Essential Organic Chemistry Study Guide & Solution Manual, Books a la Carte Edition
Essential Organic Chemistry Study Guide & Solution Manual, Books a la Carte Edition
3rd Edition
ISBN: 9780134255644
Author: Bruice, Paula Yurkanis
Publisher: PEARSON
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Chapter 6, Problem 39P

(a)

Interpretation Introduction

Interpretation:

The systematic name given should be checked that whether it is correct or not and also the correct name should be given if in case the given name is wrong.

Concept Introduction:

NOMENCLATURE RULES:

  • If the ‘ane’ ending of the alkane is replaced by ‘yne’ ending, the name of alkyne is obtained.
  • Select the longest chain which contains the triple bond in such a way to get lowest value for the functional group.
  • Two types of alkynes will be there according to the position of triple bond. Terminal alkyne is the one which contain triple bond at the end of the chain and internal alkyne is the one which contain triple bond not at the end but present in any other positions in the chain.
  • When the counting is done from either sides of triple bond in a compound which contain same number for the functional group suffix, the correct name will be the one which have lowest substituent number. In the case of more than one substituent, alphabetical order should be followed.

Skeletal structure: When the atoms bonded in a compound is drawn in a series it can be called as a skeletal structure. In the skeletal structure, we can show the branches, chains, rings or any other hetero atom other than carbon or hydrogen.

Condensed structure: In the condensed structure, atoms or group of atoms are expressed in a line. But it does not contain any vertical bonds and also the horizontal single bonds.

(b)

Interpretation Introduction

Interpretation:

The systematic name given should be checked that whether it is correct or not and also the correct name should be given if in case the given name is wrong.

Concept Introduction:

NOMENCLATURE RULES:

  • If the ‘ane’ ending of the alkane is replaced by ‘yne’ ending, the name of alkyne is obtained.
  • Select the longest chain which contains the triple bond in such a way to get lowest value for the functional group.
  • Two types of alkynes will be there according to the position of triple bond. Terminal alkyne is the one which contain triple bond at the end of the chain and internal alkyne is the one which contain triple bond not at the end but present in any other positions in the chain.
  • When the counting is done from either sides of triple bond in a compound which contain same number for the functional group suffix, the correct name will be the one which have lowest substituent number. In the case of more than one substituent, alphabetical order should be followed.

Skeletal structure: When the atoms bonded in a compound is drawn in a series it can be called as a skeletal structure. In the skeletal structure, we can show the branches, chains, rings or any other hetero atom other than carbon or hydrogen.

Condensed structure: In the condensed structure, atoms or group of atoms are expressed in a line. But it does not contain any vertical bonds and also the horizontal single bonds.

(c)

Interpretation Introduction

Interpretation:

The systematic name given should be checked that whether it is correct or not and also the correct name should be given if in case the given name is wrong.

Concept Introduction:

NOMENCLATURE RULES:

  • If the ‘ane’ ending of the alkane is replaced by ‘yne’ ending, the name of alkyne is obtained.
  • Select the longest chain which contains the triple bond in such a way to get lowest value for the functional group.
  • Two types of alkynes will be there according to the position of triple bond. Terminal alkyne is the one which contain triple bond at the end of the chain and internal alkyne is the one which contain triple bond not at the end but present in any other positions in the chain.
  • When the counting is done from either sides of triple bond in a compound which contain same number for the functional group suffix, the correct name will be the one which have lowest substituent number. In the case of more than one substituent, alphabetical order should be followed.

Skeletal structure: When the atoms bonded in a compound is drawn in a series it can be called as a skeletal structure. In the skeletal structure, we can show the branches, chains, rings or any other hetero atom other than carbon or hydrogen.

Condensed structure: In the condensed structure, atoms or group of atoms are expressed in a line. But it does not contain any vertical bonds and also the horizontal single bonds.

(d)

Interpretation Introduction

Interpretation:

The systematic name given should be checked that whether it is correct or not and also the correct name should be given if in case the given name is wrong.

Concept Introduction:

NOMENCLATURE RULES:

  • If the ‘ane’ ending of the alkane is replaced by ‘yne’ ending, the name of alkyne is obtained.
  • Select the longest chain which contains the triple bond in such a way to get lowest value for the functional group.
  • Two types of alkynes will be there according to the position of triple bond. Terminal alkyne is the one which contain triple bond at the end of the chain and internal alkyne is the one which contain triple bond not at the end but present in any other positions in the chain.
  • When the counting is done from either sides of triple bond in a compound which contain same number for the functional group suffix, the correct name will be the one which have lowest substituent number. In the case of more than one substituent, alphabetical order should be followed.

Skeletal structure: When the atoms bonded in a compound is drawn in a series it can be called as a skeletal structure. In the skeletal structure, we can show the branches, chains, rings or any other hetero atom other than carbon or hydrogen.

Condensed structure: In the condensed structure, atoms or group of atoms are expressed in a line. But it does not contain any vertical bonds and also the horizontal single bonds.

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Students have asked these similar questions
What spectral features allow you to differentiate the product from the starting material? Use four separate paragraphs for each set of comparisons. You should have one paragraph each devoted to MS, HNMR, CNMR and IR. 2) For MS, the differing masses of molecular ions are a popular starting point. Including a unique fragmentation is important, too. 3) For HNMR, CNMR and IR state the peaks that are different and what makes them different (usually the presence or absence of certain groups). See if you can find two differences (in each set of IR, HNMR and CNMR spectra) due to the presence or absence of a functional group. Include peak locations. Alternatively, you can state a shift of a peak due to a change near a given functional group. Including peak locations for shifted peaks, as well as what these peaks are due to. Ideally, your focus should be on not just identifying the differences but explaining them in terms of functional group changes.
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Chapter 6 Solutions

Essential Organic Chemistry Study Guide & Solution Manual, Books a la Carte Edition

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