Principles of General, Organic, Biological Chemistry
2nd Edition
ISBN: 9780073511191
Author: Janice Gorzynski Smith Dr.
Publisher: McGraw-Hill Education
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Chapter 5.8, Problem 5.33P
Interpretation Introduction
Interpretation:
The energy change diagram of the reaction with low activation energy and the energy of products are lower in energy than the reactants has to be drawn.
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When an unknown amine reacts with an unknown acid chloride, an amide with a molecular mass of 163 g/mol (M* = 163 m/z)
is formed. In the infrared spectrum, important absorptions appear at 1661, 750 and 690 cm. The 13C NMR and DEPT spectra
are provided. Draw the structure of the product as the resonance contributor lacking any formal charges.
13C NMR
DEPT 90
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120
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DEPT 135
T
200
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Draw the unknown amide.
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Chapter 5 Solutions
Principles of General, Organic, Biological Chemistry
Ch. 5.1 - Use the molecular art to identify the process as a...Ch. 5.1 - Use the molecular at to identify the process as a...Ch. 5.1 - Prob. 5.3PCh. 5.1 - Prob. 5.4PCh. 5.1 - Write a chemical equation from the following...Ch. 5.2 - Prob. 5.6PCh. 5.2 - Prob. 5.7PCh. 5.2 - Prob. 5.8PCh. 5.2 - Prob. 5.9PCh. 5.2 - Prob. 5.10P
Ch. 5.3 - Prob. 5.11PCh. 5.3 - Prob. 5.12PCh. 5.3 - How many molecules are contained in each of the...Ch. 5.3 - Prob. 5.14PCh. 5.4 - Prob. 5.15PCh. 5.4 - Prob. 5.16PCh. 5.4 - Prob. 5.18PCh. 5.4 - Prob. 5.19PCh. 5.5 - Use the balanced equation for the reaction of N2...Ch. 5.5 - Prob. 5.21PCh. 5.6 - Using the balanced equation for fermentation...Ch. 5.6 - Prob. 5.23PCh. 5.6 - Prob. 5.24PCh. 5.6 - Prob. 5.25PCh. 5.7 - Prob. 5.26PCh. 5.7 - Prob. 5.27PCh. 5.7 - Prob. 5.28PCh. 5.7 - Early pacemakers generated an electrical impulse...Ch. 5.8 - Prob. 5.30PCh. 5.8 - Prob. 5.31PCh. 5.8 - Prob. 5.32PCh. 5.8 - Prob. 5.33PCh. 5.9 - Prob. 5.34PCh. 5.9 - Prob. 5.35PCh. 5.9 - Prob. 5.36PCh. 5.10 - Prob. 5.37PCh. 5.10 - In which direction is the equilibrium shifted with...Ch. 5 - Use the molecular art to identify the process as a...Ch. 5 - Prob. 5.40UKCCh. 5 - Prob. 5.41UKCCh. 5 - Prob. 5.42UKCCh. 5 - Prob. 5.43UKCCh. 5 - Prob. 5.44UKCCh. 5 - Prob. 5.45UKCCh. 5 - Spinach, cabbage, and broccoli are excellent...Ch. 5 - Prob. 5.47UKCCh. 5 - Prob. 5.48UKCCh. 5 - Prob. 5.49UKCCh. 5 - Rechargeable nickelcadmium batteries are used in...Ch. 5 - Prob. 5.51UKCCh. 5 - Prob. 5.52UKCCh. 5 - Prob. 5.53UKCCh. 5 - Prob. 5.54UKCCh. 5 - Prob. 5.55APCh. 5 - Prob. 5.56APCh. 5 - Prob. 5.57APCh. 5 - Prob. 5.58APCh. 5 - Prob. 5.59APCh. 5 - Prob. 5.60APCh. 5 - Prob. 5.61APCh. 5 - Prob. 5.62APCh. 5 - Prob. 5.63APCh. 5 - Consider the reaction, 2 NO + 2 CO N2 + 2 CO2....Ch. 5 - Prob. 5.65APCh. 5 - Prob. 5.66APCh. 5 - Prob. 5.67APCh. 5 - Prob. 5.68APCh. 5 - Prob. 5.69APCh. 5 - Prob. 5.70APCh. 5 - Prob. 5.71APCh. 5 - Prob. 5.72APCh. 5 - Prob. 5.73APCh. 5 - Prob. 5.74APCh. 5 - Prob. 5.75APCh. 5 - Prob. 5.76APCh. 5 - Prob. 5.77APCh. 5 - Prob. 5.78APCh. 5 - Prob. 5.79APCh. 5 - Prob. 5.80APCh. 5 - Prob. 5.81APCh. 5 - Prob. 5.82APCh. 5 - Prob. 5.83APCh. 5 - Prob. 5.84APCh. 5 - Prob. 5.85APCh. 5 - Prob. 5.86APCh. 5 - Prob. 5.87APCh. 5 - Prob. 5.88APCh. 5 - Prob. 5.89APCh. 5 - Prob. 5.90APCh. 5 - Prob. 5.91APCh. 5 - Prob. 5.92APCh. 5 - Prob. 5.93APCh. 5 - Prob. 5.94APCh. 5 - Prob. 5.95APCh. 5 - Prob. 5.96APCh. 5 - Prob. 5.97APCh. 5 - Prob. 5.98APCh. 5 - Prob. 5.99APCh. 5 - Prob. 5.100APCh. 5 - Prob. 5.101APCh. 5 - Prob. 5.102APCh. 5 - Prob. 5.103CP
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