EBK ORGANIC CHEMISTRY-PRINT COMPANION (
4th Edition
ISBN: 9781119776741
Author: Klein
Publisher: WILEY CONS
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Question
Chapter 5.4, Problem 5LTS
Interpretation Introduction
Interpretation: The stereoisomers should identify for the given molecule by using its structure.
Concept Introduction:
Chiral: An asymmetric molecule attached to four different types of atoms or groups of atoms.
Enantiomers: The chiral molecules that are mirror images of one another. These types of molecules are non-superimposable on one another. This means that the molecules cannot be placed on top of one another and give the same molecule. Furthermore chiral molecules with one or more stereo centers can be enantiomers.
To Find: The stereoisomers to be identified.
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For each reaction below, decide if the first stable organic product that forms in solution will create a new CC bond, and check the appropriate box.
Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below.
Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first
stable product you expect to form in solution.
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✗MgBr
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O
CI
Will the first product that forms in this reaction
create a new C-C bond?
Yes
No
•
?
Will the first product that forms in this reaction
create a new CC bond?
Yes
No
×
: ☐
X
Predict the major products of this organic reaction:
OH
NaBH4
H
?
CH3OH
Note: be sure you use dash and wedge bonds when necessary, for example to distinguish between major products with different stereochemistry.
Click and drag to start drawing a
structure.
☐ :
S
Predict the major products of this organic reaction:
1. LIAIHA
2. H₂O
?
Note: be sure you use dash and wedge bonds when necessary, for example to distinguish between major products with different stereochemistry.
Click and drag to start drawing a
structure.
X
: ☐
Chapter 5 Solutions
EBK ORGANIC CHEMISTRY-PRINT COMPANION (
Ch. 5.2 - Prob. 1LTSCh. 5.3 - Prob. 3LTSCh. 5.4 - Prob. 4LTSCh. 5.4 - Prob. 11PTSCh. 5.4 - Prob. 12PTSCh. 5.4 - Prob. 13PTSCh. 5.4 - Prob. 5LTSCh. 5.4 - Prob. 15PTSCh. 5.4 - Prob. 16PTSCh. 5.4 - Prob. 17PTS
Ch. 5.5 - Prob. 6LTSCh. 5.5 - Prob. 19PTSCh. 5.6 - Prob. 21CCCh. 5.6 - Prob. 23CCCh. 5 - Prob. 31PPCh. 5 - Prob. 32PPCh. 5 - Prob. 33PPCh. 5 - Prob. 40PPCh. 5 - Prob. 46PPCh. 5 - Prob. 49PPCh. 5 - Prob. 50PPCh. 5 - Prob. 51PPCh. 5 - Prob. 52PPCh. 5 - Prob. 54PPCh. 5 - Prob. 56PPCh. 5 - Prob. 64IPCh. 5 - Prob. 65IPCh. 5 - Prob. 66IPCh. 5 - Prob. 67IP
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