For a chemical reaction with K eq = 1 .2 , the condition of equilibrium is to be interpreted if it will favor the product over the reactant. Concept introduction: One or more reactant molecules are changed into product molecules during a chemical reaction. The equilibrium is the point in a reversible reaction where the rates of the forward and backward reactions must balance out.

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Answer 1

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Chapter 6, Problem 21PP

(a)

Interpretation Introduction

Interpretation: For a chemical reaction with Keq = 1.2 , the condition of equilibrium is to be interpreted if it will favor the product over the reactant.

Concept introduction: One or more reactant molecules are changed into product molecules during a chemical reaction. The equilibrium is the point in a reversible reaction where the rates of the forward and backward reactions must balance out.

(b)

Interpretation Introduction

Interpretation: For a chemical reaction with Keq = 0.2 , the condition of equilibrium is to be interpreted if it will favor the product over the reactant.

Concept introduction: One or more reactant molecules are changed into product molecules during a chemical reaction. The equilibrium is the point in a reversible reaction where the rates of the forward and backward reactions must balance out.

(c)

Interpretation Introduction

Interpretation: For a chemical reaction with positive value of ΔG , the condition of equilibrium is to be interpreted if it will favor the product over reactant.

Concept introduction: One or more reactant molecules are changed into product molecules during a chemical reaction. The equilibrium is the point in a reversible reaction where the rates of the forward and backward reactions must balance out.

(d)

Interpretation Introduction

Interpretation: For an exothermic reaction with positive value of ΔS , the condition of equilibrium is to be interpreted if it will favor product over reactant.

Concept introduction: A chemical reaction involves the conversion of one or more reactant molecules to product molecules. The Gibb’s equation provides the relation between ΔS , ΔH , and ΔG of the reaction.

ΔG = ΔH - T ΔS

(e)

Interpretation Introduction

Interpretation: For an endothermic reaction with negative value of ΔS , the condition of equilibrium is to be interpreted if it will favor product over reactant.

Concept introduction: A chemical reaction involves the conversion of one or more reactant molecules to product molecules. The Gibb’s equation provides the relation between ΔS , ΔH , and ΔG of the reaction.

ΔG = ΔH - T ΔS

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In the video, we looked at the absorbance of a certain substance and how it varies depending on what wavelength of light we are looking at. Below is a similar scan of a different substance. What color BEST describes how this substance will appear? Absorbance (AU) Violet Blue Green Orange 1.2 1.0- 0.8- 0.6- 0.4- 0.2 0.0 450 500 550 600 650 700 Wavelength (nm) violet indigo blue green yellow orange red Red O Cannot tell from this information In the above graph, what causes -450 nm wavelength of light to have a higher absorbance than light with a -550 nm wavelength? Check all that are true. The distance the light travels is different The different data points are for different substances The concentration is different at different times in the experiment Epsilon (molar absortivity) is different at different wavelengths

5. a. Data were collected for Trial 1 to determine the molar mass of a nonvolatile solid solute when dissolved in cyclo- hexane. Complete the table for the analysis (See Report Sheet). Record calculated values with the correct number of significant figures. B. Freezing Point of Cyclohexane plus Calculation Zone Unknown Solute 2. Mass of cyclohexane (g) 10.14 Part C.4 3. Mass of added solute (g) 0.255 C. Calculations 1. k; for cyclohexane (°C⚫ kg/mol) 20.0 2. Freezing point change, AT, (°C) 3.04 Part C.6 3. Mass of cyclohexane in solution (kg) 4. Moles of solute, total (mol) Show calculation. 5. Mass of solute in solution, total (g) 6. Molar mass of solute (g/mol) Show calculation.

Answer 2

Question

Chapter 6, Problem 21PP

(a)

Interpretation Introduction

Interpretation: For a chemical reaction with Keq = 1.2 , the condition of equilibrium is to be interpreted if it will favor the product over the reactant.

Concept introduction: One or more reactant molecules are changed into product molecules during a chemical reaction. The equilibrium is the point in a reversible reaction where the rates of the forward and backward reactions must balance out.

(b)

Interpretation Introduction

Interpretation: For a chemical reaction with Keq = 0.2 , the condition of equilibrium is to be interpreted if it will favor the product over the reactant.

Concept introduction: One or more reactant molecules are changed into product molecules during a chemical reaction. The equilibrium is the point in a reversible reaction where the rates of the forward and backward reactions must balance out.

(c)

Interpretation Introduction

Interpretation: For a chemical reaction with positive value of ΔG , the condition of equilibrium is to be interpreted if it will favor the product over reactant.

Concept introduction: One or more reactant molecules are changed into product molecules during a chemical reaction. The equilibrium is the point in a reversible reaction where the rates of the forward and backward reactions must balance out.

(d)

Interpretation Introduction

Interpretation: For an exothermic reaction with positive value of ΔS , the condition of equilibrium is to be interpreted if it will favor product over reactant.

Concept introduction: A chemical reaction involves the conversion of one or more reactant molecules to product molecules. The Gibb’s equation provides the relation between ΔS , ΔH , and ΔG of the reaction.

ΔG = ΔH - T ΔS

(e)

Interpretation Introduction

Interpretation: For an endothermic reaction with negative value of ΔS , the condition of equilibrium is to be interpreted if it will favor product over reactant.

Concept introduction: A chemical reaction involves the conversion of one or more reactant molecules to product molecules. The Gibb’s equation provides the relation between ΔS , ΔH , and ΔG of the reaction.

ΔG = ΔH - T ΔS

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Answer 3

Question

Chapter 6, Problem 21PP

(a)

Interpretation Introduction

Interpretation: For a chemical reaction with Keq = 1.2 , the condition of equilibrium is to be interpreted if it will favor the product over the reactant.

Concept introduction: One or more reactant molecules are changed into product molecules during a chemical reaction. The equilibrium is the point in a reversible reaction where the rates of the forward and backward reactions must balance out.

(b)

Interpretation Introduction

Interpretation: For a chemical reaction with Keq = 0.2 , the condition of equilibrium is to be interpreted if it will favor the product over the reactant.

Concept introduction: One or more reactant molecules are changed into product molecules during a chemical reaction. The equilibrium is the point in a reversible reaction where the rates of the forward and backward reactions must balance out.

(c)

Interpretation Introduction

Interpretation: For a chemical reaction with positive value of ΔG , the condition of equilibrium is to be interpreted if it will favor the product over reactant.

Concept introduction: One or more reactant molecules are changed into product molecules during a chemical reaction. The equilibrium is the point in a reversible reaction where the rates of the forward and backward reactions must balance out.

(d)

Interpretation Introduction

Interpretation: For an exothermic reaction with positive value of ΔS , the condition of equilibrium is to be interpreted if it will favor product over reactant.

Concept introduction: A chemical reaction involves the conversion of one or more reactant molecules to product molecules. The Gibb’s equation provides the relation between ΔS , ΔH , and ΔG of the reaction.

ΔG = ΔH - T ΔS

(e)

Interpretation Introduction

Interpretation: For an endothermic reaction with negative value of ΔS , the condition of equilibrium is to be interpreted if it will favor product over reactant.

Concept introduction: A chemical reaction involves the conversion of one or more reactant molecules to product molecules. The Gibb’s equation provides the relation between ΔS , ΔH , and ΔG of the reaction.

ΔG = ΔH - T ΔS

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Answer 4

Question

Chapter 6, Problem 21PP

(a)

Interpretation Introduction

Interpretation: For a chemical reaction with Keq = 1.2 , the condition of equilibrium is to be interpreted if it will favor the product over the reactant.

Concept introduction: One or more reactant molecules are changed into product molecules during a chemical reaction. The equilibrium is the point in a reversible reaction where the rates of the forward and backward reactions must balance out.

(b)

Interpretation Introduction

Interpretation: For a chemical reaction with Keq = 0.2 , the condition of equilibrium is to be interpreted if it will favor the product over the reactant.

Concept introduction: One or more reactant molecules are changed into product molecules during a chemical reaction. The equilibrium is the point in a reversible reaction where the rates of the forward and backward reactions must balance out.

(c)

Interpretation Introduction

Interpretation: For a chemical reaction with positive value of ΔG , the condition of equilibrium is to be interpreted if it will favor the product over reactant.

Concept introduction: One or more reactant molecules are changed into product molecules during a chemical reaction. The equilibrium is the point in a reversible reaction where the rates of the forward and backward reactions must balance out.

(d)

Interpretation Introduction

Interpretation: For an exothermic reaction with positive value of ΔS , the condition of equilibrium is to be interpreted if it will favor product over reactant.

Concept introduction: A chemical reaction involves the conversion of one or more reactant molecules to product molecules. The Gibb’s equation provides the relation between ΔS , ΔH , and ΔG of the reaction.

ΔG = ΔH - T ΔS

(e)

Interpretation Introduction

Interpretation: For an endothermic reaction with negative value of ΔS , the condition of equilibrium is to be interpreted if it will favor product over reactant.

Concept introduction: A chemical reaction involves the conversion of one or more reactant molecules to product molecules. The Gibb’s equation provides the relation between ΔS , ΔH , and ΔG of the reaction.

ΔG = ΔH - T ΔS

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Answer 5

Chapter 6, Problem 21PP

(a)

Interpretation Introduction

Interpretation: For a chemical reaction with Keq = 1.2 , the condition of equilibrium is to be interpreted if it will favor the product over the reactant.

Concept introduction: One or more reactant molecules are changed into product molecules during a chemical reaction. The equilibrium is the point in a reversible reaction where the rates of the forward and backward reactions must balance out.

(b)

Interpretation Introduction

Interpretation: For a chemical reaction with Keq = 0.2 , the condition of equilibrium is to be interpreted if it will favor the product over the reactant.

Concept introduction: One or more reactant molecules are changed into product molecules during a chemical reaction. The equilibrium is the point in a reversible reaction where the rates of the forward and backward reactions must balance out.

(c)

Interpretation Introduction

Interpretation: For a chemical reaction with positive value of ΔG , the condition of equilibrium is to be interpreted if it will favor the product over reactant.

Concept introduction: One or more reactant molecules are changed into product molecules during a chemical reaction. The equilibrium is the point in a reversible reaction where the rates of the forward and backward reactions must balance out.

(d)

Interpretation Introduction

Interpretation: For an exothermic reaction with positive value of ΔS , the condition of equilibrium is to be interpreted if it will favor product over reactant.

Concept introduction: A chemical reaction involves the conversion of one or more reactant molecules to product molecules. The Gibb’s equation provides the relation between ΔS , ΔH , and ΔG of the reaction.

ΔG = ΔH - T ΔS

(e)

Interpretation Introduction

Interpretation: For an endothermic reaction with negative value of ΔS , the condition of equilibrium is to be interpreted if it will favor product over reactant.

Concept introduction: A chemical reaction involves the conversion of one or more reactant molecules to product molecules. The Gibb’s equation provides the relation between ΔS , ΔH , and ΔG of the reaction.

ΔG = ΔH - T ΔS

Answer 6

Chapter 6, Problem 21PP

(a)

Interpretation Introduction

Interpretation: For a chemical reaction with Keq = 1.2 , the condition of equilibrium is to be interpreted if it will favor the product over the reactant.

Concept introduction: One or more reactant molecules are changed into product molecules during a chemical reaction. The equilibrium is the point in a reversible reaction where the rates of the forward and backward reactions must balance out.

Answer 7

Chapter 6, Problem 21PP

(a)

Interpretation Introduction

Interpretation: For a chemical reaction with Keq = 1.2 , the condition of equilibrium is to be interpreted if it will favor the product over the reactant.

Concept introduction: One or more reactant molecules are changed into product molecules during a chemical reaction. The equilibrium is the point in a reversible reaction where the rates of the forward and backward reactions must balance out.

Answer 8

(b)

Interpretation Introduction

Interpretation: For a chemical reaction with Keq = 0.2 , the condition of equilibrium is to be interpreted if it will favor the product over the reactant.

Concept introduction: One or more reactant molecules are changed into product molecules during a chemical reaction. The equilibrium is the point in a reversible reaction where the rates of the forward and backward reactions must balance out.

Answer 9

(b)

Interpretation Introduction

Interpretation: For a chemical reaction with Keq = 0.2 , the condition of equilibrium is to be interpreted if it will favor the product over the reactant.

Concept introduction: One or more reactant molecules are changed into product molecules during a chemical reaction. The equilibrium is the point in a reversible reaction where the rates of the forward and backward reactions must balance out.

Answer 10

(c)

Interpretation Introduction

Interpretation: For a chemical reaction with positive value of ΔG , the condition of equilibrium is to be interpreted if it will favor the product over reactant.

Concept introduction: One or more reactant molecules are changed into product molecules during a chemical reaction. The equilibrium is the point in a reversible reaction where the rates of the forward and backward reactions must balance out.

Answer 11

(c)

Interpretation Introduction

Interpretation: For a chemical reaction with positive value of ΔG , the condition of equilibrium is to be interpreted if it will favor the product over reactant.

Concept introduction: One or more reactant molecules are changed into product molecules during a chemical reaction. The equilibrium is the point in a reversible reaction where the rates of the forward and backward reactions must balance out.

Answer 12

(d)

Interpretation Introduction

Interpretation: For an exothermic reaction with positive value of ΔS , the condition of equilibrium is to be interpreted if it will favor product over reactant.

Concept introduction: A chemical reaction involves the conversion of one or more reactant molecules to product molecules. The Gibb’s equation provides the relation between ΔS , ΔH , and ΔG of the reaction.

ΔG = ΔH - T ΔS

Answer 13

(d)

Interpretation Introduction

Interpretation: For an exothermic reaction with positive value of ΔS , the condition of equilibrium is to be interpreted if it will favor product over reactant.

Concept introduction: A chemical reaction involves the conversion of one or more reactant molecules to product molecules. The Gibb’s equation provides the relation between ΔS , ΔH , and ΔG of the reaction.

ΔG = ΔH - T ΔS

Answer 14

(e)

Interpretation Introduction

Interpretation: For an endothermic reaction with negative value of ΔS , the condition of equilibrium is to be interpreted if it will favor product over reactant.

Concept introduction: A chemical reaction involves the conversion of one or more reactant molecules to product molecules. The Gibb’s equation provides the relation between ΔS , ΔH , and ΔG of the reaction.

ΔG = ΔH - T ΔS

Answer 15

(e)

Interpretation Introduction

Interpretation: For an endothermic reaction with negative value of ΔS , the condition of equilibrium is to be interpreted if it will favor product over reactant.

Concept introduction: A chemical reaction involves the conversion of one or more reactant molecules to product molecules. The Gibb’s equation provides the relation between ΔS , ΔH , and ΔG of the reaction.

ΔG = ΔH - T ΔS

Answer 16

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Answer 17

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Answer 18

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Answer 19

Ch. 6.1 - Prob. 1LTS Ch. 6.1 - Prob. 1PTS Ch. 6.1 - Prob. 2ATS Ch. 6.2 - Prob. 3CC Ch. 6.3 - Prob. 4CC Ch. 6.3 - Prob. 5CC Ch. 6.4 - Prob. 6CC Ch. 6.6 - Prob. 7CC Ch. 6.7 - Prob. 2LTS Ch. 6.7 - Prob. 8PTS

Solution Summary: The author explains the condition of equilibrium in a reversible reaction where the rates of the forward and backward reactions must balance out.

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