Chemistry: An Introduction to General, Organic, and Biological Chemistry (13th Edition)
13th Edition
ISBN: 9780134421353
Author: Karen C. Timberlake
Publisher: PEARSON
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Textbook Question
Chapter 5.2, Problem 5.21PP
Complete each of the following reactions:
a.
b.
c.
d.
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its just one question with parts till (g) JUST ONE QUESTION with its parts spread out in the form of different images attached 2 IMAGES ATTACHED PLEASE SEE ALL, please answer EACH part till the end and dont just provide wordy explanations wherever asked for structures or diagrams, please DRAW DRAW them on a paper and post clearly!! answer the full question with all details EACH PART CLEARLY please thanks!!
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The complex anion in Ba₂[Cr(CN)6] is a tetragonally distorted octahedral complex (Dan). Baz[Cr(CN)6] is
paramagnetic at room temperature with S = 1. Assume that the complex is a low-spin complex.
a) Identify if the [Cr(CN)6] anionic complex has 4 long and
2 short bonds (left side of figure) or if the complex has 4
short and 2 long bonds (right side of figure) with respect
to Oh symmetry. Use crystal field theory to answer this
question. Explain/rationalize your decision. Can the
provided information decide on the order of orbital
energies?
Dah
Tetragonal Distortion
ய
Dab
z-compression
z-elongation
x and y elongation
O symmetry
x and y compression
E
eg d² dx²-y²
t2g
dxy dxz dyz
Question 4 a) continued:
Provide your explanations in the space below.
b) At low temperatures Ba₂[Cr(CN)6] is ferromagnetically ordered with a phase transition to a paramagnetic
phase at Tc = 150K. Sketch the magnetic susceptibility vs. temperature in the diagram below. Indicate Tc
as well as the paramagnetic and…
Chapter 5 Solutions
Chemistry: An Introduction to General, Organic, and Biological Chemistry (13th Edition)
Ch. 5.1 - Prob. 5.1PPCh. 5.1 - Prob. 5.2PPCh. 5.1 - Naturally occurring potassium consists of three...Ch. 5.1 - Naturally occurring iodine is iodine-127....Ch. 5.1 - Identify each of the following: a. 10X b. 24X c....Ch. 5.1 - Identify each of the following: a. 11X b. 3581X c....Ch. 5.1 - Prob. 5.7PPCh. 5.1 - Prob. 5.8PPCh. 5.1 - Prob. 5.9PPCh. 5.1 - Prob. 5.10PP
Ch. 5.1 - Prob. 5.11PPCh. 5.1 - Prob. 5.12PPCh. 5.2 - Prob. 5.13PPCh. 5.2 - Prob. 5.14PPCh. 5.2 - Prob. 5.15PPCh. 5.2 - Prob. 5.16PPCh. 5.2 - Prob. 5.17PPCh. 5.2 - Prob. 5.18PPCh. 5.2 - Prob. 5.19PPCh. 5.2 - Prob. 5.20PPCh. 5.2 - Complete each of the following reactions: a....Ch. 5.2 - Prob. 5.22PPCh. 5.3 - Prob. 5.23PPCh. 5.3 - Prob. 5.24PPCh. 5.3 - Prob. 5.25PPCh. 5.3 - Prob. 5.26PPCh. 5.3 - Prob. 5.27PPCh. 5.3 - Prob. 5.28PPCh. 5.4 - Prob. 5.29PPCh. 5.4 - Prob. 5.30PPCh. 5.4 - Prob. 5.31PPCh. 5.4 - Prob. 5.32PPCh. 5.4 - Prob. 5.33PPCh. 5.4 - Prob. 5.34PPCh. 5.5 - Prob. 5.35PPCh. 5.5 - Prob. 5.36PPCh. 5.5 - Prob. 5.37PPCh. 5.5 - Prob. 5.38PPCh. 5.5 - Prob. 5.39PPCh. 5.5 - Prob. 5.40PPCh. 5.6 - Prob. 5.41PPCh. 5.6 - Prob. 5.42PPCh. 5.6 - Prob. 5.43PPCh. 5.6 - Prob. 5.44PPCh. 5.6 - Prob. 5.45PPCh. 5.6 - Prob. 5.46PPCh. 5.6 - Prob. 5.47PPCh. 5.6 - Prob. 5.48PPCh. 5.6 - Prob. 5.49PPCh. 5.6 - Prob. 5.50PPCh. 5 - Prob. 5.51UTCCh. 5 - Prob. 5.52UTCCh. 5 - 5.53 Draw the nucleus of the isotope that is...Ch. 5 - Prob. 5.54UTCCh. 5 - Prob. 5.55UTCCh. 5 - Prob. 5.56UTCCh. 5 - Determine the number of protons and number of...Ch. 5 - Determine the number of protons and number of...Ch. 5 - Prob. 5.59APPCh. 5 - Prob. 5.60APPCh. 5 - Prob. 5.61APPCh. 5 - Prob. 5.62APPCh. 5 - Prob. 5.63APPCh. 5 - Prob. 5.64APPCh. 5 - Prob. 5.65APPCh. 5 - Prob. 5.66APPCh. 5 - Prob. 5.67APPCh. 5 - Prob. 5.68APPCh. 5 - Prob. 5.69APPCh. 5 - Prob. 5.70APPCh. 5 - Where does fusion occur naturally? (5.6)Ch. 5 - Prob. 5.72APPCh. 5 - Prob. 5.73APPCh. 5 - Prob. 5.74APPCh. 5 - Prob. 5.75APPCh. 5 - Prob. 5.76APPCh. 5 - Prob. 5.77APPCh. 5 - Prob. 5.78APPCh. 5 - Prob. 5.79CPCh. 5 - Prob. 5.80CPCh. 5 - Prob. 5.81CPCh. 5 - Prob. 5.82CPCh. 5 - Prob. 5.83CPCh. 5 - Prob. 5.84CPCh. 5 - Prob. 5.85CPCh. 5 - Prob. 5.86CPCh. 5 - Prob. 5.87CPCh. 5 - Prob. 5.88CPCh. 5 - Prob. 5.89CPCh. 5 - Prob. 5.90CP
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