The energy in J and the wavelength associated with given NMR signal needs to be calculated. Concept introduction: The formula relating energy with frequency is: E = hf The formula relating energy with wavelength is: E = h c λ E = Energy h = Planck constant f = Frequency c = speed of light λ= wavelength

Question

Protecting Groups and Carbonyls 6) The synthesis generates allethrolone that exhibits high insect toxicity but low mammalian toxicity. They are used in pet shampoo, human lice shampoo, and industrial sprays for insects and mosquitos. Propose detailed mechanistic steps to generate the allethrolone label the different types of reagents (Grignard, acid/base protonation, acid/base deprotonation, reduction, oxidation, witting, aldol condensation, Robinson annulation, etc.) III + VI HS HS H+ CH,CH,Li III I II IV CI + P(Ph)3 V ༼ Hint: no strong base added VI S VII IX HO VIII -MgBr HgCl2,HgO HO. isomerization aqeuous solution H,SO, ༽༽༤༽༽ X MeOH Hint: enhances selectivity for reaction at the S X ☑

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Chapter 6, Problem 6.4QAP

Interpretation Introduction

Interpretation:

The energy in J and the wavelength associated with given NMR signal needs to be calculated.

Concept introduction:

The formula relating energy with frequency is:

E = hf

The formula relating energy with wavelength is:

E=hcλ

E = Energy

h = Planck constant

f = Frequency

c = speed of light

λ= wavelength

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