The indicated bonds in order of increasing bond dissociation energy are to be ranked. Concept introduction: The energy which is released or absorbed in the chemical reactions is referred to as bond dissociation energy. The strength of a bond in the reaction is determined by bond dissociation energy. The chemical reactions in which energy is released from dissociation during the formation of products are known as exothermic reactions. In endothermic reactions, reactants absorb energy to form the desired products. Exothermic and endothermic reactions are opposite to each other.

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Formula Formula Bond dissociation energy (BDE) is the energy required to break a bond, making it an endothermic process. BDE is calculated for a particular bond and therefore consists of fragments such as radicals since it undergoes homolytic bond cleavage. For the homolysis of a X-Y molecule, the energy of bond dissociation is calculated as the difference in the total enthalpy of formation for the reactants and products. X-Y → X + Y BDE = Δ H f X + Δ H f Y – Δ H f X-Y where, ΔHf is the heat of formation.

Chapter 6, Problem 35P

Interpretation Introduction

Interpretation: The indicated bonds in order of increasing bond dissociation energy are to be ranked.

Concept introduction: The energy which is released or absorbed in the chemical reactions is referred to as bond dissociation energy. The strength of a bond in the reaction is determined by bond dissociation energy. The chemical reactions in which energy is released from dissociation during the formation of products are known as exothermic reactions. In endothermic reactions, reactants absorb energy to form the desired products. Exothermic and endothermic reactions are opposite to each other.

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1. Calculate the accurate monoisotopic mass (using all 1H, 12C, 14N, 160 and 35CI) for your product using the table in your lab manual. Don't include the Cl, since you should only have [M+H]*. Compare this to the value you see on the LC-MS printout. How much different are they? 2. There are four isotopic peaks for the [M+H]* ion at m/z 240, 241, 242 and 243. For one point of extra credit, explain what each of these is and why they are present. 3. There is a fragment ion at m/z 184. For one point of extra credit, identify this fragment and confirm by calculating the accurate monoisotopic mass. 4. The UV spectrum is also at the bottom of your printout. For one point of extra credit, look up the UV spectrum of bupropion on Google Images and compare to your spectrum. Do they match? Cite your source. 5. For most of you, there will be a second chromatographic peak whose m/z is 74 (to a round number). For one point of extra credit, see if you can identify this molecule as well and confirm by…

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Answer 2

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Formula Formula Bond dissociation energy (BDE) is the energy required to break a bond, making it an endothermic process. BDE is calculated for a particular bond and therefore consists of fragments such as radicals since it undergoes homolytic bond cleavage. For the homolysis of a X-Y molecule, the energy of bond dissociation is calculated as the difference in the total enthalpy of formation for the reactants and products. X-Y → X + Y BDE = Δ H f X + Δ H f Y – Δ H f X-Y where, ΔHf is the heat of formation.

Chapter 6, Problem 35P

Interpretation Introduction

Interpretation: The indicated bonds in order of increasing bond dissociation energy are to be ranked.

Concept introduction: The energy which is released or absorbed in the chemical reactions is referred to as bond dissociation energy. The strength of a bond in the reaction is determined by bond dissociation energy. The chemical reactions in which energy is released from dissociation during the formation of products are known as exothermic reactions. In endothermic reactions, reactants absorb energy to form the desired products. Exothermic and endothermic reactions are opposite to each other.

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Answer 3

Question

Formula Formula Bond dissociation energy (BDE) is the energy required to break a bond, making it an endothermic process. BDE is calculated for a particular bond and therefore consists of fragments such as radicals since it undergoes homolytic bond cleavage. For the homolysis of a X-Y molecule, the energy of bond dissociation is calculated as the difference in the total enthalpy of formation for the reactants and products. X-Y → X + Y BDE = Δ H f X + Δ H f Y – Δ H f X-Y where, ΔHf is the heat of formation.

Chapter 6, Problem 35P

Interpretation Introduction

Interpretation: The indicated bonds in order of increasing bond dissociation energy are to be ranked.

Concept introduction: The energy which is released or absorbed in the chemical reactions is referred to as bond dissociation energy. The strength of a bond in the reaction is determined by bond dissociation energy. The chemical reactions in which energy is released from dissociation during the formation of products are known as exothermic reactions. In endothermic reactions, reactants absorb energy to form the desired products. Exothermic and endothermic reactions are opposite to each other.

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Answer 4

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Formula Formula Bond dissociation energy (BDE) is the energy required to break a bond, making it an endothermic process. BDE is calculated for a particular bond and therefore consists of fragments such as radicals since it undergoes homolytic bond cleavage. For the homolysis of a X-Y molecule, the energy of bond dissociation is calculated as the difference in the total enthalpy of formation for the reactants and products. X-Y → X + Y BDE = Δ H f X + Δ H f Y – Δ H f X-Y where, ΔHf is the heat of formation.

Chapter 6, Problem 35P

Interpretation Introduction