Chemistry: The Molecular Science
5th Edition
ISBN: 9781285199047
Author: John W. Moore, Conrad L. Stanitski
Publisher: Cengage Learning
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Chapter 6, Problem 54QRT
Interpretation Introduction
Interpretation:
Which ions have longer Carbon-Oxygen bond lengths in Carbonate ion and in formate ion should be explained.
Concept Introduction:
Lewis structure is also known as Lewis dot diagrams or electron dot structures. The bond between atoms and lone pairs of electrons that is present in the molecule. Lewis structure represents each atom and their position in structure using the chemical symbol. Excess electrons forms the lone pair are given by pair of dots, and are located next to the atom.
According to the concept of resonance, when a single Lewis structure cannot describe a molecule accurately, a number of structures with same energy, position of nuclei, bonding and non-bonding pair of electrons are taken as the canonical structures of the hybrid which describes the molecule accurately.
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Students have asked these similar questions
==
Vid4Q2
Unanswered
☑
Provide IUPAC name of product in the reaction
below
A 3,4-dimethylcyclohexene
B 1,2-dimethylcyclohexane
C 1,2-dimethylcyclohexene
D 3,4-dimethylcyclohexane
H₂
Pd
5.
Use the MS data to answer the questions on the next page.
14.0
1.4
15.0
8.1
100-
MS-IW-5644
26.0
2.8
27.0
6.7
28.0
1.8
29.0
80
4.4
38.0
1.0
39.0
1.5
41.0
1.2
42.0
11.2
43.0
100.0
44.0
4.3
79.0
1.9
80.0
2.6
Relative Intensity
40
81.0
1.9
82.0
2.5
93.0
8.7
20-
95.0
8.2
121.0
2.0
123.0
2.0
136.0
11.8
0
138.0
11.5
20
40
8.
60
a.
Br
- 0
80
100
120
140
160
180
200
220
m/z
Identify the m/z of the base peak and molecular ion.
2
b.
Draw structures for each of the following fragments (include electrons and charges): 43.0, 93.0,
95.0, 136.0, and 138.0 m/z.
C.
Draw a reasonable a-fragmentation mechanism for the fragmentation of the molecular ion to
fragment 43.0 m/z. Be sure to include all electrons and formal charges.
6. Using the values provided in Appendix E of your lab manual, calculate the monoisotopic mass for the pyridinium
ion (CsH6N) and show your work.
None
Chapter 6 Solutions
Chemistry: The Molecular Science
Ch. 6.2 - Write Lewis structures for (a) NF3, (b) N2H4, and...Ch. 6.3 - Prob. 6.1ECh. 6.3 - Prob. 6.2PSPCh. 6.4 - Prob. 6.2CECh. 6.4 - Write Lewis structures for (a) nitrosyl ion, NO+;...Ch. 6.5 - Prob. 6.4CECh. 6.5 - Prob. 6.5CECh. 6.5 - Prob. 6.4PSPCh. 6.6 - Prob. 6.5PSPCh. 6.6 - Use Equation 6.1 and values from Table 6.2 to...
Ch. 6.6 - Prob. 6.6CECh. 6.7 - Prob. 6.7PSPCh. 6.7 - Prob. 6.7CECh. 6.8 - Prob. 6.8PSPCh. 6.9 - Prob. 6.9PSPCh. 6.9 - Prob. 6.9CECh. 6.10 - Prob. 6.10PSPCh. 6.11 - Prob. 6.10ECh. 6.11 - Prob. 6.11ECh. 6.11 - Prob. 1CECh. 6.11 - Prob. 2CECh. 6.12 - Repeat Problem-Solving Example 6.11, but use N2...Ch. 6.12 - Use MO theory to predict the bond order and the...Ch. 6 - Prob. 1QRTCh. 6 - Prob. 2QRTCh. 6 - Prob. 3QRTCh. 6 - Prob. 4QRTCh. 6 - Prob. 5QRTCh. 6 - Prob. 6QRTCh. 6 - Which of these molecules have an odd number of...Ch. 6 - Prob. 8QRTCh. 6 - Prob. 9QRTCh. 6 - Prob. 10QRTCh. 6 - Prob. 11QRTCh. 6 - Prob. 12QRTCh. 6 - Explain in your own words why the energy of two H...Ch. 6 - Prob. 14QRTCh. 6 - Prob. 15QRTCh. 6 - Prob. 16QRTCh. 6 - Prob. 17QRTCh. 6 - Prob. 18QRTCh. 6 - Prob. 19QRTCh. 6 -
Write Lewis structures for
tetracyanoethene,...Ch. 6 - Prob. 21QRTCh. 6 - Prob. 22QRTCh. 6 - Prob. 23QRTCh. 6 - Prob. 24QRTCh. 6 - Prob. 25QRTCh. 6 - Prob. 26QRTCh. 6 - Prob. 27QRTCh. 6 - Prob. 28QRTCh. 6 - Prob. 29QRTCh. 6 - For each pair of bonds, predict which is the...Ch. 6 - Prob. 31QRTCh. 6 - Prob. 32QRTCh. 6 - Which bond requires more energy to break: the...Ch. 6 -
Estimate ΔrH° for forming 2 mol ammonia from...Ch. 6 - Prob. 35QRTCh. 6 - Light of appropriate wavelength can break chemical...Ch. 6 - Prob. 37QRTCh. 6 - Prob. 38QRTCh. 6 - Prob. 39QRTCh. 6 - Acrolein is the starting material for certain...Ch. 6 - Prob. 41QRTCh. 6 - Prob. 42QRTCh. 6 - Write the correct Lewis structure and assign a...Ch. 6 - Prob. 44QRTCh. 6 - Prob. 45QRTCh. 6 - Two Lewis structures can be written for nitrosyl...Ch. 6 - Prob. 47QRTCh. 6 - Prob. 48QRTCh. 6 - Prob. 49QRTCh. 6 - Prob. 50QRTCh. 6 - Several Lewis structures can be written for...Ch. 6 - Prob. 52QRTCh. 6 - Prob. 53QRTCh. 6 - Prob. 54QRTCh. 6 - Prob. 55QRTCh. 6 - Draw resonance structures for each of these ions:...Ch. 6 - Three known isomers exist of N2CO, with the atoms...Ch. 6 - Write the Lewis structure for (a) BrF5 (b) IF5 (c)...Ch. 6 - Write the Lewis structure for
BrF3
XeF4
Ch. 6 - Prob. 60QRTCh. 6 - Prob. 61QRTCh. 6 - Prob. 62QRTCh. 6 - All carbon-to-carbon bond lengths are identical in...Ch. 6 - Prob. 64QRTCh. 6 - Prob. 65QRTCh. 6 - Prob. 66QRTCh. 6 - Prob. 67QRTCh. 6 - Prob. 68QRTCh. 6 - Prob. 69QRTCh. 6 - Prob. 70QRTCh. 6 - Using just a periodic table (not a table of...Ch. 6 - The CBr bond length in CBr4 is 191 pm; the BrBr...Ch. 6 - Prob. 73QRTCh. 6 -
Acrylonitrile is the building block of the...Ch. 6 - Prob. 75QRTCh. 6 - Write Lewis structures for (a) SCl2 (b) Cl3+ (c)...Ch. 6 - Prob. 77QRTCh. 6 - Prob. 78QRTCh. 6 - A student drew this incorrect Lewis structure for...Ch. 6 - This Lewis structure for SF5+ is drawn...Ch. 6 - Tribromide, Br3, and triiodide, I3, ions are often...Ch. 6 - Explain why nonmetal atoms in Period 3 and beyond...Ch. 6 - Prob. 83QRTCh. 6 - Prob. 84QRTCh. 6 - Prob. 85QRTCh. 6 - Prob. 86QRTCh. 6 - Which of these molecules is least likely to exist:...Ch. 6 - Write the Lewis structure for nitrosyl fluoride,...Ch. 6 - Prob. 91QRTCh. 6 - Methylcyanoacrylate is the active ingredient in...Ch. 6 - Aspirin is made from salicylic acid, which has...Ch. 6 - Prob. 94QRTCh. 6 - Prob. 95QRTCh. 6 - Prob. 96QRTCh. 6 - Prob. 97QRTCh. 6 - Prob. 98QRTCh. 6 - Nitrosyl azide, N4O, is a pale yellow solid first...Ch. 6 - Write the Lewis structures for (a) (Cl2PN)3 (b)...Ch. 6 - Nitrous oxide, N2O, is a linear molecule that has...Ch. 6 - The azide ion, N3, has three resonance hybrid...Ch. 6 - Hydrazoic acid, HN3, has three resonance hybrid...Ch. 6 - Prob. 104QRTCh. 6 - Experimental evidence indicates the existence of...Ch. 6 - Prob. 106QRTCh. 6 - Prob. 107QRTCh. 6 - Pipeline, the active ingredient in black pepper,...Ch. 6 - Sulfur and oxygen form a series of 2 anions...Ch. 6 - Prob. 110QRTCh. 6 - Prob. 111QRTCh. 6 - Prob. 112QRTCh. 6 - Prob. 113QRTCh. 6 - Prob. 114QRTCh. 6 - Prob. 115QRTCh. 6 - Prob. 116QRTCh. 6 - Prob. 117QRTCh. 6 - Prob. 118QRTCh. 6 - Prob. 6.ACPCh. 6 - Prob. 6.BCPCh. 6 - Prob. 6.CCP
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