The arrow pushing method is to be interpreted for the given transformation. Concept introduction: The chemical transformation can occur with the hydride shift; methylene shifts or methyl shifts etc. Each transformation can be shown by the arrow pushing method in which the curved arrows show the movement of electrons or protons. The chemical transformation leads to the formation of intermediates.

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Answer 1

Question

Chapter 6, Problem 27PP

(a)

Interpretation Introduction

Interpretation: The arrow pushing method is to be interpreted for the given transformation.

Concept introduction: The chemical transformation can occur with the hydride shift; methylene shifts or methyl shifts etc.

Each transformation can be shown by the arrow pushing method in which the curved arrows show the movement of electrons or protons. The chemical transformation leads to the formation of intermediates.

(b)

Interpretation Introduction

Interpretation: The arrow pushing method is to be interpreted for the given transformation.

Concept introduction: The chemical transformation can occur with the hydride shift; methylene shifts or methyl shifts etc.

Each transformation can be shown by the arrow pushing method in which the curved arrows show the movement of electrons or protons. The chemical transformation leads to the formation of intermediates.

(c)

Interpretation Introduction

Interpretation: The arrow pushing method is to be interpreted for the given transformation.

Concept introduction: The chemical transformation can occur with the hydride shift; methylene shifts or methyl shifts etc.

Each transformation can be shown by the arrow pushing method in which the curved arrows show the movement of electrons or protons. The chemical transformation leads to the formation of intermediates.

(d)

Interpretation Introduction

Interpretation: The arrow pushing method is to be interpreted for the given transformation.

Concept introduction: The chemical transformation can occur with the hydride shift; methylene shifts or methyl shifts etc.

Each transformation can be shown by the arrow pushing method in which the curved arrows show the movement of electrons or protons. The chemical transformation leads to the formation of intermediates.

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2. Name the following hydrocarbons. (9 marks) a) HHHHHHHH H-C-C- H-O-S b) HCEC-CH3 H H H H H d) c) H C=C- H H H e) CH3 CH3 CH2CH=CH-CH=CHCH3 HHHH H-C-C-C-C-H H HH H f) large CH2CH3 pola H3C section lovels tower, able ocart firs g) Tower H3C-CH2 then in H3C-CH-CH-CH3 enblbano bne noitsidab Copyright © 2008. Durham Continuing Education CH3

Name the molecules & Identify any chiral center CH3CH2CH2CHCH₂CH₂CH₂CH₂ OH CH₂CHCH2CH3 Br CH3 CH3CHCH2CHCH2CH3 CH3

Curved arrows are used to illustrate the flow of electrons. Using the provided starting and product structures, draw the curved electrons-pushing arrows for the following reaction or mechanistic step(s).

Answer 2

Question

Chapter 6, Problem 27PP

(a)

Interpretation Introduction

Interpretation: The arrow pushing method is to be interpreted for the given transformation.

Concept introduction: The chemical transformation can occur with the hydride shift; methylene shifts or methyl shifts etc.

Each transformation can be shown by the arrow pushing method in which the curved arrows show the movement of electrons or protons. The chemical transformation leads to the formation of intermediates.

(b)

Interpretation Introduction

Interpretation: The arrow pushing method is to be interpreted for the given transformation.

Concept introduction: The chemical transformation can occur with the hydride shift; methylene shifts or methyl shifts etc.

Each transformation can be shown by the arrow pushing method in which the curved arrows show the movement of electrons or protons. The chemical transformation leads to the formation of intermediates.

(c)

Interpretation Introduction

Interpretation: The arrow pushing method is to be interpreted for the given transformation.

Concept introduction: The chemical transformation can occur with the hydride shift; methylene shifts or methyl shifts etc.

Each transformation can be shown by the arrow pushing method in which the curved arrows show the movement of electrons or protons. The chemical transformation leads to the formation of intermediates.

(d)

Interpretation Introduction

Interpretation: The arrow pushing method is to be interpreted for the given transformation.

Concept introduction: The chemical transformation can occur with the hydride shift; methylene shifts or methyl shifts etc.

Each transformation can be shown by the arrow pushing method in which the curved arrows show the movement of electrons or protons. The chemical transformation leads to the formation of intermediates.

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Answer 3

Question

Chapter 6, Problem 27PP

(a)

Interpretation Introduction

Interpretation: The arrow pushing method is to be interpreted for the given transformation.

Concept introduction: The chemical transformation can occur with the hydride shift; methylene shifts or methyl shifts etc.

Each transformation can be shown by the arrow pushing method in which the curved arrows show the movement of electrons or protons. The chemical transformation leads to the formation of intermediates.

(b)

Interpretation Introduction

Interpretation: The arrow pushing method is to be interpreted for the given transformation.

Concept introduction: The chemical transformation can occur with the hydride shift; methylene shifts or methyl shifts etc.

Each transformation can be shown by the arrow pushing method in which the curved arrows show the movement of electrons or protons. The chemical transformation leads to the formation of intermediates.

(c)

Interpretation Introduction

Interpretation: The arrow pushing method is to be interpreted for the given transformation.

Concept introduction: The chemical transformation can occur with the hydride shift; methylene shifts or methyl shifts etc.

Each transformation can be shown by the arrow pushing method in which the curved arrows show the movement of electrons or protons. The chemical transformation leads to the formation of intermediates.

(d)

Interpretation Introduction

Interpretation: The arrow pushing method is to be interpreted for the given transformation.

Concept introduction: The chemical transformation can occur with the hydride shift; methylene shifts or methyl shifts etc.

Each transformation can be shown by the arrow pushing method in which the curved arrows show the movement of electrons or protons. The chemical transformation leads to the formation of intermediates.

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Answer 4

Question

Chapter 6, Problem 27PP

(a)

Interpretation Introduction

Interpretation: The arrow pushing method is to be interpreted for the given transformation.

Concept introduction: The chemical transformation can occur with the hydride shift; methylene shifts or methyl shifts etc.

Each transformation can be shown by the arrow pushing method in which the curved arrows show the movement of electrons or protons. The chemical transformation leads to the formation of intermediates.

(b)

Interpretation Introduction

Interpretation: The arrow pushing method is to be interpreted for the given transformation.

Concept introduction: The chemical transformation can occur with the hydride shift; methylene shifts or methyl shifts etc.

Each transformation can be shown by the arrow pushing method in which the curved arrows show the movement of electrons or protons. The chemical transformation leads to the formation of intermediates.

(c)

Interpretation Introduction

Interpretation: The arrow pushing method is to be interpreted for the given transformation.

Concept introduction: The chemical transformation can occur with the hydride shift; methylene shifts or methyl shifts etc.

Each transformation can be shown by the arrow pushing method in which the curved arrows show the movement of electrons or protons. The chemical transformation leads to the formation of intermediates.

(d)

Interpretation Introduction

Interpretation: The arrow pushing method is to be interpreted for the given transformation.

Concept introduction: The chemical transformation can occur with the hydride shift; methylene shifts or methyl shifts etc.

Each transformation can be shown by the arrow pushing method in which the curved arrows show the movement of electrons or protons. The chemical transformation leads to the formation of intermediates.

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Answer 5

Chapter 6, Problem 27PP

(a)

Interpretation Introduction

Interpretation: The arrow pushing method is to be interpreted for the given transformation.

Concept introduction: The chemical transformation can occur with the hydride shift; methylene shifts or methyl shifts etc.

Each transformation can be shown by the arrow pushing method in which the curved arrows show the movement of electrons or protons. The chemical transformation leads to the formation of intermediates.

(b)

Interpretation Introduction

Interpretation: The arrow pushing method is to be interpreted for the given transformation.

Concept introduction: The chemical transformation can occur with the hydride shift; methylene shifts or methyl shifts etc.

Each transformation can be shown by the arrow pushing method in which the curved arrows show the movement of electrons or protons. The chemical transformation leads to the formation of intermediates.

(c)

Interpretation Introduction

Interpretation: The arrow pushing method is to be interpreted for the given transformation.

Concept introduction: The chemical transformation can occur with the hydride shift; methylene shifts or methyl shifts etc.

Each transformation can be shown by the arrow pushing method in which the curved arrows show the movement of electrons or protons. The chemical transformation leads to the formation of intermediates.

(d)

Interpretation Introduction

Interpretation: The arrow pushing method is to be interpreted for the given transformation.

Concept introduction: The chemical transformation can occur with the hydride shift; methylene shifts or methyl shifts etc.

Each transformation can be shown by the arrow pushing method in which the curved arrows show the movement of electrons or protons. The chemical transformation leads to the formation of intermediates.

Answer 6

Chapter 6, Problem 27PP

(a)

Interpretation Introduction

Interpretation: The arrow pushing method is to be interpreted for the given transformation.

Concept introduction: The chemical transformation can occur with the hydride shift; methylene shifts or methyl shifts etc.

Each transformation can be shown by the arrow pushing method in which the curved arrows show the movement of electrons or protons. The chemical transformation leads to the formation of intermediates.

Answer 7

Chapter 6, Problem 27PP

(a)

Interpretation Introduction

Interpretation: The arrow pushing method is to be interpreted for the given transformation.

Concept introduction: The chemical transformation can occur with the hydride shift; methylene shifts or methyl shifts etc.

Each transformation can be shown by the arrow pushing method in which the curved arrows show the movement of electrons or protons. The chemical transformation leads to the formation of intermediates.

Answer 8

(b)

Interpretation Introduction

Interpretation: The arrow pushing method is to be interpreted for the given transformation.

Concept introduction: The chemical transformation can occur with the hydride shift; methylene shifts or methyl shifts etc.

Each transformation can be shown by the arrow pushing method in which the curved arrows show the movement of electrons or protons. The chemical transformation leads to the formation of intermediates.

Answer 9

(b)

Interpretation Introduction

Interpretation: The arrow pushing method is to be interpreted for the given transformation.

Concept introduction: The chemical transformation can occur with the hydride shift; methylene shifts or methyl shifts etc.

Each transformation can be shown by the arrow pushing method in which the curved arrows show the movement of electrons or protons. The chemical transformation leads to the formation of intermediates.

Answer 10

(c)

Interpretation Introduction

Interpretation: The arrow pushing method is to be interpreted for the given transformation.

Concept introduction: The chemical transformation can occur with the hydride shift; methylene shifts or methyl shifts etc.

Each transformation can be shown by the arrow pushing method in which the curved arrows show the movement of electrons or protons. The chemical transformation leads to the formation of intermediates.

Answer 11

(c)

Interpretation Introduction

Interpretation: The arrow pushing method is to be interpreted for the given transformation.

Concept introduction: The chemical transformation can occur with the hydride shift; methylene shifts or methyl shifts etc.

Each transformation can be shown by the arrow pushing method in which the curved arrows show the movement of electrons or protons. The chemical transformation leads to the formation of intermediates.

Answer 12

(d)

Interpretation Introduction

Interpretation: The arrow pushing method is to be interpreted for the given transformation.

Concept introduction: The chemical transformation can occur with the hydride shift; methylene shifts or methyl shifts etc.

Each transformation can be shown by the arrow pushing method in which the curved arrows show the movement of electrons or protons. The chemical transformation leads to the formation of intermediates.

Answer 13

(d)

Interpretation Introduction

Interpretation: The arrow pushing method is to be interpreted for the given transformation.

Concept introduction: The chemical transformation can occur with the hydride shift; methylene shifts or methyl shifts etc.

Each transformation can be shown by the arrow pushing method in which the curved arrows show the movement of electrons or protons. The chemical transformation leads to the formation of intermediates.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 6.1 - Prob. 1LTS Ch. 6.1 - Prob. 1PTS Ch. 6.1 - Prob. 2ATS Ch. 6.2 - Prob. 3CC Ch. 6.3 - Prob. 4CC Ch. 6.3 - Prob. 5CC Ch. 6.4 - Prob. 6CC Ch. 6.6 - Prob. 7CC Ch. 6.7 - Prob. 2LTS Ch. 6.7 - Prob. 8PTS

Solution Summary: The author explains how the arrow pushing method is to be interpreted for the given transformation.

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Chapter 6 Solutions