Chemistry: Structure and Properties Custom Edition for Rutgers University General Chemistry
15th Edition
ISBN: 9781269935678
Author: Nivaldo J. Tro
Publisher: Pearson Education
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Chapter 6, Problem 49E
Interpretation Introduction
To find:
The Lewis structure of the given molecules
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Write Lewis structures for each of the following species. Use expanded octets as necessary.
I-3
Draw Lewis structures of the following. Select the structure(s) that do NOT obey the octet rule. (for molecules with resonance, consider the best structure by formal charge)
H2SO4
CH3-
AlCl3
NF3
PH3
Draw a Lewis structure for the following ions/molecules, including any resonance structures and/or formal charges. Place a box around any contributing resonance structures
XeO4^-2, BrF5, CHF2CL
What is the electron group geometry around the central atom for each of the above ions/molecules?
For the above ions/molecules, what is the shape of the entire molecule/ion of the entire ion/molecule?
Identify polar bonds with dipole arrows
Indicate whether each of the ions/molecules is POLAR or NON-POLAR
Chapter 6 Solutions
Chemistry: Structure and Properties Custom Edition for Rutgers University General Chemistry
Ch. 6 - Which set of elements is arranged in order of...Ch. 6 - Prob. 2SAQCh. 6 - Which pair of atoms forms the most polar bond? C...Ch. 6 - Which pair of atoms forms a nonpolar covalent...Ch. 6 - Prob. 5SAQCh. 6 - Prob. 6SAQCh. 6 - Prob. 7SAQCh. 6 - Prob. 8SAQCh. 6 - Prob. 9SAQCh. 6 - Prob. 10SAQ
Ch. 6 - Prob. 11SAQCh. 6 - Predict the relative bond angles in BF3 and SO2Ch. 6 - Predict the molecular geometry about N in the...Ch. 6 - Which molecule is polar?Ch. 6 - What is electronegativity? What are the periodic...Ch. 6 - Explain the difference between a pure covalent...Ch. 6 - What is meant by the percent ionic character of a...Ch. 6 - Prob. 4ECh. 6 - What is the magnitude of the dipole moment formed...Ch. 6 - What is the basic procedure for writing a covalent...Ch. 6 - How do you determine the number of electrons that...Ch. 6 - What are resonance structures? What is a resonance...Ch. 6 - Prob. 9ECh. 6 - Prob. 10ECh. 6 - Prob. 11ECh. 6 - Prob. 12ECh. 6 - What is bond energy?Ch. 6 - Give some examples of some typical bond lengths....Ch. 6 - Why is molecular geometry important? Cite some...Ch. 6 - According to VSEPR theory, what determines the...Ch. 6 - Name and draw the five basic electron geometries,...Ch. 6 - Explain the difference between electron geometry...Ch. 6 - List the correct electron and molecular geometries...Ch. 6 - How do you apply VSEPR theory to predict the shape...Ch. 6 - How do you determine if a molecule is polar?Ch. 6 - Why is polarity a key connection between the...Ch. 6 - Prob. 23ECh. 6 - Determine if a bond between each pair of atoms...Ch. 6 - Prob. 25ECh. 6 - Draw the Lewis structure for BrF with an arrow...Ch. 6 - Prob. 27ECh. 6 - Write the Lewis structure for each molecule. NF3...Ch. 6 - Prob. 29ECh. 6 - Write the Lewis structure for each molecule. CH2O...Ch. 6 - Prob. 31ECh. 6 - Prob. 32ECh. 6 - Write the Lewis structure for each molecule or ion...Ch. 6 - Prob. 34ECh. 6 - Write a Lewis structure that obeys the octet rule...Ch. 6 - Prob. 36ECh. 6 - Use formal charge to determine which Lewis...Ch. 6 - Prob. 38ECh. 6 - How important is this resonance structure to the...Ch. 6 - Prob. 40ECh. 6 - Prob. 41ECh. 6 - Prob. 42ECh. 6 - Determine the formal charges of the atoms shown in...Ch. 6 - Prob. 44ECh. 6 - Prob. 45ECh. 6 - Write the Lewis structure for each molecule (octet...Ch. 6 - Prob. 47ECh. 6 - Write Lewis structures for each molecule or ion....Ch. 6 - Prob. 49ECh. 6 - Write Lewis structures for each molecule or ion....Ch. 6 - List these compounds in order of increasing...Ch. 6 - Which of these compounds has the stronger...Ch. 6 - A molecule with the formula AB3 has a trigonal...Ch. 6 - A molecule with the formula AB3 has a trigonal...Ch. 6 - For each molecular geometry shown here, list the...Ch. 6 - For each molecular geometry shown here, list the...Ch. 6 - Determine the electron geometry, molecular...Ch. 6 - Determine the electron geometry, molecular...Ch. 6 - Which species has the smaller bond angle, H3O+ or...Ch. 6 - Which species has the smaller bond angle; C1O4- or...Ch. 6 - Determine the molecular geometry and draw each...Ch. 6 - Determine the molecular geometry and draw each...Ch. 6 - Determine the molecular geometry about each...Ch. 6 - Prob. 64ECh. 6 - Prob. 65ECh. 6 - Prob. 66ECh. 6 - Prob. 67ECh. 6 - Determine the geometry about each interior atom in...Ch. 6 - Explain why CO2 and CCl4 are both nonpolar even...Ch. 6 - CH3F is a polar molecule, even though the...Ch. 6 - Determine whether each molecule in Exercise 57 is...Ch. 6 - Prob. 72ECh. 6 - Determine whether each molecule or ion is polar or...Ch. 6 - Determine whether each molecule is polar or...Ch. 6 - Each compound contains both ionic and covalent...Ch. 6 - Prob. 76ECh. 6 - Carbon ring structures are common in organic...Ch. 6 - Prob. 78ECh. 6 - Prob. 79ECh. 6 - Diazomethane is a highly poisonous, explosive...Ch. 6 - Prob. 81ECh. 6 - Phosgene (Cl2CO) is a poisonous gas that was used...Ch. 6 - The cyanate ion (OCN-) and the fulminate ion...Ch. 6 - Prob. 84ECh. 6 - Prob. 85ECh. 6 - Prob. 86ECh. 6 - Prob. 87ECh. 6 - Prob. 88ECh. 6 - Prob. 89ECh. 6 - Free radicals are important in many...Ch. 6 - A compound composed of only carbon and hydrogen is...Ch. 6 - A compound composed of only carbon and chlorine is...Ch. 6 - Prob. 93ECh. 6 - The genetic code is based on four different bases...Ch. 6 - Prob. 95ECh. 6 - Prob. 96ECh. 6 - Prob. 97ECh. 6 - A 0.167-g sample of an unknown compound contains...Ch. 6 - Use the dipole moments of HF and HCI (given at the...Ch. 6 - One form of phosphorus exists as P4 molecules....Ch. 6 - A compound has the formula C8H8 and does not...Ch. 6 - Prob. 102ECh. 6 - The bond angles increase steadily in the series...Ch. 6 - Draw the Lewis structure for acetamide (CH3CONH2),...Ch. 6 - Prob. 105ECh. 6 - In the very first chapter of this book, we...Ch. 6 - Which statement best captures the fundamental idea...Ch. 6 - Prob. 108E
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- A polyatomic ion is composed of C, N, and an unknown element X. The skeletal Lewis structure of this polyatomic ion is [XCN]. The ion X2 has an electron configuration of [Ar]4s23d104p6. What is element X? Knowing the identity of X, complete the Lewis structure of the polyatomic ion, including all important resonance structures.arrow_forwardUsing the symbols and +, indicate the direction of polarity in each polar covalent bond. (a) CN (b) NO (c) CClarrow_forwardDraw Lewis structures for the following polyatomic ions. a. OH b. BeH42 c. AlCl4 d. NO3arrow_forward
- Write Lewis structures for these ions. Show all valence electrons and all formal charges. (a) Amide ion, NH2 (b) Bicarbonate ion, HCO3 (c) Carbonate ion, CO32 (d) Nitrate ion, NO3 (e) Formate ion, HCOO (f) Acetate ion, CH3COOarrow_forward• define electronegativity and state how electronegativity varies with position in the periodic table.arrow_forwardMany monatomic ions are found in seawater, including the ions formed from the following list of elements. Write the Lewis symbols for the monatomic ions formed from the following elements: (a) Cl (b) Na (c) Mg (d) Ca (e) K (f) Br (g) Sr (h) Farrow_forward
- Classify each bond as nonpolar covalent or polar covalent or state that ions are formed. (a) SH (b) PH (c) CF (d) CClarrow_forwardWhich statements are true about electronegativity? (a) Electronegativity increases from left to right in a period of the Periodic Table. (b) Electronegativity increases from top to bottom in a column of the Periodic Table. (c) Hydrogen, the element with the lowest atomic number, has the smallest electronegativity. (d) The higher the atomic number of an element, the greater its electronegativity.arrow_forwardSuccessive substitution of F atoms for H atoms in the molecule NH3 produces the molecules NH2F, NHF2, and NF3. a. Draw Lewis structures for each of the four molecules. b. Using VSEPR theory, predict the geometry of each of the four molecules. c. Specify the polarity (polar or nonpolar) for each of the four molecules.arrow_forward
- Draw Lewis structures for the following species. (The skeleton is indicated by the way the molecule is written.) (a) Cl2CO (b) H3CCNarrow_forwardDraw Lewis structures for the following species. (The skeleton is indicated by the way the molecule is written.) (a) Cl2CO (b) H3C—CN (c) H2C—CH2arrow_forwardWrite the Lewis structure for nitrosyl fluoride, FNO. Using only a periodic table, identify (a) which is the longer bond. (b) which is the stronger bond. (c) which is the more polar bond.arrow_forward
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