EBK ORGANIC CHEMISTRY-STUD.SOLNS.MAN+SG
EBK ORGANIC CHEMISTRY-STUD.SOLNS.MAN+SG
4th Edition
ISBN: 9781119659525
Author: Klein
Publisher: WILEY CONS
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Chapter 6, Problem 21PP

(a)

Interpretation Introduction

Interpretation: For a chemical reaction with Keq = 1.2 , the condition of equilibrium is to be interpreted if it will favor the product over the reactant.

Concept introduction: One or more reactant molecules are changed into product molecules during a chemical reaction. The equilibrium is the point in a reversible reaction where the rates of the forward and backward reactions must balance out.

(b)

Interpretation Introduction

Interpretation: For a chemical reaction with Keq = 0.2 , the condition of equilibrium is to be interpreted if it will favor the product over the reactant.

Concept introduction: One or more reactant molecules are changed into product molecules during a chemical reaction. The equilibrium is the point in a reversible reaction where the rates of the forward and backward reactions must balance out.

(c)

Interpretation Introduction

Interpretation: For a chemical reaction with positive value of ΔG , the condition of equilibrium is to be interpreted if it will favor the product over reactant.

Concept introduction: One or more reactant molecules are changed into product molecules during a chemical reaction. The equilibrium is the point in a reversible reaction where the rates of the forward and backward reactions must balance out.

(d)

Interpretation Introduction

Interpretation: For an exothermic reaction with positive value of ΔS , the condition of equilibrium is to be interpreted if it will favor product over reactant.

Concept introduction: A chemical reaction involves the conversion of one or more reactant molecules to product molecules. The Gibb’s equation provides the relation between ΔS , ΔH , and ΔG of the reaction.

  ΔG  = ΔH - T ΔS

(e)

Interpretation Introduction

Interpretation: For an endothermic reaction with negative value of ΔS , the condition of equilibrium is to be interpreted if it will favor product over reactant.

Concept introduction: A chemical reaction involves the conversion of one or more reactant molecules to product molecules. The Gibb’s equation provides the relation between ΔS , ΔH , and ΔG of the reaction.

  ΔG  = ΔH - T ΔS

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