Student Solutions Manual for Bettelheim/Brown/Campbell/Farrell/Torres' Introduction to General, Organic and Biochemistry, 11th
11th Edition
ISBN: 9781305081055
Author: Bettelheim, Frederick A.
Publisher: Cengage Learning
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Textbook Question
Chapter 6, Problem 6.40P
6-40 What is the molarity of each solution?
(a) 47 g of KCI dissolved in enough water to give 375 mL of solution
(b) 82.6 g of sucrose, C12H22O11, dissolved in enough water to give 725 mL of solution
(c) 9.3 g of ammonium sulfate, (NH4)2SO4 dissolved in enough water to give 2.35 L of solution
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(a) Lead azide, Pb3(N3)3 has been used as a detonator in automobile airbags. A saturated solution of lead (IV) azide contains 25 mg in 100.0 mL What is Ksp?
Moles of Pb(N3)4 =
folarity of Pb(N3)4 =
mass
molar mass
0.025 g
375.2804 g / mol
= 6.66 ×10-5 mol
moles
volume (in L)
6.66 × 10-5 mol
1 L
1000 mL
= 6.66 ×10-4 M
100 mLx
The expression for the solubility product constant, Ksp iS
Ksp = [Pb4+][N3-]
= (s)(4s)4
= 256s5
= 256(6.66×10-4)5
= 3.3586×10-14
=3.4×10-14
How many grams of lead azide will dissolve in 500 mL of 100 M Pb(NO3)2 solution?
0180328145532
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PART B
Specify which of the following criteria should be met by a good solvent for a
recrystallisation by marking yes (Y) or no (N).
1.
(a)Solutes should bo soluble in cold solvent.
(b) Solvents should not react chemically with the solvent.
(c) Solvents should be polar rather than non-polar.
(d) Boiling point of solvent should be above 1000°C.
(e) Boiling point of the solvent should ideally be below the melting point of the
solute begun purified.
What is the molarity of each of the following solutions:(a) 15.0 g of Al2(SO4)3 in 0.250 mL solution, (b) 5.25 g ofMn(NO3)2 . 2 H2O in 175 mL of solution, (c) 35.0 mL of9.00 M H2SO4 diluted to 0.500 L?
Chapter 6 Solutions
Student Solutions Manual for Bettelheim/Brown/Campbell/Farrell/Torres' Introduction to General, Organic and Biochemistry, 11th
Ch. 6.5 - Problem 6-1 How would we prepare 250 mL of a 4.4%...Ch. 6.5 - Prob. 6.2PCh. 6.5 - Problem 6-3 How would we prepare 2.0 L of a 1.06 M...Ch. 6.5 - Prob. 6.4PCh. 6.5 - Problem 6-5 If a 0.300 M glucose solution is...Ch. 6.5 - Problem 6-6 A certain wine contains 0.010 M NaHSO3...Ch. 6.5 - Prob. 6.7PCh. 6.5 - Problem 6-8 A concentrated solution of 15% w/v KOH...Ch. 6.5 - Problem 6-9 Sodium hydrogen sulfate, NaHSO4, which...Ch. 6.8 - Prob. 6.10P
Ch. 6.8 - Prob. 6.11PCh. 6.8 - Prob. 6.12PCh. 6.8 - Problem 6-13 What is the osmolarity of a 3.3% w/v...Ch. 6.8 - Prob. 6.14PCh. 6 - 6-15 Answer true or false. (a) A solute is the...Ch. 6 - 6-16 Answer true or false. (a) Solubility is a...Ch. 6 - 6-17 Vinegar is a homogeneous aqueous solution...Ch. 6 - 6-18 Suppose you prepare a solution by dissolving...Ch. 6 - 6-19 In each of the following, tell whether the...Ch. 6 - 6-20 Give a familiar example of solutions of each...Ch. 6 - 6-21 Are mixtures of gases true solutions or...Ch. 6 - 6-22 Answer true or false. (a) Water is a good...Ch. 6 - 6-23 We dissolved 0.32 g of aspartic acid in 115.0...Ch. 6 - Prob. 6.24PCh. 6 - 6-25 A small amount of solid is added to a...Ch. 6 - 6-26 On the basis of polarity and hydrogen...Ch. 6 - Prob. 6.27PCh. 6 - 6-28 Which pairs of liquids are likely to be...Ch. 6 - Prob. 6.29PCh. 6 - 6-30 Near a power plant, warm water is discharged...Ch. 6 - 6-31 If a bottle of beer is allowed to stand for...Ch. 6 - 6-32 Would you expect the solubility of ammonia...Ch. 6 - Prob. 6.33PCh. 6 - Prob. 6.34PCh. 6 - 6-35 Describe how we would prepare the following...Ch. 6 - Prob. 6.36PCh. 6 - 6-37 Calculate the w/v percentage of each of these...Ch. 6 - 6-38 Describe how we would prepare 250 mL of 0.10...Ch. 6 - 6-39 Assuming that the appropriate volumetric...Ch. 6 - 6-40 What is the molarity of each solution? (a) 47...Ch. 6 - 6-41 A teardrop with a volume of 0.5 mL contains...Ch. 6 - Prob. 6.42PCh. 6 - 6-43 The label on a sparkling cider says it...Ch. 6 - Prob. 6.44PCh. 6 - 6-45 The label on ajar of jam says it contains 13...Ch. 6 - 6-46 A particular toothpaste contains 0.17 g NaF...Ch. 6 - 6-47 A student has a bottle labeled 0.750% albumin...Ch. 6 - 6-48 How many grams of solute are present in each...Ch. 6 - 6-49 A student has a stock solution of 30.0% w/v...Ch. 6 - Prob. 6.50PCh. 6 - Prob. 6.51PCh. 6 - Prob. 6.52PCh. 6 - 6-53 Dioxin is considered to be poisonous in...Ch. 6 - 6-54 An industrial wastewater contains 3.60 ppb...Ch. 6 - 6-55 According to the label on a piece of cheese,...Ch. 6 - Prob. 6.56PCh. 6 - Prob. 6.57PCh. 6 - Prob. 6.58PCh. 6 - Prob. 6.59PCh. 6 - 6-60 Predict which of these covalent compounds is...Ch. 6 - Prob. 6.61PCh. 6 - Prob. 6.62PCh. 6 - Prob. 6.63PCh. 6 - Prob. 6.64PCh. 6 - Prob. 6.65PCh. 6 - 6-66 What gives nanotubes their unique optical and...Ch. 6 - 6-67 Calculate the freezing points of solutions...Ch. 6 - 6-68 If we add 175 g of ethylene glycol, C2H6O2,...Ch. 6 - Prob. 6.69PCh. 6 - 6-70 In winter, after a snowstorm, salt (NaCI) is...Ch. 6 - 6-71 A 4 M acetic acid (CH3COOH) solution lowers...Ch. 6 - Prob. 6.72PCh. 6 - 6-73 In each case, tell which side (if either)...Ch. 6 - 6-74 An osmotic semipermeable membrane that allows...Ch. 6 - 6-75 Calculate the osmolarity of each of the...Ch. 6 - Prob. 6.76PCh. 6 - Prob. 6.77PCh. 6 - 6-78 (Chemical Connections 6A) Oxides of nitrogen...Ch. 6 - Prob. 6.79PCh. 6 - Prob. 6.80PCh. 6 - Prob. 6.81PCh. 6 - 6-82 (Chemical Connections 6C) A solution contains...Ch. 6 - 6-83 (Chemical Connections 6C) The concentration...Ch. 6 - 6-84 (Chemical Connections 6D) What is the...Ch. 6 - Prob. 6.85PCh. 6 - Prob. 6.86PCh. 6 - Prob. 6.87PCh. 6 - Prob. 6.88PCh. 6 - Prob. 6.89PCh. 6 - Prob. 6.90PCh. 6 - 6-91 When a cucumber is put into a saline solution...Ch. 6 - Prob. 6.92PCh. 6 - 6-93 Two bottles of water are carbonated, with CO2...Ch. 6 - Prob. 6.94PCh. 6 - Prob. 6.95PCh. 6 - 6-96 We know that a 0.89% saline (NaCI) solution...Ch. 6 - Prob. 6.97PCh. 6 - Prob. 6.98PCh. 6 - 6-99 A concentrated nitric acid solution contains...Ch. 6 - 6-100 Which will have greater osmotic pressure?...Ch. 6 - Prob. 6.101PCh. 6 - Prob. 6.102PCh. 6 - 6-103 A swimming pool containing 20,000. L of...Ch. 6 - Prob. 6.104PCh. 6 - Prob. 6.105PCh. 6 - Prob. 6.106PCh. 6 - Prob. 6.107PCh. 6 - Prob. 6.108PCh. 6 - Prob. 6.109PCh. 6 - Prob. 6.110PCh. 6 - 6-111 As noted in Section 6-8C, the amount of...Ch. 6 - 6-112 List the following aqueous solutions in...Ch. 6 - 6-113 List the following aqueous solutions in...
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- 6-38 Describe how we would prepare 250 mL of 0.10 M NaOH from solid NaOH and water.arrow_forward6-96 We know that a 0.89% saline (NaCI) solution is isotonic with blood. In a real-life emergency, you run out of physiological saline solution and have only KCI as a salt and distilled water. Would it be acceptable to make a 0.89% aqueous KCI solution and use it for intravenous infusion? Explain.arrow_forward6-103 A swimming pool containing 20,000. L of water is chlorinated to have a final CI2 concentration of 0.00500 M. What is the CI2 concentration in ppm? How many kilograms of CI2 were added to the swimming pool to reach this concentration?arrow_forward
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- 6-112 List the following aqueous solutions in order of increasing boiling point: 0.060 M glucose (C6H12O6), 0.025 M LiBr, and 0.025 M Zn(NO3)2.Assume complete dissociation of any salts.arrow_forward6-15 Answer true or false. (a) A solute is the substance dissolved in a solvent to form a solution. (b) A solvent is the medium in which a solute is dissolved to form a solution. (c) Some solutions can be separated into their components by filtration. (d) Acid rain is a solution.arrow_forward6-48 How many grams of solute are present in each of the following aqueous solutions? (a) 575 mL of a 2.00 M solution of nitric acid, HNO3 (b) 1.65 L of a 0.286 M solution of alanine, C3H7NO2 (c) 320 mL of a 0.0081 M solution of calcium sulfate, CaSO4arrow_forward
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