ORGANIC CHEM PRINT STUDY GDE & SSM
ORGANIC CHEM PRINT STUDY GDE & SSM
4th Edition
ISBN: 9781119810650
Author: Klein
Publisher: WILEY
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Chapter 6, Problem 64CP

(a)

Interpretation Introduction

Interpretation:

The curved arrow must be shown for the Lewis acid mediated transformation of compound 1 to compound 2.

Concept Introduction :

The Lewis acids are those which can accept lone pair of electrons. These may enhance the reactivity of groups like oxygen by coordinating with it.

(b)

Interpretation Introduction

Interpretation:

The curved arrow must be shown for the transformation of compound 2 to compound 3.

Concept Introduction :

The Cyclopropane ring is very strained ring which is very reactive towards ring opening reaction. This ring contains 49°28’ angle strain.

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(a) Show that the lattice energies are inversely proportional to the distance between ions in MX (M = alkali metal, X = halide ions) by plotting the lattice energies of KF, KCl, and KI against the internuclear distances, dMX. The lattice energies of KF, KCl, and KI are 826, 717, and 645 kJ/mol, respectively. Does the correlation obtained correlate well? You will need to use a standard graphing program to construct the graph (such as a spreadsheet program). It will generate an equation for the line and calculate a correlation coefficient. (b) Estimate the lattice energy of KBr from your graph. (c) Find an experimental value for the lattice energy of KBr in the literature, and compare this value with the one calculated in (b). Do they agree?
Show the curved arrow mechanism and both products for the reaction between methyl iodide and propoxide. 1st attempt NV H 10: H H 1 Add the missing curved arrow notation. H + See Periodic Table
First I wanted to see if you would mind checking my graphs behind me. (They haven't been coming out right)? Second, could you help me explain if the rate of reaction is proportional to iodide and persulfate of each graph. I highlighted my answer and understanding but I'm not sure if I'm on the right track. Thank you in advance.
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