Concept explainers
Interpretation:
The parent chain has to be named in the given compound.
Concept Introduction:
All the molecules have their unique names. These names must be known in order to communicate. But remembering all the chemical names is impossible as there are many numbers of molecules. To avoid this, the
Stereoisomerism | Substituents | Parent | Unsaturation | Functional Group |
Stereoisomerism indicate if the considered molecule has any stereocenters are present (R,S) and if double bond is present are cis/trans.
The groups that are connected to the main carbon chain is known as substituents.
The longest carbon chain is known as the parent. Parent carbon chain is the lengthiest carbon chain in the molecule that must include the functional group that is present in the compound. The longest carbon chain is identified and the parent name is given by the number of carbon atoms that is present in it. It must be remembered that even though functional group is not present in parent carbon chain, the double bond, triple bond if present has to be included.
Number of carbon atoms in chain | Parent |
1 | Meth |
2 | Eth |
3 | Prop |
4 | But |
5 | Pent |
6 | Hex |
Unsaturation indicates that if any triple or double bonds are present in the molecule. If a compound contains a double bond it is named as “-en-” and if a triple bond is present “-yn-” is used. If a compound contains two double bonds, then it is named as “-dien-”. If three double bonds are present in the given compound, then it is named as “-trien-”. This same rule applies for the compound that contains multiple triple bonds also.
Functional group is the one after which the considered compound is being named.
Functional Group | Class of compound | Suffix |
![]() | Ester | -oate |
![]() | -one | |
![]() | -al | |
![]() | -oic acid | |
![]() | Alcohol | -ol |
![]() | -amine |

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Chapter 5 Solutions
ORGANIC CHEMISTRY-NEXTGEN+BOX (1 SEM.)
- + C8H16O2 (Fatty acid) + 11 02 → 8 CO2 a. Which of the above are the reactants? b. Which of the above are the products? H2o CO₂ c. Which reactant is the electron donor? Futty acid d. Which reactant is the electron acceptor? e. Which of the product is now reduced? f. Which of the products is now oxidized? 02 #20 102 8 H₂O g. Where was the carbon initially in this chemical reaction and where is it now that it is finished? 2 h. Where were the electrons initially in this chemical reaction and where is it now that it is finished?arrow_forward→ Acetyl-CoA + 3NAD+ + 1FAD + 1ADP 2CO2 + CoA + 3NADH + 1FADH2 + 1ATP a. Which of the above are the reactants? b. Which of the above are the products? c. Which reactant is the electron donor? d. Which reactants are the electron acceptors? e. Which of the products are now reduced? f. Which product is now oxidized? g. Which process was used to produce the ATP? h. Where was the energy initially in this chemical reaction and where is it now that it is finished? i. Where was the carbon initially in this chemical reaction and where is it now that it is finished? j. Where were the electrons initially in this chemical reaction and where is it now that it is finished?arrow_forwardRank each of the following substituted benzene molecules in order of which will react fastest (1) to slowest (4) by electrophilic aromatic substitution. OCH 3 (Choose one) OH (Choose one) Br (Choose one) Explanation Check NO2 (Choose one) © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center | Aarrow_forward
- For each of the substituted benzene molecules below, determine the inductive and resonance effects the substituent will have on the benzene ring, as well as the overall electron-density of the ring compared to unsubstituted benzene. Molecule Inductive Effects O donating O withdrawing O no inductive effects Resonance Effects Overall Electron-Density ○ donating ○ withdrawing O no resonance effects O electron-rich O electron-deficient O similar to benzene Cl O donating O withdrawing ○ donating ○ withdrawing O no inductive effects O no resonance effects O Explanation Check O electron-rich O electron-deficient similar to benzene X © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center | Accessarrow_forwardIdentifying electron-donating and For each of the substituted benzene molecules below, determine the inductive and resonance effects the substituent will have on the benzene ring, as well as the overall electron-density of the ring compared to unsubstituted benzene. Molecule Inductive Effects NH2 ○ donating NO2 Explanation Check withdrawing no inductive effects Resonance Effects Overall Electron-Density ○ donating O withdrawing O no resonance effects O donating O withdrawing O donating withdrawing O no inductive effects Ono resonance effects O electron-rich electron-deficient O similar to benzene O electron-rich O electron-deficient O similar to benzene olo 18 Ar 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center | Accessibilityarrow_forwardRank each of the following substituted benzene molecules in order of which will react fastest (1) to slowest (4) by electrophilic aromatic substitution. Explanation Check Х (Choose one) OH (Choose one) OCH3 (Choose one) OH (Choose one) © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Centerarrow_forward
- Assign R or S to all the chiral centers in each compound drawn below porat bg 9 Br Brarrow_forwarddescrive the energy levels of an atom and howan electron moces between themarrow_forwardRank each set of substituents using the Cahn-Ingold-Perlog sequence rules (priority) by numbering the highest priority substituent 1.arrow_forward
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