For the given set of molecules the optically active or optically inactive should be identified. Concept Introduction : Enantiomers are chiral molecules that are mirror images of one another. The molecules are non-superimposable on one another. Optically active: These are capable of rotating the plane of polarized light to the right or left either dextrorotatory or levorotatory used of compounds, molecules, or atoms. Optically inactive: A racemic mixture is an optically inactive; there is no net rotation of plane-polarized light. Although the two enantiomers rotate plane-polarized light in opposite directions, the rotations cancel because they are present in equal amounts.

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Answer 1

Question

Chapter 5, Problem 66IP

(a)

Interpretation Introduction

Interpretation:

For the given set of molecules the optically active or optically inactive should be identified.

Concept Introduction:

Enantiomers are chiral molecules that are mirror images of one another. The molecules are non-superimposable on one another.

Optically active: These are capable of rotating the plane of polarized light to the right or left either dextrorotatory or levorotatory used of compounds, molecules, or atoms.

Optically inactive: A racemic mixture is an optically inactive; there is no net rotation of plane-polarized light. Although the two enantiomers rotate plane-polarized light in opposite directions, the rotations cancel because they are present in equal amounts.

(b)

Interpretation Introduction

Interpretation:

For the given set of molecules the optically active or optically inactive should be identified.

Concept Introduction:

Enantiomers are chiral molecules that are mirror images of one another. The molecules are non-superimposable on one another.

Optically active: These are capable of rotating the plane of polarized light to the right or left either dextrorotatory or levorotatory used of compounds, molecules, or atoms.

Optically inactive: A racemic mixture is an optically inactive; there is no net rotation of plane-polarized light. Although the two enantiomers rotate plane-polarized light in opposite directions, the rotations cancel because they are present in equal amounts.

(c)

Interpretation Introduction

Interpretation:

For the given set of molecules the optically active or optically inactive should be identified.

Concept Introduction:

Enantiomers are chiral molecules that are mirror images of one another. The molecules are non-superimposable on one another.

Optically active: These are capable of rotating the plane of polarized light to the right or left either dextrorotatory or levorotatory used of compounds, molecules, or atoms.

Optically inactive: A racemic mixture is an optically inactive; there is no net rotation of plane-polarized light. Although the two enantiomers rotate plane-polarized light in opposite directions, the rotations cancel because they are present in equal amounts.

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Answer 2

Question

Chapter 5, Problem 66IP

(a)

Interpretation Introduction

Interpretation:

For the given set of molecules the optically active or optically inactive should be identified.

Concept Introduction:

Enantiomers are chiral molecules that are mirror images of one another. The molecules are non-superimposable on one another.

Optically active: These are capable of rotating the plane of polarized light to the right or left either dextrorotatory or levorotatory used of compounds, molecules, or atoms.

Optically inactive: A racemic mixture is an optically inactive; there is no net rotation of plane-polarized light. Although the two enantiomers rotate plane-polarized light in opposite directions, the rotations cancel because they are present in equal amounts.

(b)

Interpretation Introduction

Interpretation:

For the given set of molecules the optically active or optically inactive should be identified.

Concept Introduction:

Enantiomers are chiral molecules that are mirror images of one another. The molecules are non-superimposable on one another.

Optically active: These are capable of rotating the plane of polarized light to the right or left either dextrorotatory or levorotatory used of compounds, molecules, or atoms.

Optically inactive: A racemic mixture is an optically inactive; there is no net rotation of plane-polarized light. Although the two enantiomers rotate plane-polarized light in opposite directions, the rotations cancel because they are present in equal amounts.

(c)

Interpretation Introduction

Interpretation:

For the given set of molecules the optically active or optically inactive should be identified.

Concept Introduction:

Enantiomers are chiral molecules that are mirror images of one another. The molecules are non-superimposable on one another.

Optically active: These are capable of rotating the plane of polarized light to the right or left either dextrorotatory or levorotatory used of compounds, molecules, or atoms.

Optically inactive: A racemic mixture is an optically inactive; there is no net rotation of plane-polarized light. Although the two enantiomers rotate plane-polarized light in opposite directions, the rotations cancel because they are present in equal amounts.

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Answer 3

Question

Chapter 5, Problem 66IP

(a)

Interpretation Introduction

Interpretation:

For the given set of molecules the optically active or optically inactive should be identified.

Concept Introduction:

Enantiomers are chiral molecules that are mirror images of one another. The molecules are non-superimposable on one another.

Optically active: These are capable of rotating the plane of polarized light to the right or left either dextrorotatory or levorotatory used of compounds, molecules, or atoms.

Optically inactive: A racemic mixture is an optically inactive; there is no net rotation of plane-polarized light. Although the two enantiomers rotate plane-polarized light in opposite directions, the rotations cancel because they are present in equal amounts.

(b)

Interpretation Introduction

Interpretation:

For the given set of molecules the optically active or optically inactive should be identified.

Concept Introduction:

Enantiomers are chiral molecules that are mirror images of one another. The molecules are non-superimposable on one another.

Optically active: These are capable of rotating the plane of polarized light to the right or left either dextrorotatory or levorotatory used of compounds, molecules, or atoms.

Optically inactive: A racemic mixture is an optically inactive; there is no net rotation of plane-polarized light. Although the two enantiomers rotate plane-polarized light in opposite directions, the rotations cancel because they are present in equal amounts.

(c)

Interpretation Introduction

Interpretation:

For the given set of molecules the optically active or optically inactive should be identified.

Concept Introduction:

Enantiomers are chiral molecules that are mirror images of one another. The molecules are non-superimposable on one another.

Optically active: These are capable of rotating the plane of polarized light to the right or left either dextrorotatory or levorotatory used of compounds, molecules, or atoms.

Optically inactive: A racemic mixture is an optically inactive; there is no net rotation of plane-polarized light. Although the two enantiomers rotate plane-polarized light in opposite directions, the rotations cancel because they are present in equal amounts.

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Answer 4

Question

Chapter 5, Problem 66IP

(a)

Interpretation Introduction

Interpretation:

For the given set of molecules the optically active or optically inactive should be identified.

Concept Introduction:

Enantiomers are chiral molecules that are mirror images of one another. The molecules are non-superimposable on one another.

Optically active: These are capable of rotating the plane of polarized light to the right or left either dextrorotatory or levorotatory used of compounds, molecules, or atoms.

Optically inactive: A racemic mixture is an optically inactive; there is no net rotation of plane-polarized light. Although the two enantiomers rotate plane-polarized light in opposite directions, the rotations cancel because they are present in equal amounts.

(b)

Interpretation Introduction

Interpretation:

For the given set of molecules the optically active or optically inactive should be identified.

Concept Introduction:

Enantiomers are chiral molecules that are mirror images of one another. The molecules are non-superimposable on one another.

Optically active: These are capable of rotating the plane of polarized light to the right or left either dextrorotatory or levorotatory used of compounds, molecules, or atoms.

Optically inactive: A racemic mixture is an optically inactive; there is no net rotation of plane-polarized light. Although the two enantiomers rotate plane-polarized light in opposite directions, the rotations cancel because they are present in equal amounts.

(c)

Interpretation Introduction

Interpretation:

For the given set of molecules the optically active or optically inactive should be identified.

Concept Introduction:

Enantiomers are chiral molecules that are mirror images of one another. The molecules are non-superimposable on one another.

Optically active: These are capable of rotating the plane of polarized light to the right or left either dextrorotatory or levorotatory used of compounds, molecules, or atoms.

Optically inactive: A racemic mixture is an optically inactive; there is no net rotation of plane-polarized light. Although the two enantiomers rotate plane-polarized light in opposite directions, the rotations cancel because they are present in equal amounts.

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Answer 5

Chapter 5, Problem 66IP

(a)

Interpretation Introduction

Interpretation:

For the given set of molecules the optically active or optically inactive should be identified.

Concept Introduction:

Enantiomers are chiral molecules that are mirror images of one another. The molecules are non-superimposable on one another.

Optically active: These are capable of rotating the plane of polarized light to the right or left either dextrorotatory or levorotatory used of compounds, molecules, or atoms.

Optically inactive: A racemic mixture is an optically inactive; there is no net rotation of plane-polarized light. Although the two enantiomers rotate plane-polarized light in opposite directions, the rotations cancel because they are present in equal amounts.

(b)

Interpretation Introduction

Interpretation:

For the given set of molecules the optically active or optically inactive should be identified.

Concept Introduction:

Enantiomers are chiral molecules that are mirror images of one another. The molecules are non-superimposable on one another.

Optically active: These are capable of rotating the plane of polarized light to the right or left either dextrorotatory or levorotatory used of compounds, molecules, or atoms.

Optically inactive: A racemic mixture is an optically inactive; there is no net rotation of plane-polarized light. Although the two enantiomers rotate plane-polarized light in opposite directions, the rotations cancel because they are present in equal amounts.

(c)

Interpretation Introduction

Interpretation:

For the given set of molecules the optically active or optically inactive should be identified.

Concept Introduction:

Enantiomers are chiral molecules that are mirror images of one another. The molecules are non-superimposable on one another.

Optically active: These are capable of rotating the plane of polarized light to the right or left either dextrorotatory or levorotatory used of compounds, molecules, or atoms.

Optically inactive: A racemic mixture is an optically inactive; there is no net rotation of plane-polarized light. Although the two enantiomers rotate plane-polarized light in opposite directions, the rotations cancel because they are present in equal amounts.

Answer 6

Chapter 5, Problem 66IP

(a)

Interpretation Introduction

Interpretation:

For the given set of molecules the optically active or optically inactive should be identified.

Concept Introduction:

Enantiomers are chiral molecules that are mirror images of one another. The molecules are non-superimposable on one another.

Optically active: These are capable of rotating the plane of polarized light to the right or left either dextrorotatory or levorotatory used of compounds, molecules, or atoms.

Optically inactive: A racemic mixture is an optically inactive; there is no net rotation of plane-polarized light. Although the two enantiomers rotate plane-polarized light in opposite directions, the rotations cancel because they are present in equal amounts.

Answer 7

Chapter 5, Problem 66IP

(a)

Interpretation Introduction

Interpretation:

For the given set of molecules the optically active or optically inactive should be identified.

Concept Introduction:

Enantiomers are chiral molecules that are mirror images of one another. The molecules are non-superimposable on one another.

Optically active: These are capable of rotating the plane of polarized light to the right or left either dextrorotatory or levorotatory used of compounds, molecules, or atoms.

Optically inactive: A racemic mixture is an optically inactive; there is no net rotation of plane-polarized light. Although the two enantiomers rotate plane-polarized light in opposite directions, the rotations cancel because they are present in equal amounts.

Answer 8

(b)

Interpretation Introduction

Interpretation:

For the given set of molecules the optically active or optically inactive should be identified.

Concept Introduction:

Enantiomers are chiral molecules that are mirror images of one another. The molecules are non-superimposable on one another.

Optically active: These are capable of rotating the plane of polarized light to the right or left either dextrorotatory or levorotatory used of compounds, molecules, or atoms.

Optically inactive: A racemic mixture is an optically inactive; there is no net rotation of plane-polarized light. Although the two enantiomers rotate plane-polarized light in opposite directions, the rotations cancel because they are present in equal amounts.

Answer 9

(b)

Interpretation Introduction

Interpretation:

For the given set of molecules the optically active or optically inactive should be identified.

Concept Introduction:

Enantiomers are chiral molecules that are mirror images of one another. The molecules are non-superimposable on one another.

Optically active: These are capable of rotating the plane of polarized light to the right or left either dextrorotatory or levorotatory used of compounds, molecules, or atoms.

Optically inactive: A racemic mixture is an optically inactive; there is no net rotation of plane-polarized light. Although the two enantiomers rotate plane-polarized light in opposite directions, the rotations cancel because they are present in equal amounts.

Answer 10

(c)

Interpretation Introduction

Interpretation:

For the given set of molecules the optically active or optically inactive should be identified.

Concept Introduction:

Enantiomers are chiral molecules that are mirror images of one another. The molecules are non-superimposable on one another.

Optically active: These are capable of rotating the plane of polarized light to the right or left either dextrorotatory or levorotatory used of compounds, molecules, or atoms.

Optically inactive: A racemic mixture is an optically inactive; there is no net rotation of plane-polarized light. Although the two enantiomers rotate plane-polarized light in opposite directions, the rotations cancel because they are present in equal amounts.

Answer 11

(c)

Interpretation Introduction

Interpretation:

For the given set of molecules the optically active or optically inactive should be identified.

Concept Introduction:

Enantiomers are chiral molecules that are mirror images of one another. The molecules are non-superimposable on one another.

Optically active: These are capable of rotating the plane of polarized light to the right or left either dextrorotatory or levorotatory used of compounds, molecules, or atoms.

Optically inactive: A racemic mixture is an optically inactive; there is no net rotation of plane-polarized light. Although the two enantiomers rotate plane-polarized light in opposite directions, the rotations cancel because they are present in equal amounts.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 5.2 - Prob. 1LTS Ch. 5.3 - Prob. 3LTS Ch. 5.4 - Prob. 4LTS Ch. 5.4 - Prob. 11PTS Ch. 5.4 - Prob. 12PTS Ch. 5.4 - Prob. 13PTS Ch. 5.4 - Prob. 5LTS Ch. 5.4 - Prob. 15PTS Ch. 5.4 - Prob. 16PTS Ch. 5.4 - Prob. 17PTS

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