ORGANIC CHEMISTRY-PRINT COMPANION (LL)
3rd Edition
ISBN: 9781119444251
Author: Klein
Publisher: WILEY
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Question
Chapter 5.2, Problem 8ATS
Interpretation Introduction
Interpretation:
Enantiomer of the given compound has to be drawn.
Concept introduction:
The stereoisomerism is the arrangement of atoms in molecules whose connectivity remains the same but their arrangement in different in each isomer.
The two molecules are described as stereoisomers if they are made of the same atoms connected in the same sequence, but the atoms are positions differently in space.
Enantiomers: These are the structures of compounds in which the configuration of all the carbon atoms is different from each other. Both the structures are non-superimposable on it mirror image.
Chiral centre: A chiral centre is defined as the tetrahedral carbon atom in an organic molecule that is connected to four non-identical groups/substituents. It is sometimes known as a stereo genic centre.
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Give the major product of the following reaction.
excess
1. OH, H₂O
1.OH
H
CH3CH2CH21
H
2. A.-H₂O
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2. Use Hess's law to calculate the AH
(in kJ) for:
rxn
CIF(g) + F2(g) →
CIF 3 (1)
using the following information:
2CIF(g) + O2(g) →
Cl₂O(g) + OF 2(g)
AH = 167.5 kJ
ΔΗ
2F2 (g) + O2(g) → 2 OF 2(g)
2C1F3 (1) + 202(g) → Cl₂O(g) + 3 OF 2(g)
о
=
= -43.5 kJ
AH = 394.1kJ
ci
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Chapter 5 Solutions
ORGANIC CHEMISTRY-PRINT COMPANION (LL)
Ch. 5.1 -
In the following compound, identify each unit...Ch. 5.1 - Prob. 2CCCh. 5.1 - Prob. 3CCCh. 5.2 - Prob. 1LTSCh. 5.2 - Prob. 4PTSCh. 5.2 - Prob. 5ATSCh. 5.2 - Prob. 6ATSCh. 5.2 - Prob. 2LTSCh. 5.2 - Prob. 7PTSCh. 5.2 - Prob. 8ATS
Ch. 5.3 - Prob. 3LTSCh. 5.3 - Prob. 9PTSCh. 5.3 - Prob. 10ATSCh. 5.4 - Prob. 4LTSCh. 5.4 - Prob. 11PTSCh. 5.4 - Prob. 12PTSCh. 5.4 - Prob. 13PTSCh. 5.4 - Prob. 14ATSCh. 5.4 - Prob. 5LTSCh. 5.4 - Prob. 15PTSCh. 5.4 - Prob. 16PTSCh. 5.4 - Prob. 17PTSCh. 5.4 - Prob. 18ATSCh. 5.5 - Prob. 6LTSCh. 5.5 - Prob. 19PTSCh. 5.5 - Prob. 20ATSCh. 5.6 - Prob. 21CCCh. 5.6 - Prob. 22CCCh. 5.6 - Prob. 23CCCh. 5.6 - Prob. 7LTSCh. 5.6 - Prob. 24PTSCh. 5.6 - Prob. 25ATSCh. 5.7 - Prob. 8LTSCh. 5.7 - Prob. 26PTSCh. 5.7 -
Protease inhibitors are a class of anti-viral...Ch. 5.9 - Prob. 28CCCh. 5.11 - Prob. 9LTSCh. 5.11 - Prob. 29PTSCh. 5.11 - Prob. 30ATSCh. 5 - Prob. 31PPCh. 5 - Prob. 32PPCh. 5 - Prob. 33PPCh. 5 - Prob. 34PPCh. 5 - Prob. 35PPCh. 5 - Prob. 36PPCh. 5 - Prob. 37PPCh. 5 - Prob. 38PPCh. 5 - Prob. 39PPCh. 5 - Prob. 40PPCh. 5 - Prob. 41PPCh. 5 - Prob. 42PPCh. 5 - Prob. 43PPCh. 5 - Prob. 44PPCh. 5 - Prob. 45PPCh. 5 - Prob. 46PPCh. 5 - Prob. 47PPCh. 5 - Prob. 48PPCh. 5 - Prob. 49PPCh. 5 - Prob. 50PPCh. 5 - Prob. 51PPCh. 5 - Prob. 52PPCh. 5 - For each of the following pairs of compounds,...Ch. 5 - Prob. 54PPCh. 5 - Prob. 55PPCh. 5 - Prob. 56PPCh. 5 - Prob. 57IPCh. 5 - Prob. 58IPCh. 5 - Prob. 59IPCh. 5 - Prob. 60IPCh. 5 - There are only two stereoisomers of...Ch. 5 - Prob. 62IPCh. 5 - Prob. 63IPCh. 5 - Prob. 64IPCh. 5 - Prob. 65IPCh. 5 - Prob. 66IPCh. 5 - Prob. 67IPCh. 5 - Prob. 68IPCh. 5 - Prob. 69IPCh. 5 - Prob. 70IPCh. 5 - Prob. 71IPCh. 5 - Prob. 72IPCh. 5 - Prob. 73IPCh. 5 - Prob. 74IPCh. 5 - Prob. 75IPCh. 5 - Prob. 76IPCh. 5 - Prob. 77CPCh. 5 - Prob. 78CPCh. 5 - Prob. 79CPCh. 5 - Prob. 80CP
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