Selected Solutions Manual For General Chemistry: Principles And Modern Applications
11th Edition
ISBN: 9780133387902
Author: Ralph H. Petrucci, F. Geoffrey Herring, Jeffry D. Madura, Carey Bissonnette
Publisher: PEARSON
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Textbook Question
Chapter 6, Problem 52E
Hydrogen peroxide, H2O2, is used to disinfect contact lenses. How many milliliters of O2(g) at 22 °C and 1.00 bar can be liberated from 10.0 mL of an aqueous solution containing 3.00% H2O2 by mass? The density of the aqueous solution of H2O2 is 1.01 g/mL.
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Part VII. The H-NMR of a compound with molecular formula C5 H 10 O2 is given below.
Find the following:
(a) The no. of protons corresponding to each signal in the spectra
(6) Give the structure of the compound and assign the signals to each
proton in the compound.
a
70.2
Integration Values
C5H10O2
b
47.7
C
46.5
d
69.5
3.6 3.5
3.4 3.3 3.2 3.1 3.0
2.9 2.8
2.7
2.6 2.5
2.4 2.3 2.2 2.1 2.0
Chemical Shift (ppm)
1.9
1.8
1.7 1.6
1.5
1.4 1.3 1.2
1.1 1.0
0.9 0.8
Part 111. 1 H-NMR spectrum of a compound with integration values in red is given below.
Answer the following:
(a) write the signals in the 'H-NMR spectrum to the corresponding protons on the structure
of the molecule below.
(b) Identify the theoretical multiplicities for each proton in the compound. Also give the possible.
complex splitting patterns assuming J values are not similar.
там
Br
22
2
3
6
4 7.2 7.0 6.8 6.6 6.4 6.2 6.0 5.8 5.6 5.4 5.2 5.0 4.8 4.6 4.4 4.2 4.0 3.8 3.6 3.4 3.2 3.0 2.8 2.6 2.4 2.2 2.0 1.8 1.6 1.4 1.2 1.0 0.8 0
Chemical Shift (ppm)
ra.
Br
2
3
6
6
2.5
2.4
2.3
2.2
2.1
2.0
1.9
1.8
1.7
1.6
1.5
1.4
1.3
1.2
1.1
1.0
0.9
0.8
Chemical Shift (ppm)
2
2
Br
7.3
7.2
7.1
7.0 6.9
6.7 6.6 6.5
6.4
6.3
6.2
6.1
6.0
Chemical Shift (ppm)
5.9
5.8 5.7
5.5 5.4 5.3 5.2
5.0 4.9
1600°
1538°C
1493°C
In the diagram, the letter L indicates
that it is a liquid. Indicate its
components in the upper region
where only L is indicated.
The
iron-iron carbide phase
diagram.
Temperature (°C)
1400
8
1394°C
y+L
1200
2.14
y, Austenite
10000
912°C
800a
0.76
0.022
600
400
(Fe)
a, Ferrite
Composition (at% C)
15
1147°C
a + Fe3C
2
3
Composition (wt% C)
L
2500
4.30
2000
y + Fe3C
727°C
1500
Cementite (Fe3C)
1000
4
5
6
6.70
Temperature (°F)
Chapter 6 Solutions
Selected Solutions Manual For General Chemistry: Principles And Modern Applications
Ch. 6 - Convert each pressure to an equivalent pressure in...Ch. 6 - Prob. 2ECh. 6 - Calculate the height of a column of liquid benzene...Ch. 6 - Prob. 4ECh. 6 - Prob. 5ECh. 6 - What is the pressure (in mmHg) of the gas...Ch. 6 - At times, a pressure is stated in units of mass...Ch. 6 - Prob. 8ECh. 6 - A sample of O2(g) has a volume of 26.7 L at 762...Ch. 6 - An 886 mL sample of Ne(g) is at 752 mmHg 26 C....
Ch. 6 - Prob. 11ECh. 6 - We want to change the volume of a fixed amount of...Ch. 6 - Prob. 13ECh. 6 - A sample of N2(g) occupies a volume of 42.0 ml...Ch. 6 - Prob. 15ECh. 6 - Prob. 16ECh. 6 - Prob. 17ECh. 6 - Prob. 18ECh. 6 - Prob. 19ECh. 6 - Prob. 20ECh. 6 - Prob. 21ECh. 6 - Prob. 22ECh. 6 - A sample of gas has a volume of 4.25 L at 25.6 C...Ch. 6 - A 10.0 sample of a gas has a volume of 5.25 L at...Ch. 6 - Prob. 25ECh. 6 - Prob. 26ECh. 6 - What is the volume, in liters, occupied by 89.2 g...Ch. 6 - Prob. 28ECh. 6 - Kr(g) in a 18.5 L cylinder exerts a pressure of...Ch. 6 - Prob. 30ECh. 6 - A laboratory high vacuum system is capable of...Ch. 6 - What is the pressure, in pascals, exerted by 1242...Ch. 6 - What is the molar volume of an ideal gas at (a) 25...Ch. 6 - Prob. 34ECh. 6 - A 0.418 g sample of gas has a volume of 115 mL at...Ch. 6 - What is the molar mass of a gas found to have a...Ch. 6 - Whatis the molecular formula of a gaseous fluoride...Ch. 6 - A 2.650 g sample of a gaseous compound occupies...Ch. 6 - A gaseous hydrocarbon webbing 0.231 g occupies a...Ch. 6 - Prob. 40ECh. 6 - Prob. 41ECh. 6 - Monochloroethylene gas is used to make...Ch. 6 - In order for a gas-filled balloon to rise in air,...Ch. 6 - Prob. 44ECh. 6 - The density of phosphorus vapor is 2.64 g/L at 310...Ch. 6 - A particular gaseous hydrocarbon that is 82.7% C...Ch. 6 - Prob. 47ECh. 6 - Prob. 48ECh. 6 - Prob. 49ECh. 6 - Prob. 50ECh. 6 - Prob. 51ECh. 6 - Hydrogen peroxide, H2O2, is used to disinfect...Ch. 6 - Calculate the volume of H2(g), measured at 26 C...Ch. 6 - The Haber process is the principal method for...Ch. 6 - What is the volume. in liters, occupied by a...Ch. 6 - Prob. 56ECh. 6 - A gas cylinder of 53.7 L volume contains N2(g) at...Ch. 6 - Prob. 58ECh. 6 - Which actions you take to establish a pressure of...Ch. 6 - Prob. 60ECh. 6 - Prob. 61ECh. 6 - The chemical composition of air that is exhaled...Ch. 6 - In the drawing below, 1.00 g H2(g) is maintained...Ch. 6 - In the drawing above, 1.00 g H2(g) at 300 K is...Ch. 6 - Prob. 65ECh. 6 - Prob. 66ECh. 6 - A 1.65 g sample of Al reacts with excess HCI, and...Ch. 6 - An 89.3 mL sample of wet O2(g) is collected over...Ch. 6 - A sampleof O2(g) is collected over water at 24 C....Ch. 6 - Prob. 70ECh. 6 - At elevated temperatures, solid sodium chlorate...Ch. 6 - Prob. 72ECh. 6 - CalculateUnta,in meters per second, for CI2(g)...Ch. 6 - Prob. 74ECh. 6 - Prob. 75ECh. 6 - Prob. 76ECh. 6 - Prob. 77ECh. 6 - Determine um, u, and Urmafor a group often...Ch. 6 - Prob. 79ECh. 6 - Prob. 80ECh. 6 - If 0.00484 mol N2O(g) effuses through an orifice...Ch. 6 - Prob. 82ECh. 6 - What are the ratios of rates for the pairs of...Ch. 6 - Prob. 84ECh. 6 - Prob. 85ECh. 6 - The molar mass of radon gas was first estimated by...Ch. 6 - Prob. 87ECh. 6 - Use both the deal gas equation and the van der...Ch. 6 - Prob. 89ECh. 6 - (a) Use the value of the van der Waals constant b...Ch. 6 - Prob. 91IAECh. 6 - Assume the following initial conditions for the...Ch. 6 - Consider the diagram to the right. The "initial"...Ch. 6 - Two evacuated bubs of equal volume are connected...Ch. 6 - Prob. 95IAECh. 6 - A 0.7178 g sample of a hydrocarbon occupies a...Ch. 6 - Prob. 97IAECh. 6 - Ammonium nitrite, NH4NO2,decomposes according to...Ch. 6 - A mature of 100 g H2 and 860 g O2, introduced into...Ch. 6 - Prob. 100IAECh. 6 - What is the partial pressure of CI2(g) , in...Ch. 6 - Prob. 102IAECh. 6 - When working with a mixture of gases, it is...Ch. 6 - Prob. 104IAECh. 6 - Gas cylinder A has e volume of 48.2 L and contains...Ch. 6 - Prob. 106IAECh. 6 - Producer gas is a type of fuel gas made by passing...Ch. 6 - Prob. 108IAECh. 6 - A mixture of H2(g) and O2(g) is prepared by...Ch. 6 - Prob. 110IAECh. 6 - Prob. 111IAECh. 6 - A breathing mixture is prepared which He is...Ch. 6 - Chlorine dioxide,CIO2, is sometimes used as a...Ch. 6 - The amount of ozone, O2,in a mixture of gases can...Ch. 6 - Prob. 115IAECh. 6 - Prob. 116IAECh. 6 - We have noted that atmospheric pressure depends on...Ch. 6 - Consider a sample ofO2(g) at 298 K and 1.0 atm....Ch. 6 - A nitrogen molecule (N2) having the average...Ch. 6 - Prob. 120IAECh. 6 - Prob. 121IAECh. 6 - Prob. 122IAECh. 6 - Prob. 123IAECh. 6 - A 0.156 g sample of magnesium-aluminum alloy...Ch. 6 - Prob. 125FPCh. 6 - Prob. 126FPCh. 6 - Prob. 127FPCh. 6 - Prob. 128FPCh. 6 - Prob. 129FPCh. 6 - Prob. 130SAECh. 6 - Briefly describe each concept or process: (a)...Ch. 6 - Prob. 132SAECh. 6 - Which exerts the greatest pressure. (a) a 75.0 cm...Ch. 6 - Prob. 134SAECh. 6 - Prob. 135SAECh. 6 - A fragile glass vessel will break if the internal...Ch. 6 - Which of the following choices represents the...Ch. 6 - The gas with the greatest density at STP is (a)...Ch. 6 - Precisely 1mol of helium and 1 mol of neon are...Ch. 6 - Prob. 140SAECh. 6 - Prob. 141SAECh. 6 - Prob. 142SAECh. 6 - Prob. 143SAECh. 6 - At 0 C and 0.500 atm, 4.48 L of gaseous NH2(a)...Ch. 6 - To establish a pressure of 2.00 atm in a 2.24 L...Ch. 6 - Carbon monoxide, CO, and hydrogenreact according...Ch. 6 - A mixture of 5.010-5molH2(g) and 5.010-5molSO2(g)...Ch. 6 - Prob. 148SAECh. 6 - Prob. 149SAECh. 6 - Prob. 150SAECh. 6 - A gaseous hydrocarbon that is 82.7% C and 17.3% H...Ch. 6 - Draw a box to represent a sample of air containing...Ch. 6 - Prob. 153SAE
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Solutions: Crash Course Chemistry #27; Author: Crash Course;https://www.youtube.com/watch?v=9h2f1Bjr0p4;License: Standard YouTube License, CC-BY