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OWLv2 for Moore/Stanitski's Chemistry: The Molecular Science, 5th Edition, [Instant Access], 1 term (6 months)
5th Edition
ISBN: 9781285460420
Author: John W. Moore; Conrad L. Stanitski
Publisher: Cengage Learning US
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Chapter 6, Problem 48QRT
Interpretation Introduction
Interpretation:
Lewis structure and formal charges to write resonance structure and the most plausible resonance form
Concept Introduction:
Lewis structure is also known as Lewis dot diagrams or electron dot structures. The bond between atoms and lone pairs of electrons that is present in the molecule. Lewis structure represents each atom and their position in structure using the chemical symbol. Excess electrons forms the lone pair are given by pair of dots, and are located next to the atom.
According to the concept of resonance, when a single Lewis structure cannot describe a molecule accurately, a number of structures with same energy, position of nuclei, bonding and non-bonding pair of electrons are taken as the canonical structures of the hybrid which describes the molecule accurately.
The formula for the formal charge can be written as
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Under aqueous basic conditions, nitriles will react to form a neutral organic intermediate 1 that has an N atom in it first, and then they will continue to react to
form the final product 2:
NC
H₂O
он-
H₂O
1
2
OH
Draw the missing intermediate 1 and the final product 2 in the box below. You can draw the two structures in any arrangement you like.
Click and drag to start drawing a
structure.
Assign these COSY Spectrum
Assign these C-NMR and H-NMR Spectrum
Chapter 6 Solutions
OWLv2 for Moore/Stanitski's Chemistry: The Molecular Science, 5th Edition, [Instant Access], 1 term (6 months)
Ch. 6.2 - Write Lewis structures for (a) NF3, (b) N2H4, and...Ch. 6.3 - Prob. 6.1ECh. 6.3 - Prob. 6.2PSPCh. 6.4 - Prob. 6.2CECh. 6.4 - Write Lewis structures for (a) nitrosyl ion, NO+;...Ch. 6.5 - Prob. 6.4CECh. 6.5 - Prob. 6.5CECh. 6.5 - Prob. 6.4PSPCh. 6.6 - Prob. 6.5PSPCh. 6.6 - Use Equation 6.1 and values from Table 6.2 to...
Ch. 6.6 - Prob. 6.6CECh. 6.7 - Prob. 6.7PSPCh. 6.7 - Prob. 6.7CECh. 6.8 - Prob. 6.8PSPCh. 6.9 - Prob. 6.9PSPCh. 6.9 - Prob. 6.9CECh. 6.10 - Prob. 6.10PSPCh. 6.11 - Prob. 6.10ECh. 6.11 - Prob. 6.11ECh. 6.11 - Prob. 1CECh. 6.11 - Prob. 2CECh. 6.12 - Repeat Problem-Solving Example 6.11, but use N2...Ch. 6.12 - Use MO theory to predict the bond order and the...Ch. 6 - Prob. 1QRTCh. 6 - Prob. 2QRTCh. 6 - Prob. 3QRTCh. 6 - Prob. 4QRTCh. 6 - Prob. 5QRTCh. 6 - Prob. 6QRTCh. 6 - Which of these molecules have an odd number of...Ch. 6 - Prob. 8QRTCh. 6 - Prob. 9QRTCh. 6 - Prob. 10QRTCh. 6 - Prob. 11QRTCh. 6 - Prob. 12QRTCh. 6 - Explain in your own words why the energy of two H...Ch. 6 - Prob. 14QRTCh. 6 - Prob. 15QRTCh. 6 - Prob. 16QRTCh. 6 - Prob. 17QRTCh. 6 - Prob. 18QRTCh. 6 - Prob. 19QRTCh. 6 -
Write Lewis structures for
tetracyanoethene,...Ch. 6 - Prob. 21QRTCh. 6 - Prob. 22QRTCh. 6 - Prob. 23QRTCh. 6 - Prob. 24QRTCh. 6 - Prob. 25QRTCh. 6 - Prob. 26QRTCh. 6 - Prob. 27QRTCh. 6 - Prob. 28QRTCh. 6 - Prob. 29QRTCh. 6 - For each pair of bonds, predict which is the...Ch. 6 - Prob. 31QRTCh. 6 - Prob. 32QRTCh. 6 - Which bond requires more energy to break: the...Ch. 6 -
Estimate ΔrH° for forming 2 mol ammonia from...Ch. 6 - Prob. 35QRTCh. 6 - Light of appropriate wavelength can break chemical...Ch. 6 - Prob. 37QRTCh. 6 - Prob. 38QRTCh. 6 - Prob. 39QRTCh. 6 - Acrolein is the starting material for certain...Ch. 6 - Prob. 41QRTCh. 6 - Prob. 42QRTCh. 6 - Write the correct Lewis structure and assign a...Ch. 6 - Prob. 44QRTCh. 6 - Prob. 45QRTCh. 6 - Two Lewis structures can be written for nitrosyl...Ch. 6 - Prob. 47QRTCh. 6 - Prob. 48QRTCh. 6 - Prob. 49QRTCh. 6 - Prob. 50QRTCh. 6 - Several Lewis structures can be written for...Ch. 6 - Prob. 52QRTCh. 6 - Prob. 53QRTCh. 6 - Prob. 54QRTCh. 6 - Prob. 55QRTCh. 6 - Draw resonance structures for each of these ions:...Ch. 6 - Three known isomers exist of N2CO, with the atoms...Ch. 6 - Write the Lewis structure for (a) BrF5 (b) IF5 (c)...Ch. 6 - Write the Lewis structure for
BrF3
XeF4
Ch. 6 - Prob. 60QRTCh. 6 - Prob. 61QRTCh. 6 - Prob. 62QRTCh. 6 - All carbon-to-carbon bond lengths are identical in...Ch. 6 - Prob. 64QRTCh. 6 - Prob. 65QRTCh. 6 - Prob. 66QRTCh. 6 - Prob. 67QRTCh. 6 - Prob. 68QRTCh. 6 - Prob. 69QRTCh. 6 - Prob. 70QRTCh. 6 - Using just a periodic table (not a table of...Ch. 6 - The CBr bond length in CBr4 is 191 pm; the BrBr...Ch. 6 - Prob. 73QRTCh. 6 -
Acrylonitrile is the building block of the...Ch. 6 - Prob. 75QRTCh. 6 - Write Lewis structures for (a) SCl2 (b) Cl3+ (c)...Ch. 6 - Prob. 77QRTCh. 6 - Prob. 78QRTCh. 6 - A student drew this incorrect Lewis structure for...Ch. 6 - This Lewis structure for SF5+ is drawn...Ch. 6 - Tribromide, Br3, and triiodide, I3, ions are often...Ch. 6 - Explain why nonmetal atoms in Period 3 and beyond...Ch. 6 - Prob. 83QRTCh. 6 - Prob. 84QRTCh. 6 - Prob. 85QRTCh. 6 - Prob. 86QRTCh. 6 - Which of these molecules is least likely to exist:...Ch. 6 - Write the Lewis structure for nitrosyl fluoride,...Ch. 6 - Prob. 91QRTCh. 6 - Methylcyanoacrylate is the active ingredient in...Ch. 6 - Aspirin is made from salicylic acid, which has...Ch. 6 - Prob. 94QRTCh. 6 - Prob. 95QRTCh. 6 - Prob. 96QRTCh. 6 - Prob. 97QRTCh. 6 - Prob. 98QRTCh. 6 - Nitrosyl azide, N4O, is a pale yellow solid first...Ch. 6 - Write the Lewis structures for (a) (Cl2PN)3 (b)...Ch. 6 - Nitrous oxide, N2O, is a linear molecule that has...Ch. 6 - The azide ion, N3, has three resonance hybrid...Ch. 6 - Hydrazoic acid, HN3, has three resonance hybrid...Ch. 6 - Prob. 104QRTCh. 6 - Experimental evidence indicates the existence of...Ch. 6 - Prob. 106QRTCh. 6 - Prob. 107QRTCh. 6 - Pipeline, the active ingredient in black pepper,...Ch. 6 - Sulfur and oxygen form a series of 2 anions...Ch. 6 - Prob. 110QRTCh. 6 - Prob. 111QRTCh. 6 - Prob. 112QRTCh. 6 - Prob. 113QRTCh. 6 - Prob. 114QRTCh. 6 - Prob. 115QRTCh. 6 - Prob. 116QRTCh. 6 - Prob. 117QRTCh. 6 - Prob. 118QRTCh. 6 - Prob. 6.ACPCh. 6 - Prob. 6.BCPCh. 6 - Prob. 6.CCP
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