An Introduction to Thermal Physics
1st Edition
ISBN: 9780201380279
Author: Daniel V. Schroeder
Publisher: Addison Wesley
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Chapter 5.5, Problem 81P
To determine
The shift in the freezing temperature of a dilute solution.
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Chapter 5 Solutions
An Introduction to Thermal Physics
Ch. 5.1 - Prob. 1PCh. 5.1 - Consider the production of ammonia from nitrogen...Ch. 5.1 - Prob. 3PCh. 5.1 - Prob. 4PCh. 5.1 - Consider a fuel cell that uses methane (natural...Ch. 5.1 - Prob. 6PCh. 5.1 - The metabolism of a glucose molecule (see previous...Ch. 5.1 - Derive the thermodynamic identity for G (equation...Ch. 5.1 - Sketch a qualitatively accurate graph of G vs. T...Ch. 5.1 - Suppose you have a mole of water at 25C and...
Ch. 5.1 - Suppose that a hydrogen fuel cell, as described in...Ch. 5.1 - Prob. 12PCh. 5.1 - Prob. 13PCh. 5.1 - Prob. 14PCh. 5.1 - Prob. 15PCh. 5.1 - Prob. 16PCh. 5.1 - Prob. 17PCh. 5.2 - Prob. 18PCh. 5.2 - In the previous section 1 derived the formula...Ch. 5.2 - Prob. 20PCh. 5.2 - Is heat capacity (C) extensive or intensive? What...Ch. 5.2 - Prob. 22PCh. 5.2 - Prob. 23PCh. 5.3 - Go through the arithmetic to verify that diamond...Ch. 5.3 - Prob. 25PCh. 5.3 - How can diamond ever be more stable than graphite,...Ch. 5.3 - Prob. 27PCh. 5.3 - Calcium carbonate, CaCO3, has two common...Ch. 5.3 - Aluminum silicate, Al2SiO5, has three different...Ch. 5.3 - Sketch qualitatively accurate graphs of G vs. T...Ch. 5.3 - Sketch qualitatively accurate graphs of G vs. P...Ch. 5.3 - The density of ice is 917kg/m3. (a) Use the...Ch. 5.3 - An inventor proposes to make a heat engine using...Ch. 5.3 - Below 0.3 K the Slope of the 3He solid–liquid...Ch. 5.3 - Prob. 35PCh. 5.3 - Effect of altitude on boiling water. (a) Use the...Ch. 5.3 - Prob. 37PCh. 5.3 - Prob. 38PCh. 5.3 - Prob. 39PCh. 5.3 - The methods of this section can also be applied to...Ch. 5.3 - Suppose you have a liquid (say, water) in...Ch. 5.3 - Ordinarily, the partial pressure of water vapor in...Ch. 5.3 - Assume that the air you exhale is at 35C, with a...Ch. 5.3 - Prob. 44PCh. 5.3 - Prob. 46PCh. 5.3 - Prob. 47PCh. 5.3 - Prob. 48PCh. 5.3 - Prob. 49PCh. 5.3 - The compression factor of a fluid is defined as...Ch. 5.3 - Prob. 51PCh. 5.3 - Prob. 52PCh. 5.3 - Repeat the preceding problem for T/Tc=0.8.Ch. 5.3 - Prob. 54PCh. 5.3 - Prob. 55PCh. 5.4 - Prove that the entropy of mixing of an ideal...Ch. 5.4 - In this problem you will model the mixing energy...Ch. 5.4 - Suppose you cool a mixture of 50% nitrogen and 50%...Ch. 5.4 - Suppose you start with a liquid mixture of 60%...Ch. 5.4 - Suppose you need a tank of oxygen that is 95%...Ch. 5.4 - Prob. 62PCh. 5.4 - Everything in this section assumes that the total...Ch. 5.4 - Figure 5.32 shows the phase diagram of plagioclase...Ch. 5.4 - Prob. 65PCh. 5.4 - Prob. 66PCh. 5.4 - Prob. 67PCh. 5.4 - Plumbers solder is composed of 67% lead and 33%...Ch. 5.4 - What happens when you spread salt crystals over an...Ch. 5.4 - What happens when you add salt to the ice bath in...Ch. 5.4 - Figure 5.35 (left) shows the free energy curves at...Ch. 5.4 - Repeat the previous problem for the diagram in...Ch. 5.5 - If expression 5.68 is correct, it must be...Ch. 5.5 - Prob. 74PCh. 5.5 - Compare expression 5.68 for the Gibbs free energy...Ch. 5.5 - Seawater has a salinity of 3.5%, meaning that if...Ch. 5.5 - Osmotic pressure measurements can be used to...Ch. 5.5 - Because osmotic pressures can be quite large, you...Ch. 5.5 - Most pasta recipes instruct you to add a teaspoon...Ch. 5.5 - Use the Clausius–Clapeyron relation to derive...Ch. 5.5 - Prob. 81PCh. 5.5 - Use the result of the previous problem to...Ch. 5.6 - Prob. 83PCh. 5.6 - Prob. 84PCh. 5.6 - Prob. 85PCh. 5.6 - Prob. 86PCh. 5.6 - Sulfuric acid, H2SO4, readily dissociates into H+...Ch. 5.6 - Prob. 88PCh. 5.6 - Prob. 89PCh. 5.6 - When solid quartz dissolves in water, it combines...Ch. 5.6 - When carbon dioxide dissolves in water,...Ch. 5.6 - Prob. 92P
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- 10. Imagine you have a system in which you have 54 grams of ice. You can melt this ice and then vaporize it all at 0 C. The melting and vaporization are done reversibly into a balloon held at a pressure of 0.250 bar. Here are some facts about water you may wish to know. The density of liquid water at 0 C is 1 g/cm³. The density of ice at 0 C is 0.917 g/cm³. The enthalpy of vaporization of liquid water is 2.496 kJ/gram and the enthalpy of fusion of solid water is 333.55 J/gram. A. How much energy does the ice absorb as heat when it melts? B. How much work is involved in melting the ice? C. What is the total change in energy for melting the ice? D. What is the enthalpy change for melting the ice? E. What is the entropy change for melting the ice? F. What is the change in Helmholtz energy for melting the ice? G. What is the change in Gibbs energy for melting the ice?arrow_forwardIn the figure Q = 5.7 nC and all other quantities are accurate to 2 significant figures. What is the magnitude of the force on the charge Q? (k = 1/4πε 0 = 8.99 × 109 N · m2/C2)arrow_forwardNow add a fourth charged particle, particle 3, with positive charge q3, fixed in the yz-plane at (0,d2,d2). What is the net force F→ on particle 0 due solely to this charge? Express your answer (a vector) using k, q0, q3, d2, i^, j^, and k^. Include only the force caused by particle 3.arrow_forward
- For a tornadoes and hurricanes, which of the following is most critical? an alert a watch a warning a predictionarrow_forwardWhen a warm front advances up and over a cold front, what is it called? front inversion stationary front cold front occlusion warm front occlusionarrow_forward1) Consider two positively charged particles, one of charge q0 (particle 0) fixed at the origin, and another of charge q1 (particle 1) fixed on the y-axis at (0,d1,0). What is the net force F→ on particle 0 due to particle 1? Express your answer (a vector) using any or all of k, q0, q1, d1, i^, j^, and k^. 2) Now add a third, negatively charged, particle, whose charge is −q2− (particle 2). Particle 2 fixed on the y-axis at position (0,d2,0). What is the new net force on particle 0, from particle 1 and particle 2? Express your answer (a vector) using any or all of k, q0, q1, q2, d1, d2, i^, j^, and k^. 3) Particle 0 experiences a repulsion from particle 1 and an attraction toward particle 2. For certain values of d1 and d2, the repulsion and attraction should balance each other, resulting in no net force. For what ratio d1/d2 is there no net force on particle 0? Express your answer in terms of any or all of the following variables: k, q0, q1, q2.arrow_forward
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