Organic Chemistry
Organic Chemistry
2nd Edition
ISBN: 9781118452288
Author: David R. Klein
Publisher: WILEY
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Chapter 6, Problem 52IP
Interpretation Introduction

Interpretation:

The impact of temperature on product formation should be predicted and justified.

Concept introduction:

Sigma bond: A molecular orbital forms end-to-end overlap of atomic orbitals which forms covalent bond is called sigma bond.

Pi bond: A molecular orbital forms end-to-end overlap of atomic orbitals which forms a covalent bond is called π bond.

General formula to calculate the Gibbs free energy is ΔG = ΔΗ –TΔS

ΔΗ = Enthalpy, ΔH is determined by the system not by the surrounding, a system that releases heat to the surrounding and it is called exothermic reaction and ΔΗ is negative.

ΔS = Entropy, a measure of the randomness of the system.

ΔS (Entropy) of the molecule should be identified by using further down formula.

ΔS = Number of products – Number of reactants

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