this organic reaction: Pt + 2 H₂ ? Specifically, in the drawing area below draw the skeletal ("line") structure of each product. If there's more than one product, you can draw them in any arrangement you like. If there is no reaction, check the No reaction box under the drawing area. No reaction. Click and drag to start drawing a structure. D: G ם P dlo Ararrow_forward8. Draw structural formulas for the major organic product(s) of the reaction shown below.arrow_forward
Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage Learning