EBK BASIC CHEMISTRY
6th Edition
ISBN: 9780134987088
Author: Timberlake
Publisher: PEARSON CO
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Textbook Question
Chapter 5.4, Problem 40PP
Give the
a. has five electrons in the 3p sublevel
b. has four 2p electrons
c. completes the 3s sublevel
d. has one electron in the 3s sublevel
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10.
Stereochemistry. Assign R/S stereochemistry for the chiral center indicated on the
following compound. In order to recieve full credit, you MUST SHOW YOUR WORK!
H₂N
CI
OH
CI
カー
11. () Stereochemistry. Draw all possible stereoisomers of the following compound. Assign
R/S configurations for all stereoisomers and indicate the relationship between each as
enantiomer, diastereomer, or meso.
NH2
H
HNH,
-18
b)
8.
Indicate whether the following carbocation rearrangements are likely to occur
Please explain your rational using 10 words or less
not likely to occur
• The double bond is still in the
Same position
+
Likely
to oc
occur
WHY?
-3
H3C
Brave
Chair Conformers. Draw the chair conformer of the following substituted
cyclohexane. Peform a RING FLIP and indicate the most stable
conformation and briefly explain why using 20 words or less.
CI
2
-cobs ??
MUST INDICATE H -2
-2
Br
EQ
Cl
OR
AT
Br
H&
most stable
WHY?
- 4
CH
12
Conformational Analysis. Draw all 6 conformers (one above each letter) of the
compound below looking down the indicated bond. Write the letter of the
conformer with the HIGHEST and LOWEST in energies on the lines provided.
NOTE: Conformer A MUST be the specific conformer of the structure as drawn below
-4 NOT
HOH
OH
3
Conformer A:
Br
OH
A
Samo
Br H
04
Br
H
H3
CH₂
H
anti
stagere
Br CH
clipsed
H
Brott
H
IV
H
MISSING 2
-2
B
C
D
E
F
X
6
Conformer with HIGHEST ENERGY:
13. (1
structure
LOWEST ENERGY:
Nomenclature. a) Give the systematic (IUPAC) name structure. b) Draw the
corresponding to this name. HINT: Do not forget to indicate stereochemistry
when applicable.
a)
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2
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Parent name (noname)
4 Bromo
Sub = 2-methylethyl-4 Bromo nonane
b) (3R,4S)-3-chloro-4-ethyl-2,7-dimethyloctane
# -2
-2
Chapter 5 Solutions
EBK BASIC CHEMISTRY
Ch. 5.1 - What is meant by the wavelength of UV light?Ch. 5.1 - How are the wavelength and frequency of light...Ch. 5.1 - What is the difference between "white” light and...Ch. 5.1 - Prob. 4PPCh. 5.1 - Ultraviolet radiation (UVB) used to treat...Ch. 5.1 - AM radio waves have a frequency of 8105s1, whereas...Ch. 5.1 - If orange light has a wavelength of 6105cm, what...Ch. 5.1 - A wavelength of 850 nm is used for fiber-optic...Ch. 5.1 - Prob. 9PPCh. 5.1 - Prob. 10PP
Ch. 5.1 - Prob. 11PPCh. 5.1 - Place the following types of electromagnetic...Ch. 5.1 - Prob. 13PPCh. 5.1 - Place the following types of electromagnetic...Ch. 5.2 - What feature of an atomic spectrum indicates that...Ch. 5.2 - How can we explain the distinct lines that appear...Ch. 5.2 - Prob. 17PPCh. 5.2 - Prob. 18PPCh. 5.2 - Prob. 19PPCh. 5.2 - Prob. 20PPCh. 5.3 - Describe the shape of each of the following...Ch. 5.3 - Describe the shape of each of the following...Ch. 5.3 - Match statements 1 to 3 with a to d: 1. They have...Ch. 5.3 - Match statements 1 to 3 with a to d: 1. They have...Ch. 5.3 - Prob. 25PPCh. 5.3 - Indicate the number of each in the following: a....Ch. 5.3 - Prob. 27PPCh. 5.3 - Prob. 28PPCh. 5.4 - Compare the terms electron configuration and...Ch. 5.4 - Compare the terms orbital diagram and electron...Ch. 5.4 - Draw the orbital diagram for each of the...Ch. 5.4 - Draw the orbital diagram for each of the...Ch. 5.4 - Prob. 33PPCh. 5.4 - Write the complete electron configuration for each...Ch. 5.4 - Prob. 35PPCh. 5.4 - Prob. 36PPCh. 5.4 - Prob. 37PPCh. 5.4 - Prob. 38PPCh. 5.4 - Prob. 39PPCh. 5.4 - Give the symbol of the element that meets the...Ch. 5.5 - Use the sublevel blocks on the periodic table to...Ch. 5.5 - Use the sublevel blocks on the periodic table to...Ch. 5.5 - Use the sublevel blocks on the periodic table to...Ch. 5.5 - Use the sublevel blocks on the periodic table to...Ch. 5.5 - Prob. 45PPCh. 5.5 - Use the periodic table to give the symbol of the...Ch. 5.5 - Prob. 47PPCh. 5.5 - Use the periodic table lo give the symbol of the...Ch. 5.5 - Prob. 49PPCh. 5.5 - Prob. 50PPCh. 5.6 - What do the group numbers from IA (1) to 8A (18)...Ch. 5.6 - Prob. 52PPCh. 5.6 - Write the group number using both A/B and 1 to 18...Ch. 5.6 - Write the group number using both A/B and 1 to 18...Ch. 5.6 - Write the valence electron configuration for each...Ch. 5.6 - Prob. 56PPCh. 5.6 - Prob. 57PPCh. 5.6 - Indicate the number of valence electrons in each...Ch. 5.6 - Prob. 59PPCh. 5.6 - Prob. 60PPCh. 5.6 - Prob. 61PPCh. 5.6 - Prob. 62PPCh. 5.6 - Prob. 63PPCh. 5.6 - Select the element in each pair with the higher...Ch. 5.6 - Prob. 65PPCh. 5.6 - Prob. 66PPCh. 5.6 - Prob. 67PPCh. 5.6 - Prob. 68PPCh. 5.6 - Prob. 69PPCh. 5.6 - Prob. 70PPCh. 5.6 - Prob. 71PPCh. 5.6 - Prob. 72PPCh. 5.6 - Which statements completed with a to e will be...Ch. 5.6 - Which statements completed with a to e will be...Ch. 5.6 - Prob. 75PPCh. 5.6 - a. What is the atomic number of Te? b. How many...Ch. 5 - The chapter sections to review are shown in...Ch. 5 - Prob. 78UTCCh. 5 - Prob. 79UTCCh. 5 - Prob. 80UTCCh. 5 - The chapter sections to review are shown in...Ch. 5 - The chapter sections to review are shown in...Ch. 5 - The chapter sections to review are shown in...Ch. 5 - Prob. 84UTCCh. 5 - Prob. 85APPCh. 5 - Prob. 86APPCh. 5 - Prob. 87APPCh. 5 - Prob. 88APPCh. 5 - Prob. 89APPCh. 5 - Prob. 90APPCh. 5 - Prob. 91APPCh. 5 - Prob. 92APPCh. 5 - a. How many 3d electrons are in Fe? (5.4) b. How...Ch. 5 - a. How many 4d electrons are in Cd? (5.4) b. How...Ch. 5 - Write the abbreviated electron configuration and...Ch. 5 - Prob. 96APPCh. 5 - What do the elements Ca, Sr, and Ba have in common...Ch. 5 - Prob. 98APPCh. 5 - Prob. 99APPCh. 5 - Name the element that corresponds to each of the...Ch. 5 - Prob. 101APPCh. 5 - Prob. 102APPCh. 5 - Select the more metallic element in each pair....Ch. 5 - Select the more metallic element in each pair....Ch. 5 - Of the elements Na, P, CI, and F, which (5.6) a....Ch. 5 - Of the elements K, Ca, Br, and Kr, which (5.6) a....Ch. 5 - Prob. 107APPCh. 5 - Prob. 108APPCh. 5 - Prob. 109CPCh. 5 - Prob. 110CPCh. 5 - Prob. 111CPCh. 5 - Prob. 112CPCh. 5 - Prob. 113CPCh. 5 - The following problems are related to the topics...Ch. 5 - The following problems are related to the topics...Ch. 5 - The following problems are related to the topics...
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