EBK ORGANIC CHEMISTRY
EBK ORGANIC CHEMISTRY
7th Edition
ISBN: 9780133556186
Author: Bruice
Publisher: VST
Question
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Chapter 5.7, Problem 26P

(a)

Interpretation Introduction

Interpretation:

Thermodynamically stable product compared with reactant in the given reaction has to be determined.

Concept introduction:

Thermodynamic stability can be represented as ΔG0.  Depend upon the value of ΔG0 it is possible to find stability of the product compared with the reactant.

If ΔG0 is negative, then the product is thermodynamically stable compared with the reactant.

If ΔG0 is positive, then the product is thermodynamically unstable compared with the reactant

In an exergonic reaction the products have a lower free energy than it consumes.

In an endergonic reaction the product have a higher free energy than it consumes.

(b)

Interpretation Introduction

Interpretation:

Most kinetically stable product compared with reactant in the given reaction has to be determined.

Concept introduction:

Kinetic stability can be represented as ΔG.  Depend upon the value of ΔG it is possible to find stability of the product compared with the reactant.

If ΔG is large, then the reactant is kinetically stable because it reacts slowly.

If ΔG is small, then the reactant is kinetically unstable because it reacts rapidly.

If ΔG for the reverse reaction is large then he product is kinetically stable, similarly if it is small then the product is kinetically unstable.

In an exergonic reaction the products have a lower free energy than it consumes.

In an endergonic reaction the product have a higher free energy than it consumes.

(c)

Interpretation Introduction

Interpretation:

Least kinetically stable product compared with reactant in the given reaction has to be determined.

Concept introduction:

Kinetic stability can be represented as ΔG.  Depend upon the value of ΔG it is possible to find stability of the product compared with the reactant.

If ΔG is large, then the reactant is kinetically stable because it reacts slowly.

If ΔG is small, then the reactant is kinetically unstable because it reacts rapidly.

If ΔG for the reverse reaction is large then he product is kinetically stable, similarly if it is small then the product is kinetically unstable.

In an exergonic reaction the products have a lower free energy than it consumes.

In an endergonic reaction the product have a higher free energy than it consumes.

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Chapter 5 Solutions

EBK ORGANIC CHEMISTRY

Ch. 5.4 - Prob. 14PCh. 5.4 - Prob. 15PCh. 5.6 - Prob. 16PCh. 5.6 - Prob. 17PCh. 5.6 - Prob. 18PCh. 5.6 - Prob. 20PCh. 5.7 - a. Which of the monosubstituted cyclohexanes in...Ch. 5.7 - a. for which reaction in each set will S be more...Ch. 5.7 - a. For a reaction with H = 12 kcal/ mol and S =...Ch. 5.7 - Prob. 25PCh. 5.7 - Prob. 26PCh. 5.7 - Prob. 27PCh. 5.9 - The rate constant for a reaction can be increased...Ch. 5.9 - Prob. 30PCh. 5.9 - a. Which reaction has a greater equilibrium...Ch. 5.10 - Draw a reaction coordinate diagram for a two-step...Ch. 5.10 - a. Which step in the reaction coordinate diagram...Ch. 5.10 - Draw a reaction coordinate diagram for the...Ch. 5.11 - Prob. 35PCh. 5 - What is each compounds systematic name?Ch. 5 - Draw the structure of a hydrocarbon that has six...Ch. 5 - Draw the condensed structure for each of the...Ch. 5 - Prob. 39PCh. 5 - Prob. 40PCh. 5 - Name the following:Ch. 5 - Prob. 42PCh. 5 - 43. Draw the skeletal structure of...Ch. 5 - In a reaction in which reactant A is in...Ch. 5 - Which bond is stronger? Briefly explain why.Ch. 5 - Prob. 46PCh. 5 - Prob. 47PCh. 5 - Assign relative priorities to each set of...Ch. 5 - Prob. 49PCh. 5 - By following the curved red arrows, draw the...Ch. 5 - Prob. 51PCh. 5 - Draw structures for the following: a....Ch. 5 - Prob. 53PCh. 5 - a. Which of the following reactions has the larger...Ch. 5 - a. What is the equilibrium constant for a reaction...Ch. 5 - Prob. 56PCh. 5 - Prob. 57PCh. 5 - Given that the free energy of the twist-boat...Ch. 5 - Prob. 59PCh. 5 - Prob. 1PCh. 5 - Prob. 2PCh. 5 - Prob. 3PCh. 5 - Prob. 4PCh. 5 - Prob. 5PCh. 5 - Prob. 6PCh. 5 - Draw curved arrows to show the movement of the...Ch. 5 - Prob. 8PCh. 5 - Prob. 9PCh. 5 - Prob. 10P
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