The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules. Concept introduction: Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis . Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement. Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon. Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

Question

In the solid state, oxalic acid occurs as a dihydrate with the formula H2C2O4 C+2H2O. Use this formula to calculate the formula weight of oxalic acid. Use the calculated formula weight and the number of moles (0.00504mol) of oxalic acid in each titrated unknown sample recorded in Table 6.4 to calculate the number of grams of pure oxalic acid dihydrate contained in each titrated unknown sample.

Answer 1

Question

Chapter 6, Problem 41PP

(a)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

(b)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

(c)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

(d)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

(e)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

(f)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

(g)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

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In the solid state, oxalic acid occurs as a dihydrate with the formula H2C2O4 C+2H2O. Use this formula to calculate the formula weight of oxalic acid. Use the calculated formula weight and the number of moles (0.00504mol) of oxalic acid in each titrated unknown sample recorded in Table 6.4 to calculate the number of grams of pure oxalic acid dihydrate contained in each titrated unknown sample.

1. Consider a pair of elements with 2p and 4p valence orbitals (e.g., N and Se). Draw their (2p and 4p AO's) radial probability plots, and sketch their angular profiles. Then, consider these orbitals from the two atoms forming a homonuclear л-bond. Which element would have a stronger bond, and why? (4 points)

Write the reaction and show the mechanism of the reaction. Include the mechanism for formation of the NO2+ 2. Explain, using resonance structures, why the meta isomer is formed. Draw possible resonance structures for ortho, meta and para.

Answer 2

Question

Chapter 6, Problem 41PP

(a)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

(b)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

(c)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

(d)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

(e)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

(f)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

(g)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

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Answer 3

Question

Chapter 6, Problem 41PP

(a)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

(b)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

(c)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

(d)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

(e)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

(f)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

(g)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

Expert Solution & Answer

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Answer 4

Question

Chapter 6, Problem 41PP

(a)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

(b)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

(c)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

(d)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

(e)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

(f)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

(g)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

Expert Solution & Answer

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Check out sample textbook solution

Answer 5

Chapter 6, Problem 41PP

(a)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

(b)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

(c)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

(d)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

(e)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

(f)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

(g)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

Answer 6

Chapter 6, Problem 41PP

(a)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

Answer 7

Chapter 6, Problem 41PP

(a)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

Answer 14

(e)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

Answer 15

(e)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

Answer 16

(f)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

Answer 17

(f)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

Answer 18

(g)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

Answer 19

(g)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

Answer 20

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Answer 21

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Ch. 6.1 - Prob. 1LTS Ch. 6.1 - Prob. 1PTS Ch. 6.1 - Prob. 2ATS Ch. 6.2 - Prob. 3CC Ch. 6.3 - Prob. 4CC Ch. 6.3 - Prob. 5CC Ch. 6.4 - Prob. 6CC Ch. 6.6 - Prob. 7CC Ch. 6.7 - Prob. 2LTS Ch. 6.7 - Prob. 8PTS

Chapter 6 Solutions