Organic Chemistry, Binder Ready Version
2nd Edition
ISBN: 9781118454312
Author: David R. Klein
Publisher: WILEY
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Question
Chapter 5.3, Problem 10ATS
Interpretation Introduction
Interpretation: To assign configuration of chirality center should be identified for the given molecule by using its structure.
Concept Introduction:
Chiral center: The single chiral atoms (or) same structural feature in a compound cause that compound to have two possible structure which are non-superimposable each mirror image of the other molecule it is called chirality. In other words chiral, a single carbon atom attached to a four different groups.
Configuration: The spatial arrangement of the atoms of a chiral molecular group and its stereo chemical description R and S it is referring to (+R) or (-S).
(R-S) configuration: The right hand and left hand nomenclature is used to name the enantiomers of a chiral compound. These stereo centers are labeled as R (counter clockwise) and S (reversed clockwise).
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6. Consider the following exothermic reaction below.
2Cu2+(aq) +41 (aq)2Cul(s) + 12(aq)
a. If Cul is added, there will be a shift left/shift right/no shift (circle one).
b. If Cu2+ is added, there will be a shift left/shift right/no shift (circle one).
c. If a solution of AgNO3 is added, there will be a shift left/shift right/no shift (circle one).
d. If the solvent hexane (C6H14) is added, there will be a shift left/shift right/no shift (circle
one). Hint: one of the reaction species is more soluble in hexane than in water.
e. If the reaction is cooled, there will be a shift left/shift right/no shift (circle one).
f. Which of the changes above will change the equilibrium constant, K?
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Chapter 5 Solutions
Organic Chemistry, Binder Ready Version
Ch. 5.1 - Prob. 1LTSCh. 5.1 - Prob. 1PTSCh. 5.2 - Prob. 2LTSCh. 5.2 - Prob. 5ATSCh. 5.2 - Prob. 3LTSCh. 5.3 - Prob. 4LTSCh. 5.3 - Prob. 10ATSCh. 5.3 - Prob. 11ATSCh. 5.4 - Prob. 5LTSCh. 5.4 - Prob. 12PTS
Ch. 5.4 - Prob. 13PTSCh. 5.4 - Prob. 14PTSCh. 5.4 - Prob. 15ATSCh. 5.4 - Prob. 16ATSCh. 5.4 - Prob. 6LTSCh. 5.4 - Prob. 17PTSCh. 5.4 - Prob. 18PTSCh. 5.4 - Prob. 19PTSCh. 5.4 - Prob. 20ATSCh. 5.5 - Prob. 7LTSCh. 5.5 - Prob. 21PTSCh. 5.5 - Prob. 22ATSCh. 5.6 - Prob. 23CCCh. 5.6 - Prob. 24CCCh. 5.6 - Prob. 25CCCh. 5.6 - Prob. 8LTSCh. 5.6 - Prob. 26PTSCh. 5.6 - Prob. 27ATSCh. 5.6 - Prob. 28ATSCh. 5.7 - Prob. 9LTSCh. 5.7 - Prob. 29PTSCh. 5.7 - Prob. 30ATSCh. 5.7 - Prob. 31ATSCh. 5 - Prob. 32PPCh. 5 - Prob. 33PPCh. 5 - Prob. 34PPCh. 5 - Prob. 35PPCh. 5 - Prob. 36PPCh. 5 - Prob. 37PPCh. 5 - Prob. 38PPCh. 5 - Prob. 39PPCh. 5 - Prob. 40PPCh. 5 - Prob. 41PPCh. 5 - Prob. 42PPCh. 5 - Prob. 43PPCh. 5 - Prob. 44PPCh. 5 - Prob. 45PPCh. 5 - Prob. 46PPCh. 5 - Prob. 47PPCh. 5 - Prob. 48PPCh. 5 - Prob. 49PPCh. 5 - Prob. 50PPCh. 5 - Prob. 51PPCh. 5 - Prob. 52PPCh. 5 - Prob. 53IPCh. 5 - Prob. 54IPCh. 5 - Prob. 55IPCh. 5 - Prob. 56IPCh. 5 - Prob. 57IPCh. 5 - Prob. 58IPCh. 5 - Prob. 59IPCh. 5 - Prob. 60IPCh. 5 - Prob. 61IPCh. 5 - Prob. 62IPCh. 5 - Prob. 63IPCh. 5 - Prob. 64IPCh. 5 - Prob. 65IP
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