Bundle: Introductory Chemistry: A Foundation, 8th + OWLv2 6-Months Printed Access Card
8th Edition
ISBN: 9781305367333
Author: Steven S. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Textbook Question
Chapter 6, Problem 47AP
Crude gunpowders often contain a mixture of potassium nitrate and charcoal (carbon). When such a mixture is heated until reaction occurs, a solid residue of potassium carbonate is produced. The explosive force of the gunpowder comes from the fact that two gases are also produced (carbon monoxide and nitrogen), which increase in volume with great force and speed. Write the unbalanced chemical equation for the process.
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Q2. Consider the hydrogenation of ethylene
C2H4 + H2 = C2H6
The heats of combustion and molar entropies for the three gases at 298 K are given by:
C2H4
C2H6
H2
AH comb/kJ mol¹
-1395
-1550
-243
Sº / J K¹ mol-1
220.7
230.4
131.1
The average heat capacity change, ACP, for the reaction over the temperature range 298-1000 K is
10.9 J K¹ mol¹. Using these data, determine:
(a) the standard enthalpy change at 800 K
(b) the standard entropy change at 800 K
(c) the equilibrium constant at 800 K.
Chapter 6 Solutions
Bundle: Introductory Chemistry: A Foundation, 8th + OWLv2 6-Months Printed Access Card
Ch. 6.2 - Prob. 6.1SCCh. 6.3 - Prob. 1CTCh. 6.3 - One part of the problem-solving strategy for...Ch. 6.3 - Prob. 6.2SCCh. 6.3 - Prob. 6.3SCCh. 6 - The following are actual student responses to the...Ch. 6 - Prob. 2ALQCh. 6 - Given the equation for the reaction:N2+H2NH3 ,...Ch. 6 - Prob. 4ALQCh. 6 - Can the subscripts in a chemical formula be...
Ch. 6 - Prob. 6ALQCh. 6 - Changing the subscripts of chemicals can...Ch. 6 - Table 6.1 lists some clues that a chemical...Ch. 6 - Use molecular-level drawings to show the...Ch. 6 - It is stated in Section 6.3 of the text that to...Ch. 6 - Prob. 11ALQCh. 6 - Consider the generic chemical equationaA+bBcC+dD...Ch. 6 - Prob. 13ALQCh. 6 - Which of the following correctly describes the...Ch. 6 - Which of the following correctly balances the...Ch. 6 - The reaction of an element X() with element Y() is...Ch. 6 - Prob. 1QAPCh. 6 - Prob. 2QAPCh. 6 - Although these days many people have...Ch. 6 - Prob. 4QAPCh. 6 - You have probably had the unpleasant experience of...Ch. 6 - If you’ve ever left bread in a toaster too long,...Ch. 6 - What are the substances to theleftof the arrow in...Ch. 6 - Prob. 8QAPCh. 6 - In a chemical reaction, the total number of atoms...Ch. 6 - Prob. 10QAPCh. 6 - Prob. 11QAPCh. 6 - The notation “(l)” after a substance’s formula...Ch. 6 - A common experiment to determine the relative...Ch. 6 - If calcium carbonate is heated strongly, carbon...Ch. 6 - If a sample of pure hydrogen gas is ignited very...Ch. 6 - Liquid hydrazine, has been used as a fuel for...Ch. 6 - If electricity of sufficient voltage is passed...Ch. 6 - Silver oxide may be decomposed by strong heating...Ch. 6 - Elemental boron is produced in one industrial...Ch. 6 - Many over-the-counter antacid tablets are now...Ch. 6 - Phosphorus trichloride is used in the manufacture...Ch. 6 - Pure silicon, which is needed in the manufacturing...Ch. 6 - Nitrous oxide gas (systematic name: dinitrogen...Ch. 6 - Solid zinc is added to an aqueous solution...Ch. 6 - Acetylene gas (C2H2) is often used by plumbers,...Ch. 6 - The burning of high-sulfur fuels has been shown to...Ch. 6 - The Group 2 metals (Ba, Ca, Sr) can be produced in...Ch. 6 - There are fears that the protective ozone layer...Ch. 6 - Carbon tetrachloride was widely used for many...Ch. 6 - When elemental phosphorus, P4, burns in oxygen...Ch. 6 - Calcium oxide is sometimes very challenging to...Ch. 6 - Prob. 32QAPCh. 6 - The element tin often occurs in nature as the...Ch. 6 - Nitric acid, HNO3 , can be produced by reacting...Ch. 6 - When balancing chemical equations, beginning...Ch. 6 - The “Chemistry in Focus” segment The Beetle That...Ch. 6 - Balance each of the following chemical equations....Ch. 6 - Balance the equations for the reaction of...Ch. 6 - Balance each of the following chemical equations....Ch. 6 - Balance each of the following chemical equations....Ch. 6 - Balance each of the following chemical equations....Ch. 6 - Prob. 42QAPCh. 6 - Prob. 43QAPCh. 6 - Prob. 44QAPCh. 6 - Acetylene gas, C2H2 , is used in welding because...Ch. 6 - When balancing a chemical equation, which of the...Ch. 6 - Crude gunpowders often contain a mixture of...Ch. 6 - Prob. 48APCh. 6 - Methanol (methyl alcohol), CH3OH , is a very...Ch. 6 - The Hall process is an important method by which...Ch. 6 - Iron oxide ores, commonly a mixture of FeO and...Ch. 6 - True or false? Coefficients can be fractions when...Ch. 6 - When steel wool (iron) is heated in pure oxygen...Ch. 6 - One method of producing hydrogen peroxide is to...Ch. 6 - When elemental boron, B, is burned in oxygen gas,...Ch. 6 - A common experiment in introductory chemistry...Ch. 6 - A common demonstration in chemistry courses...Ch. 6 - Prob. 58APCh. 6 - Prob. 59APCh. 6 - Prob. 60APCh. 6 - If you had a “sour stomach,” you might try an...Ch. 6 - When iron wire is heated in the presence of...Ch. 6 - When finely divided solid sodium is dropped into a...Ch. 6 - If aqueous solutions of potassium chromate and...Ch. 6 - When hydrogen sulfide, H2S , gas is bubbled...Ch. 6 - If an electric current is passed through aqueous...Ch. 6 - When a strip of magnesium metal is heated in...Ch. 6 - Prob. 68APCh. 6 - When solid red phosphorus, is burned in air, the...Ch. 6 - When copper (II) oxide is boiled in an aqueous...Ch. 6 - When lead(II) sulfide is heated lo high...Ch. 6 - Which of the following statements about chemical...Ch. 6 - Prob. 73APCh. 6 - Prob. 74APCh. 6 - Prob. 75APCh. 6 - Using different shapes to distinguish between...Ch. 6 - Which of the following statements about chemical...Ch. 6 - Prob. 78CPCh. 6 - Balance the following chemical equations....
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