
Principles of General, Organic, Biological Chemistry
2nd Edition
ISBN: 9780073511191
Author: Janice Gorzynski Smith Dr.
Publisher: McGraw-Hill Education
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Chapter 6, Problem 6.44AP
Interpretation Introduction
Interpretation:
The values of psi has to be converted to
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Manoharan Mariappan, Ph.D., Dept. of Natur. Sci., NFC, Tallahassee, FL
33) Synthesize the aromatic compound containing para-substituted carbonyl compound starting from
benzene. Illustrate the mechanism for reaction A.
1)
NU
(25 pts)
A
FeCl
B
(i) HNO3, H2SO4
(II) Sn, HCl(aq)
NH₂
NO₂-D NH₂
(i) MeCO2Me, heat
C
(ii) K2Cr2O7/H2SO4
D
(ii) SOCl2
(iii) 2 Et-NH2
Mechanism for reaction for the nitration of alkyl benzene (B-i):
Characterize the product compound arising from the reaction D by IR and IH NMR spectral data:
IR data (cm):
'H NMR data: Draw the structure and assign the chemical shift with the spin-splitting.
Write structural formulas for the major products by
doing addition reactions
1. You must add H2 as Pt is catalyst it does not take part in reactions
only speed up the process
H₂
CH2=CH-CH3
Pt
2. Add HCI break it into H and Cl
CH3
HCI
3. Add Br2 only CC14 is catalyst
CH3-CH=CH2
B12
CCl4
4. Add water to this and draw major product, H2SO4 is catalyst you have add
water H20 in both the reaction below
H₂SO4
CH3-CH=CH2
CH3
H2SO4/H₂O
CH3-C=CH2
reflux
?
Plan the synthesis of the following compound using the starting
material provided and any other reagents needed as long as
carbon based reagents have 3 carbons or less. Either the
retrosynthesis or the forward synthesis (mechanisms are not
required but will be graded if provided) will be accepted if all
necessary reagents and intermediates are shown (solvents and
temperature requirements are not needed unless specifically
involved in the reaction, i.e. DMSO in the Swern oxidation or
heat in the KMnO4 oxidation).
H
H
Chapter 6 Solutions
Principles of General, Organic, Biological Chemistry
Ch. 6.1 - Typical atmospheric pressure in Denver is 630 mm...Ch. 6.1 - Prob. 6.2PCh. 6.1 - Prob. 6.3PCh. 6.2 - Prob. 6.4PCh. 6.2 - Prob. 6.5PCh. 6.3 - A volume of 0.50 L of air at 37 C is expelled from...Ch. 6.3 - (a) A volume (25.0 L) of gas at 45 K is heated to...Ch. 6.3 - Prob. 6.8PCh. 6.4 - Prob. 6.9PCh. 6.4 - Prob. 6.10P
Ch. 6.4 - Prob. 6.11PCh. 6.5 - Prob. 6.12PCh. 6.6 - Prob. 6.13PCh. 6.6 - Prob. 6.14PCh. 6.6 - Prob. 6.15PCh. 6.6 - Prob. 6.16PCh. 6.7 - Prob. 6.17PCh. 6.7 - Prob. 6.18PCh. 6.7 - Prob. 6.19PCh. 6.8 - Prob. 6.20PCh. 6.8 - Prob. 6.21PCh. 6.8 - Prob. 6.22PCh. 6.9 - Prob. 6.25PCh. 6.9 - Prob. 6.26PCh. 6 - Prob. 6.27UKCCh. 6 - Prob. 6.28UKCCh. 6 - Prob. 6.29UKCCh. 6 - Prob. 6.30UKCCh. 6 - Prob. 6.31UKCCh. 6 - Prob. 6.32UKCCh. 6 - Prob. 6.33UKCCh. 6 - Prob. 6.34UKCCh. 6 - Prob. 6.35UKCCh. 6 - Prob. 6.36UKCCh. 6 - Prob. 6.37UKCCh. 6 - Prob. 6.38UKCCh. 6 - Prob. 6.39UKCCh. 6 - Prob. 6.40UKCCh. 6 - Prob. 6.41APCh. 6 - The lowest atmospheric pressure ever measured is...Ch. 6 - Prob. 6.43APCh. 6 - Prob. 6.44APCh. 6 - Prob. 6.45APCh. 6 - Prob. 6.46APCh. 6 - Prob. 6.47APCh. 6 - Prob. 6.48APCh. 6 - Prob. 6.49APCh. 6 - Prob. 6.50APCh. 6 - Prob. 6.51APCh. 6 - Prob. 6.52APCh. 6 - Prob. 6.53APCh. 6 - Prob. 6.54APCh. 6 - Prob. 6.55APCh. 6 - Prob. 6.56APCh. 6 - Prob. 6.57APCh. 6 - Prob. 6.58APCh. 6 - Prob. 6.59APCh. 6 - Prob. 6.60APCh. 6 - Prob. 6.61APCh. 6 - Prob. 6.62APCh. 6 - Prob. 6.63APCh. 6 - Prob. 6.64APCh. 6 - Prob. 6.65APCh. 6 - Prob. 6.66APCh. 6 - Prob. 6.67APCh. 6 - Prob. 6.68APCh. 6 - Prob. 6.69APCh. 6 - Prob. 6.70APCh. 6 - Prob. 6.71APCh. 6 - Prob. 6.72APCh. 6 - Prob. 6.73APCh. 6 - Prob. 6.74APCh. 6 - Prob. 6.75APCh. 6 - Prob. 6.77APCh. 6 - Prob. 6.79APCh. 6 - Prob. 6.81APCh. 6 - Prob. 6.82APCh. 6 - Prob. 6.83APCh. 6 - Prob. 6.84APCh. 6 - Prob. 6.85APCh. 6 - Prob. 6.86APCh. 6 - Prob. 6.87APCh. 6 - Prob. 6.88APCh. 6 - Prob. 6.89CP
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