Bundle: Chemistry In Focus: A Molecular View Of Our World, 6th + Owlv2 6-month Printed Access Card
6th Edition
ISBN: 9781305618374
Author: Nivaldo J. Tro
Publisher: Cengage Learning
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Chapter 6, Problem 59E
Identify each compound according to its
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Technetium is the first element in the periodic chart that does not have any stable isotopes.
Technetium-99m is an especially interesting and valuable isotope as it emits a gamma ray with a half
life ideally suited for medical tests. It would seem that the decay of technetium should fit the
treatment above with the result In(c/c) = -kt. The table below includes data from the two sites:
http://dailymed.nlm.nih.gov/dailymed/druginfo.cfm?id=7130
http://wiki.medpedia.com/Clinical: Neutrospec_(Technetium_(99m Tc)_fanolesomab).
a.
b.
C.
Graph the fraction (c/c.) on the vertical axis versus the time on the horizontal axis. Also
graph In(c/c.) on the vertical axis versus time on the horizontal axis.
When half of the original amount of starting material has hours fraction remaining
disappeared, c/c = ½ and the equation In(c/c.) = -kt becomes
In(0.5) = -kt1/2 where t₁₂ is the half life (the time for half of the
material to decay away). Determine the slope of your In(c/c.) vs
t graph and…
Please correct answer and don't use hand rating
1.
a) Assuming that an atom of arsenic has hydrogen-like atomic orbitals, sketch the radial
probability plots for 4p and 4d orbitals of S atom. Indicate angular and radial nodes in
these orbitals.
(4 points)
b) Calculate Zeff experienced by and electron in 4p AO's in a arsenic atom. Use Slater rules
that were discussed in lecture.
(3 points)
Chapter 6 Solutions
Bundle: Chemistry In Focus: A Molecular View Of Our World, 6th + Owlv2 6-month Printed Access Card
Ch. 6 - Drawing Structural and Condensed Structural...Ch. 6 - Prob. 6.2YTCh. 6 - Drawing Structural Formulas for Isomers Draw...Ch. 6 - Prob. 6.4YTCh. 6 - What are the names of the straight-chain alkanes...Ch. 6 - Which structure corresponds to CH2=CHCH3?Ch. 6 - For the following molecule, why is the name...Ch. 6 - What property is characteristic of chlorinated...Ch. 6 - Prob. 5SCCh. 6 - Prob. 6SC
Ch. 6 - Prob. 7SCCh. 6 - Prob. 1ECh. 6 - Prob. 2ECh. 6 - Prob. 3ECh. 6 - Prob. 4ECh. 6 - What is vitalism? Why did vitalism become a...Ch. 6 - Prob. 6ECh. 6 - Prob. 7ECh. 6 - Prob. 8ECh. 6 - Prob. 9ECh. 6 - List four common fuels used by our society, and...Ch. 6 - Prob. 11ECh. 6 - Why are alkenes and alkynes called unsaturated...Ch. 6 - Prob. 13ECh. 6 - Prob. 14ECh. 6 - Prob. 15ECh. 6 - Prob. 16ECh. 6 - Prob. 17ECh. 6 - Prob. 18ECh. 6 - Prob. 19ECh. 6 - Prob. 20ECh. 6 - Prob. 21ECh. 6 - Prob. 22ECh. 6 - Prob. 23ECh. 6 - Prob. 24ECh. 6 - Prob. 25ECh. 6 - Prob. 26ECh. 6 - Prob. 27ECh. 6 - Prob. 28ECh. 6 - Prob. 29ECh. 6 - Prob. 30ECh. 6 - Prob. 31ECh. 6 - Prob. 32ECh. 6 - Prob. 33ECh. 6 - Prob. 34ECh. 6 - Prob. 35ECh. 6 - Prob. 36ECh. 6 - Prob. 37ECh. 6 - Prob. 38ECh. 6 - Prob. 39ECh. 6 - Prob. 40ECh. 6 - Prob. 41ECh. 6 - Prob. 42ECh. 6 - Naming Hydrocarbons Name each alkane:Ch. 6 - Name each alkane:Ch. 6 - Name each alkyne:Ch. 6 - Name each alkyne: a.CH3CHCHCH2CH2CH3Ch. 6 - Name each alkyne:Ch. 6 - Prob. 48ECh. 6 - Prob. 49ECh. 6 - Prob. 50ECh. 6 - Drawing Hydrocarbon Structures from Names Draw the...Ch. 6 - Draw the condensed structural formula for each...Ch. 6 - Prob. 53ECh. 6 - Prob. 54ECh. 6 - Prob. 55ECh. 6 - Prob. 56ECh. 6 - Functionalized Hydrocarbons Identify each compound...Ch. 6 - Identify each compound according to its functional...Ch. 6 - Identify each compound according to its functional...Ch. 6 - Identify each compound according to its functional...Ch. 6 - Propane, CH3CH2CH3, is a gas at room temperature,...Ch. 6 - Prob. 62ECh. 6 - What was the impact of vitalisms downfall on...Ch. 6 - Why do you think our society has mixed feelings...Ch. 6 - Prob. 65ECh. 6 - Prob. 66ECh. 6 - Prob. 67ECh. 6 - Any one molecule can be represented many ways. For...Ch. 6 - Explain why the formula CH3CH2CH3 cannot mean:...Ch. 6 - Prob. 70ECh. 6 - Prob. 71ECh. 6 - Prob. 72ECh. 6 - Prob. 73E
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- What is the pH of the Tris buffer after the addition of 10 mL of 0.01M NaOH? How would I calculate this?arrow_forwardWhy do isopolianions form polymeric species with a defined molecular weight? What does it depend on?arrow_forwardWhat are isopolianions? Describe the structural unit of isopolianions.arrow_forward
- Justify the polymerization of vanadates VO43-, as a function of concentration and pH.arrow_forwardWhat is the preparation of 500 mL of 100mM MOPS buffer (pH=7.5) starting with 1 M MOPS and 1 M NaOH? How would I calculate the math?arrow_forwardIndicate the correct option.a) Isopolianions are formed around metallic atoms in a low oxidation state.b) Non-metals such as N, S, C, Cl, ... give rise to polyacids (oxygenated).c) Both are incorrect.arrow_forward
- 14. Which one of the compounds below is the major organic product obtained from the following series of reactions? Br OH OH CH3O™ Na+ H*, H₂O SN2 HO OH A B C D 0 Earrow_forwardWavelength (nm) I'm not sure what equation I can come up with other than the one generated with my graph. Can you please show me the calculations that were used to find this equation? Give an equation that relates energy to wavelength. Explain how you arrived at your equation. Wavelength Energy (kJ/mol) (nm) 350 341.8 420 284.8 470 254.5 530 225.7 580 206.3 620 192.9 700 170.9 750 159.5 Energy vs. Wavelength (Graph 1) 400 350 y=-0.4367x+470.82 300 250 200 150 100 50 O 0 100 200 300 400 500 600 700 800 Energy (kJ/mol)arrow_forward5. Draw molecular orbital diagrams for superoxide (O2¯), and peroxide (O2²-). A good starting point would be MO diagram for O2 given in your textbook. Then: a) calculate bond orders in superoxide and in peroxide; indicate which species would have a stronger oxygen-oxygen bond; b) indicate which species would be a radical. (4 points)arrow_forward
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